☣️ UN 0094 • CLASS 1

UN 0094 — Flash powder

Placard: Explosive 1.1G. ERG Guide 112. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 0094 is Flash powder, a Class 1 explosive assigned to ERG Guide 112. This entry should be treated as a high-consequence explosive hazard where isolation, evacuation and qualified explosive ordnance support are the primary responder priorities.

Hazard overview: UN 0094 presents a mass explosion hazard when exposed to fire, impact, shock, friction or other initiating conditions. A detonation may involve the entire load and produce severe blast pressure, fragmentation and secondary debris. Responders should not rely on normal firefighting PPE as protection from blast effects.

Response guidance: For a UN 0094 incident, responders should confirm the material using shipping papers, placards, package markings and ERG Guide 112. Establish incident command, isolate the area, deny entry, request law enforcement and EOD support, and withdraw personnel if fire involves the explosive material or containers.

Firefighter training notes: Training should emphasize recognizing Class 1 explosive placards, establishing command early, using standoff distance, denying entry and requesting bomb squad or EOD support. Common tactical errors include approaching packages for identification, moving damaged items, fighting fire too close and underestimating fragmentation distance. Use ERG 112, shipping papers and local explosive incident SOP.

Regulatory context: Flash powder is regulated as a Class 1 explosive hazardous material. Transport, storage, reporting and scene-control requirements may involve DOT, ATF, OSHA, military, state or local authorities depending on ownership and quantity. Responders should verify requirements through shipping papers, facility documents, law enforcement and current regulations.

Storage & handling: Flash powder should be stored only in approved explosive magazines or authorized storage areas, separated from ignition sources, incompatible materials and unauthorized access. Packages should be protected from heat, impact, friction, moisture where relevant and physical damage according to product documentation and applicable explosive storage regulations.

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UN 0094 Quick Details

UN 0094
Product name: Flash powder
DOT Class: 1
Placard type: Explosive 1.1G
ERG Guide: 112 (check current ERG)
Initial isolation: ERG 112: Initial isolation 500m in all directions; for fire or large spill evacuate 1600m downwind; treat as mass explosion hazard

Common Hazards of UN 0094

  • Mass explosion hazard; the entire load may detonate simultaneously if initiated.
  • Severe blast overpressure, fragmentation and debris may extend far beyond the immediate container or vehicle.
  • Explosive articles or substances may be sensitive to heat, shock, friction, impact or fire exposure.
  • Fire involving the material can transition rapidly to detonation without reliable warning.
  • Secondary fires, projectiles and container fragments may create hazards after an initial event.
  • Smoke from fire may contain irritating or toxic combustion products.

Chemical Identity & Physical Properties

Fine gray to silver metallic powder mixture, typically composed of aluminum or magnesium metal combined with oxidizing agents such as potassium perchlorate. Odorless when dry.

Also known asPhotoflash powderPyrotechnic flash compositionFlash compositionMagnesium flash powder
AppearanceFine gray to silver metallic powder mixture, typically composed of aluminum or magnesium metal combined with oxidizing agents such as potassium perchlorate. Odorless when dry.
Flash PointNot applicable (explosive solid)
Boiling PointNot applicable (decomposes explosively)
Vapor DensityNot applicable (solid)
Water ReactivityMay react with water if magnesium-based; keep dry to prevent degradation and sensitivity increase
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 0094

Extinguishing Media

Do not fight fire involving explosives at close range. Use unmanned master streams or remote cooling only if directed by incident command and safe under local SOP.

PPE Requirements

⚠️ No standard PPE protects against blast and fragmentation. Use distance, cover, evacuation, SCBA for smoke exposure and EOD/bomb squad support for any approach.

For UN 0094, distance, cover and evacuation are more important than close-range PPE. Structural firefighting gear and SCBA may be used only for remote exposure protection or support roles; direct approach or handling should be limited to qualified EOD or explosive specialists under incident command.

Isolation & Evacuation

ERG 112: Initial isolation 500m in all directions; for fire or large spill evacuate 1600m downwind; treat as mass explosion hazard
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 112).

First Actions for a UN 0094 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away and deny entry to the hazard area.
  • Stage responders upwind, uphill and outside the recommended isolation distance.
  • Request law enforcement, bomb squad or EOD, hazmat and additional command resources immediately.
  • Do not handle, move or disturb explosive articles unless directed by qualified explosive ordnance personnel.
  • Do not fight fire involving explosives at close range; withdraw and protect life safety first.
  • Protect exposures only from a safe, remote position if directed by incident command and local SOP.
  • Use ERG Guide 112, shipping papers and incident command to set isolation and evacuation distances.
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📋 Copy & Share Field Card

UN 0094 — Flash powder
HAZMAT RADIO NOTE — UN 0094 Product: Flash powder Class 1 / Explosive 1.1G / ERG 112 PPE: No standard PPE protects against blast and fragmentation. Use distance, cover, evacuation, SCBA for smoke exposure and EOD/bomb squad support for any approach. ISOLATION: ERG 112: Initial isolation 500m in all directions; for fire or large spill evacuate 1600m downwind; treat as mass explosion hazard ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0094 — Flash powder Class: 1 | Placard: Explosive 1.1G | ERG Guide: 112 Appearance: Fine gray to silver metallic powder mixture, typically composed of aluminum or magnesium metal combined with oxidizing agents such as potassium perchlorate. Odorless when dry. Water Reactivity: May react with water if magnesium-based; keep dry to prevent degradation and sensitivity increase Extinguishing: Do not fight fire involving explosives at close range. Use unmanned master streams or remote cooling only if directed by incident command and safe under local SOP. PPE: No standard PPE protects against blast and fragmentation. Use distance, cover, evacuation, SCBA for smoke exposure and EOD/bomb squad support for any approach. Isolation: ERG 112: Initial isolation 500m in all directions; for fire or large spill evacuate 1600m downwind; treat as mass explosion hazard — Key Hazards — • Mass explosion hazard; the entire load may detonate simultaneously if initiated. • Severe blast overpressure, fragmentation and debris may extend far beyond the immediate container or vehicle. • Explosive articles or substances may be sensitive to heat, shock, friction, impact or fire exposure. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away and deny entry to the hazard area. • Stage responders upwind, uphill and outside the recommended isolation distance. • Request law enforcement, bomb squad or EOD, hazmat and additional command resources immediately. SOURCE: allfirefighter.com/hazmat/un/flash-powder-un-0094 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN0094 Flash powder Cls1 ERG112 | allfirefighter.com/hazmat/un/flash-powder-un-0094SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/flash-powder-un-0094

Related UN Numbers in Class 1

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 0094

UN 0094 is Flash powder, a Class 1 explosive assigned to ERG Guide 112.

Yes. UN 0094 should be treated as capable of severe blast and fragmentation; some conditions may allow the entire load to detonate.

ERG Guide 112 applies to UN 0094 and should be used for initial isolation, evacuation and first response decisions.

The main hazards are blast overpressure, fragmentation, fire involvement, shock or heat sensitivity and secondary debris or smoke hazards.

No standard firefighter PPE protects against a close-range detonation. Responders should use distance, cover and evacuation, with EOD or explosive specialists handling any approach.

Keep people away, stage upwind and outside the isolation zone, request law enforcement and EOD support, avoid moving the material and follow ERG 112, shipping papers and incident command.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.