☣️ UN 2541 • CLASS 3

UN 2541 — Terpinolene

Placard: Flammable. ERG Guide 128. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Terpinolene is a volatile, pine-scented flammable liquid shipped as UN 2541. The main emergency concern is vapor ignition, flashback and spread into drains or confined spaces.

Hazard overview: Terpinolene vapors are heavier than air and can form explosive mixtures. Vapor may travel to ignition sources and flash back, making drain, sewer and low-area control important.

Response guidance: Eliminate ignition sources, isolate the spill and keep responders upwind. Use foam, dry chemical or CO2 for fire; water spray may be used to cool exposed containers but may not control the liquid fire by itself.

Firefighter training notes: Train crews on flammable liquid vapor travel, flashback and drain protection. Practice foam application and container cooling from a protected position.

Regulatory context: UN 2541 is transported as Terpinolene, Class 3 flammable liquid. Confirm packing group, quantity and emergency contact details on shipping papers.

Storage & handling: Store in closed, grounded containers away from heat, sparks, oxidizers and direct sunlight. Keep in a cool, well-ventilated flammable liquid area.

Advertisement

UN 2541 Quick Details

UN 2541
Product name: Terpinolene
DOT Class: 3
Placard type: Flammable
ERG Guide: 128 (check current ERG)
Initial isolation: ERG 128: Small spill isolate 50m, large spill isolate 150m initial; evacuate 800m downwind if fire or large spill

Common Hazards of UN 2541

  • Terpinolene is a flammable liquid; vapors can ignite from heat, sparks, static or open flame.
  • Vapors may form explosive mixtures with air, especially in low or confined areas.
  • Vapor can travel along the ground to an ignition source and flash back.
  • Runoff to sewers, drains or basements can create a fire or explosion hazard.
  • Containers may rupture or explode when heated.
  • Burning liquid can produce irritating smoke and carbon oxides.
  • Liquid contact may irritate skin and eyes.

Chemical Identity & Physical Properties

Terpinolene is a colorless to pale yellow liquid with a fresh pine or citrus-like odor. It is insoluble in water and floats as a flammable layer.

Also known asp-Mentha-1,4(8)-diene1-Methyl-4-isopropenyl-1-cyclohexeneTerpinolenDelta-terpinene
CAS Number586-62-9
AppearanceColorless to pale yellow liquid with a fresh, piney, citrus-like odor. Liquid at room temperature.
Flash Point50C (122F)
Boiling Point185-186C (365-367F)
Vapor Density4.7 (heavier than air)
Water ReactivityInsoluble in water; no significant reaction
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2541

Extinguishing Media

AFFF foam, alcohol-resistant foam, CO2, dry chemical, water spray

PPE Requirements

⚠️ Level B minimum for spill response; SCBA and chemical-resistant clothing required in confined spaces or fire

Use SCBA for fire or high vapor areas. Wear chemical-resistant gloves, splash protection and protective clothing to prevent liquid contact.

Isolation & Evacuation

ERG 128: Small spill isolate 50m, large spill isolate 150m initial; evacuate 800m downwind if fire or large spill
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 128).

First Actions for a UN 2541 Incident

  • Call 911 and the emergency response number on the shipping papers.
  • Keep unauthorized personnel away and remove ignition sources if it can be done safely.
  • Stay upwind, uphill and upstream; avoid low areas where vapor may collect.
  • Avoid breathing vapor and prevent skin or eye contact.
  • Do not touch damaged containers or walk through spilled liquid without PPE.
  • Ventilate confined spaces only if trained, equipped and using atmospheric monitoring.
  • Use ERG 128, SDS and shipping papers to confirm isolation, foam selection and cleanup.
Advertisement

📋 Copy & Share Field Card

UN 2541 — Terpinolene
HAZMAT RADIO NOTE — UN 2541 Product: Terpinolene Class 3 / Flammable / ERG 128 PPE: Level B minimum for spill response; SCBA and chemical-resistant clothing required in confined spaces or fire ISOLATION: ERG 128: Small spill isolate 50m, large spill isolate 150m initial; evacuate 800m downwind if fire or large spill ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2541 — Terpinolene Class: 3 | Placard: Flammable | ERG Guide: 128 Appearance: Colorless to pale yellow liquid with a fresh, piney, citrus-like odor. Liquid at room temperature. Water Reactivity: Insoluble in water; no significant reaction Extinguishing: AFFF foam, alcohol-resistant foam, CO2, dry chemical, water spray PPE: Level B minimum for spill response; SCBA and chemical-resistant clothing required in confined spaces or fire Isolation: ERG 128: Small spill isolate 50m, large spill isolate 150m initial; evacuate 800m downwind if fire or large spill — Key Hazards — • Terpinolene is a flammable liquid; vapors can ignite from heat, sparks, static or open flame. • Vapors may form explosive mixtures with air, especially in low or confined areas. • Vapor can travel along the ground to an ignition source and flash back. — First Actions — • Call 911 and the emergency response number on the shipping papers. • Keep unauthorized personnel away and remove ignition sources if it can be done safely. • Stay upwind, uphill and upstream; avoid low areas where vapor may collect. • Avoid breathing vapor and prevent skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/terpinolene-un-2541 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2541 Terpinolene Cls3 ERG128 | allfirefighter.com/hazmat/un/terpinolene-un-2541SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/terpinolene-un-2541

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

Frequently Asked Questions about UN 2541

Vapor can collect in drains or sewers and ignite, causing flashback or vapor explosion.

Stop ignition sources, keep people away and prevent the liquid from entering sewers or confined spaces.

Foam, dry chemical or CO2 are typical choices; water spray is mainly for cooling containers and protecting exposures.

Yes. They can settle in low areas and move along the ground to ignition sources.

SCBA is needed for fire or significant vapor; gloves, eye protection and chemical-resistant clothing protect from liquid contact.

Use ERG 128 with the SDS and shipping papers.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.