☣️ UN 2067 • CLASS 5

UN 2067 — Ammonium nitrate based fertilizer

Placard: Oxidizer. ERG Guide 140. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2067 is Ammonium nitrate based fertilizer, an ammonium nitrate fertilizer entry assigned to ERG Guide 140. It is not a fuel, but it can accelerate burning and may decompose violently when heated or contaminated.

Hazard overview: OXIDIZER/fertilizer material; can accelerate burning when involved in fire. May decompose violently or explosively when heated, confined, contaminated or involved in a large fire. Contamination with fuels, oils, organic materials, reducing agents or finely divided metals greatly increases hazard.

Response guidance: For a UN 2067 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 140. Establish incident command, isolate the area, stay upwind, control ignition or incompatibility hazards, prevent runoff or vapor spread and base entry/fire-control actions on monitoring and local SOP.

Firefighter training notes: Training for UN 2067 should emphasize oxidizer contamination control, large-fire evacuation, decomposition signs, water-flooding tactics, separation from fuels/organics and runoff control. Use ERG 140, SDS and local SOP.

Regulatory context: Ammonium nitrate based fertilizer is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting, waste handling and environmental requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Ammonium nitrate based fertilizer should be stored cool, dry and segregated from fuels, oils, organics, reducing agents, finely divided metals and combustible contamination. Avoid confinement, heat buildup and incompatible storage; follow fertilizer-specific fire code and SDS requirements.

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UN 2067 Quick Details

UN 2067
Product name: Ammonium nitrate based fertilizer
DOT Class: 5
Placard type: Oxidizer
ERG Guide: 140 (check current ERG)
Initial isolation: ERG 140: Initial isolation 100m in all directions. For large spills isolate 500m. Evacuate area and fight fire from maximum distance. If material involved in fire or exposed to direct flame, evacuate 800m radius.

Common Hazards of UN 2067

  • OXIDIZER/fertilizer material; can accelerate burning when involved in fire.
  • May decompose violently or explosively when heated, confined, contaminated or involved in a large fire.
  • Contamination with fuels, oils, organic materials, reducing agents or finely divided metals greatly increases hazard.
  • Decomposition may release toxic nitrogen oxides and ammonia-containing gases.
  • Runoff may carry nitrate contamination and create environmental hazards.
  • Containers or piles may rupture, burst or explode when heated.
  • Material itself is not a fuel, but it can make nearby combustible materials burn more intensely.

Chemical Identity & Physical Properties

White to grayish crystalline granules or prills, hygroscopic solid. Odorless or slight ammonia odor. Appears as pellets, granules, or prilled form at room temperature.

Also known asAmmonium nitrate fertilizerAN fertilizerNitramCalcium ammonium nitrateCAN fertilizerNitrogenous fertilizer
AppearanceWhite to grayish crystalline granules or prills, hygroscopic solid. Odorless or slight ammonia odor. Appears as pellets, granules, or prilled form at room temperature.
Flash PointNot applicable (oxidizing solid, non-flammable but supports combustion)
Boiling PointDecomposes at approximately 210C (410F) before boiling; releases toxic nitrogen oxides
Vapor DensityNot applicable (solid material)
Water ReactivityDissolves readily in water; no violent reaction but forms an exothermic solution. Contaminated runoff is a pollution hazard.
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2067

Extinguishing Media

Use flooding quantities of water from a protected distance for fire involving the material when safe. Do not use foam, dry chemical or smothering agents as the main tactic on burning ammonium nitrate fertilizer; remove contamination and combustibles if safe.

PPE Requirements

⚠️ Level B minimum recommended. SCBA with full protective clothing required for fire conditions. Avoid all skin and eye contact due to oxidizer properties.

Use positive-pressure SCBA and full protective clothing for fire, decomposition smoke or dust exposure. Avoid contaminated clothing/tools and keep fertilizer away from fuels or organic contamination.

Isolation & Evacuation

ERG 140: Initial isolation 100m in all directions. For large spills isolate 500m. Evacuate area and fight fire from maximum distance. If material involved in fire or exposed to direct flame, evacuate 800m radius.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 140).

First Actions for a UN 2067 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, gas, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Keep fuels, oils, organics, reducing agents and combustible contamination away from the fertilizer.
  • Do not touch damaged containers or spilled/released material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or release area and expand the perimeter for fire involvement, vapor spread, gas accumulation, cylinder heating or unknown product identity.
  • Use ERG Guide 140, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 2067 — Ammonium nitrate based fertilizer
HAZMAT RADIO NOTE — UN 2067 Product: Ammonium nitrate based fertilizer Class 5 / Oxidizer / ERG 140 PPE: Level B minimum recommended. SCBA with full protective clothing required for fire conditions. Avoid all skin and eye contact due to oxidizer properties. ISOLATION: ERG 140: Initial isolation 100m in all directions. For large spills isolate 500m. Evacuate area and fight fire from maximum distance. If material involved in fire or exposed to direct flame, evacuate 800m radius. ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2067 — Ammonium nitrate based fertilizer Class: 5 | Placard: Oxidizer | ERG Guide: 140 Appearance: White to grayish crystalline granules or prills, hygroscopic solid. Odorless or slight ammonia odor. Appears as pellets, granules, or prilled form at room temperature. Water Reactivity: Dissolves readily in water; no violent reaction but forms an exothermic solution. Contaminated runoff is a pollution hazard. Extinguishing: Use flooding quantities of water from a protected distance for fire involving the material when safe. Do not use foam, dry chemical or smothering agents as the main tactic on burning ammonium nitrate fertilizer; remove contamination and combustibles if safe. PPE: Level B minimum recommended. SCBA with full protective clothing required for fire conditions. Avoid all skin and eye contact due to oxidizer properties. Isolation: ERG 140: Initial isolation 100m in all directions. For large spills isolate 500m. Evacuate area and fight fire from maximum distance. If material involved in fire or exposed to direct flame, evacuate 800m radius. — Key Hazards — • OXIDIZER/fertilizer material; can accelerate burning when involved in fire. • May decompose violently or explosively when heated, confined, contaminated or involved in a large fire. • Contamination with fuels, oils, organic materials, reducing agents or finely divided metals greatly increases hazard. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, gas, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/ammonium-nitrate-based-fertilizer-un-2067 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2067 Ammonium nitrate based fertilizer Cls5 ERG140 | allfirefighter.com/hazmat/un/ammonium-nitrate-based-fertilizer-un-2067SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/ammonium-nitrate-based-fertilizer-un-2067

Related UN Numbers in Class 5

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2067

UN 2067 is Ammonium nitrate based fertilizer, a hazardous material assigned to ERG Guide 140.

No. It is not a fuel, but it can accelerate burning and may decompose violently if heated or contaminated.

ERG Guide 140 applies to UN 2067 for initial isolation, protective actions and first response guidance.

OXIDIZER/fertilizer material; can accelerate burning when involved in fire. May decompose violently or explosively when heated, confined, contaminated or involved in a large fire. Contamination with fuels, oils, organic materials, reducing agents or finely divided metals greatly increases hazard.

Use positive-pressure SCBA and full protective clothing for fire, decomposition smoke or dust exposure. Avoid contaminated clothing/tools and keep fertilizer away from fuels or organic contamination.

Large fires, confinement, heat and contamination with fuels, oils, organics or reducing agents can drive violent decomposition.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.