☣️ UN 1514 • CLASS 5

UN 1514 — Zinc nitrate

Placard: Oxidizer. ERG Guide 140. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1514 is Zinc nitrate, a Class 5 nitrate/nitrite oxidizer assigned to ERG Guide 140. It can intensify fire and may decompose when heated or contaminated.

Hazard overview: UN 1514 presents oxidizer, heating and contamination hazards. Keep away from fuels, organics and reducing agents, and control dust or runoff according to SDS and incident command.

Response guidance: For a UN 1514 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 140. Establish incident command, isolate the area, stay upwind, prevent incompatible contact and choose extinguishing or spill-control actions based on ERG, SDS and local SOP.

Firefighter training notes: Training for UN 1514 should emphasize oxidizer fire behavior, separation from fuels and organics, contamination control, dust avoidance, container-heating hazards and correct extinguishing decisions. Use ERG 140, SDS and local SOP.

Regulatory context: Zinc nitrate is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Zinc nitrate should be stored in compatible oxidizer storage away from fuels, organic materials, reducing agents, acids where incompatible, heat, ignition sources and contamination. Keep containers closed, dry, clearly labeled and separated from combustible packaging or spilled residues.

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UN 1514 Quick Details

UN 1514
Product name: Zinc nitrate
DOT Class: 5
Placard type: Oxidizer
ERG Guide: 140 (check current ERG)
Initial isolation: ERG 140: isolate spill/leak area immediately for at least 25-50 meters in all directions; if tank/rail car involved in fire, isolate 800 meters in all directions and consider initial evacuation for 800 meters

Common Hazards of UN 1514

  • OXIDIZER: may intensify fire and accelerate burning of combustible materials.
  • Heating or confinement may cause decomposition and pressure buildup.
  • Nitrates and nitrites may react dangerously with fuels, organic materials, reducing agents or contamination.
  • Containers may rupture or explode when heated.
  • Fire may produce irritating and/or toxic gases.
  • Runoff may spread oxidizing material and create fire, explosion or environmental hazards.
  • Dust, solution or decomposition products may irritate or injure eyes, skin or respiratory tissue.

Chemical Identity & Physical Properties

Colorless to white crystalline solid or granular powder, odorless. Deliquescent, absorbs moisture from air.

Also known asZinc dinitrateNitric acid zinc saltZinc(II) nitrate hexahydrateZinc nitrate hexahydrate
CAS Number7779-88-6
AppearanceColorless to white crystalline solid or granular powder, odorless. Deliquescent, absorbs moisture from air.
Flash PointNot applicable (oxidizer, not flammable itself)
Boiling PointNot applicable (decomposes above 110C/230F)
Vapor DensityNot applicable (solid oxidizer)
Water ReactivitySoluble in water, exothermic dissolution produces heat but no violent reaction
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1514

Extinguishing Media

Use water spray or flooding water from a protected position when ERG, SDS and incident command confirm it is appropriate. Keep the material away from fuels, organics and contaminated absorbents; avoid agents that add incompatible contamination or fail to control oxidizer-supported fire.

PPE Requirements

⚠️ Level B minimum recommended; full protective clothing, chemical-resistant gloves, face shield, and SCBA required during fire or spill response

Use positive-pressure SCBA for fire, dust, decomposition or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS and incident command.

Isolation & Evacuation

ERG 140: isolate spill/leak area immediately for at least 25-50 meters in all directions; if tank/rail car involved in fire, isolate 800 meters in all directions and consider initial evacuation for 800 meters
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 140).

First Actions for a UN 1514 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Keep combustibles, fuels, organics, reducing agents and contaminated materials away from the spill.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Avoid creating dust clouds and prevent runoff from contacting combustibles, drains or incompatible materials when possible.
  • Ventilate closed spaces before entering, but only if properly trained, equipped and authorized by incident command.
  • Isolate the spill or fire area and expand the perimeter if large quantities, contamination, heating or container involvement are present.
  • Use ERG Guide 140, shipping papers, SDS and local SOP for protective actions and entry decisions.
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📋 Copy & Share Field Card

UN 1514 — Zinc nitrate
HAZMAT RADIO NOTE — UN 1514 Product: Zinc nitrate Class 5 / Oxidizer / ERG 140 PPE: Level B minimum recommended; full protective clothing, chemical-resistant gloves, face shield, and SCBA required during fire or spill response ISOLATION: ERG 140: isolate spill/leak area immediately for at least 25-50 meters in all directions; if tank/rail car involved in fire, isolate 800 meters in all directions and consider initial evacuation for 800 meters ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1514 — Zinc nitrate Class: 5 | Placard: Oxidizer | ERG Guide: 140 Appearance: Colorless to white crystalline solid or granular powder, odorless. Deliquescent, absorbs moisture from air. Water Reactivity: Soluble in water, exothermic dissolution produces heat but no violent reaction Extinguishing: Use water spray or flooding water from a protected position when ERG, SDS and incident command confirm it is appropriate. Keep the material away from fuels, organics and contaminated absorbents; avoid agents that add incompatible contamination or fail to control oxidizer-supported fire. PPE: Level B minimum recommended; full protective clothing, chemical-resistant gloves, face shield, and SCBA required during fire or spill response Isolation: ERG 140: isolate spill/leak area immediately for at least 25-50 meters in all directions; if tank/rail car involved in fire, isolate 800 meters in all directions and consider initial evacuation for 800 meters — Key Hazards — • OXIDIZER: may intensify fire and accelerate burning of combustible materials. • Heating or confinement may cause decomposition and pressure buildup. • Nitrates and nitrites may react dangerously with fuels, organic materials, reducing agents or contamination. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Keep combustibles, fuels, organics, reducing agents and contaminated materials away from the spill. SOURCE: allfirefighter.com/hazmat/un/zinc-nitrate-un-1514 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1514 Zinc nitrate Cls5 ERG140 | allfirefighter.com/hazmat/un/zinc-nitrate-un-1514SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/zinc-nitrate-un-1514

Related UN Numbers in Class 5

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1514

UN 1514 is Zinc nitrate, a Class 5 oxidizer assigned to ERG Guide 140.

No. It is not normally flammable, but it can strongly accelerate burning of other materials.

ERG Guide 140 applies to UN 1514 for initial isolation, protective actions and first response guidance.

UN 1514 presents oxidizer, heating and contamination hazards. Keep away from fuels, organics and reducing agents, and control dust or runoff according to SDS and incident command.

Use positive-pressure SCBA for fire, dust, decomposition or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS and incident command.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.