☣️ UN 1306 • CLASS 3

UN 1306 — Wood preservatives, liquid

Placard: Flammable. ERG Guide 129. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1306 is Wood preservatives, liquid, a Class 3 flammable liquid assigned to ERG Guide 129. It can generate vapors that ignite easily, travel to ignition sources and flash back.

Hazard overview: UN 1306 presents flammable vapor, flashback and container-heating hazards. Vapors are typically heavier than air and may collect in low, confined or sewer areas where ignition can cause a vapor explosion.

Response guidance: For a UN 1306 incident, responders should confirm the product using shipping papers, container markings, SDS and ERG Guide 129. Establish incident command, isolate the area, stay upwind and uphill, remove ignition sources when safe, keep vapors or runoff out of sewers and use compatible fire-control agents from a protected position.

Firefighter training notes: Training for UN 1306 should emphasize flammable liquid vapor travel, flashback, sewer vapor explosion risk, foam compatibility, container cooling and atmospheric monitoring. Common errors include standing downwind, allowing runoff into drains and ignoring low-area vapor collection. Use ERG 129, SDS and local SOP.

Regulatory context: Wood preservatives, liquid is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Wood preservatives, liquid should be stored in tightly closed compatible containers in a cool, dry, well-ventilated flammable-liquid storage area. Keep away from heat, sparks, open flames, oxidizers and incompatible materials, with bonding/grounding, secondary containment and drain protection where required.

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UN 1306 Quick Details

UN 1306
Product name: Wood preservatives, liquid
DOT Class: 3
Placard type: Flammable
ERG Guide: 129 (check current ERG)
Initial isolation: ERG 129: isolate spill area minimum 50m all directions; if tank/railcar involved in fire, isolate 800m all directions and evacuate for 1600m

Common Hazards of UN 1306

  • HIGHLY FLAMMABLE: will be easily ignited by heat, sparks or flames.
  • Vapors may form explosive mixtures with air.
  • Vapors may travel to an ignition source and flash back.
  • Most vapors are heavier than air and may spread along the ground into low or confined areas.
  • Vapor explosion hazard exists indoors, outdoors or in sewers.
  • Runoff to sewer may create fire or explosion hazard.
  • Containers may rupture or explode when heated.

Chemical Identity & Physical Properties

Liquid mixture typically amber to dark brown in color with a characteristic chemical or petroleum-like odor. May contain various biocides, fungicides, or insecticides dissolved in flammable solvents.

Also known asWood preservative solutionTimber treatment liquidWood treatment chemicalPreservative wood coating
AppearanceLiquid mixture typically amber to dark brown in color with a characteristic chemical or petroleum-like odor. May contain various biocides, fungicides, or insecticides dissolved in flammable solvents.
Flash PointVaries by formulation, typically below 23C (73F) for Class 3 flammable liquids
Boiling PointVaries by solvent carrier, typically 60-150C (140-302F) depending on formulation
Vapor DensityGreater than 1 (heavier than air) due to organic solvent content
Water ReactivityNo significant reaction with water, though immiscible and may form surface layer
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1306

Extinguishing Media

Use AFFF or alcohol-resistant foam where compatible, dry chemical or CO2 for Class B fires; water spray may be used to cool exposed containers.

PPE Requirements

⚠️ Level B minimum; SCBA required in fire or confined space; chemical-resistant suit and gloves to prevent skin absorption of biocides

Use positive-pressure SCBA for fire, heavy vapor or confined-space exposure. Chemical-resistant gloves, splash protection and protective clothing should be selected using SDS, product concentration and incident command.

Isolation & Evacuation

ERG 129: isolate spill area minimum 50m all directions; if tank/railcar involved in fire, isolate 800m all directions and evacuate for 1600m
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 129).

First Actions for a UN 1306 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Eliminate ignition sources if it is safe to do so.
  • Do not touch or walk through spilled liquid unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped and authorized by incident command.
  • Isolate the spill or leak area for at least 50 meters (150 feet) in all directions.
  • For large spills, fire involvement or strong vapor movement, expand isolation and consider downwind evacuation based on monitoring and incident command.
  • Use ERG Guide 129, shipping papers, SDS and local SOP for protective actions and entry decisions.
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📋 Copy & Share Field Card

UN 1306 — Wood preservatives, liquid
HAZMAT RADIO NOTE — UN 1306 Product: Wood preservatives, liquid Class 3 / Flammable / ERG 129 PPE: Level B minimum; SCBA required in fire or confined space; chemical-resistant suit and gloves to prevent skin absorption of biocides ISOLATION: ERG 129: isolate spill area minimum 50m all directions; if tank/railcar involved in fire, isolate 800m all directions and evacuate for 1600m ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1306 — Wood preservatives, liquid Class: 3 | Placard: Flammable | ERG Guide: 129 Appearance: Liquid mixture typically amber to dark brown in color with a characteristic chemical or petroleum-like odor. May contain various biocides, fungicides, or insecticides dissolved in flammable solvents. Water Reactivity: No significant reaction with water, though immiscible and may form surface layer Extinguishing: Use AFFF or alcohol-resistant foam where compatible, dry chemical or CO2 for Class B fires; water spray may be used to cool exposed containers. PPE: Level B minimum; SCBA required in fire or confined space; chemical-resistant suit and gloves to prevent skin absorption of biocides Isolation: ERG 129: isolate spill area minimum 50m all directions; if tank/railcar involved in fire, isolate 800m all directions and evacuate for 1600m — Key Hazards — • HIGHLY FLAMMABLE: will be easily ignited by heat, sparks or flames. • Vapors may form explosive mixtures with air. • Vapors may travel to an ignition source and flash back. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Eliminate ignition sources if it is safe to do so. SOURCE: allfirefighter.com/hazmat/un/wood-preservatives-liquid-un-1306 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1306 Wood preservatives, liquid Cls3 ERG129 | allfirefighter.com/hazmat/un/wood-preservatives-liquid-un-1306SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/wood-preservatives-liquid-un-1306

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1306

UN 1306 is Wood preservatives, liquid, a hazardous material assigned to ERG Guide 129.

Yes. It is flammable and vapors may form explosive mixtures with air.

ERG Guide 129 applies to UN 1306 for initial isolation, protective actions and first response guidance.

UN 1306 presents flammable vapor, flashback and container-heating hazards. Vapors are typically heavier than air and may collect in low, confined or sewer areas where ignition can cause a vapor explosion.

Use AFFF or alcohol-resistant foam where compatible, dry chemical or CO2 for Class B fires; water spray may be used to cool exposed containers.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.