☣️ UN 0405 • CLASS 1

UN 0405 — Cartridges, signal

Placard: Explosive 1.4S. ERG Guide 114. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 0405 signal cartridges are small cylindrical pyrotechnic devices in metal or plastic casings designed to produce colored smoke, flame, or light signals, classified as Division 1.4S—the least hazardous explosive classification, indicating that any hazardous effects are largely confined to the package itself. Despite their low classification, these cartridges contain pyrotechnic compositions that can include water-reactive compounds and should be handled with appropriate precaution.

Hazard overview: UN 0405 cartridges present a localized deflagration and fire hazard; while mass detonation is not expected, burning cartridges can project burning stars or hot debris and may produce toxic combustion products from pyrotechnic compositions. Water-reactive components within the pyrotechnic fill can react violently if water is applied to actively burning cartridges.

Response guidance: ERG Guide 114 calls for an initial isolation of 25 meters in all directions; if cargo is involved in fire, increase isolation to 800 meters and evaluate the need for broader evacuation. Extinguish with dry chemical, sand, or smothering agents and strictly avoid water application on burning cartridges containing water-reactive pyrotechnic compounds.

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UN 0405 Quick Details

UN 0405
Product name: Cartridges, signal
DOT Class: 1
Placard type: Explosive 1.4S
ERG Guide: 114 (check current ERG)
Initial isolation: ERG 114: isolate 25m in all directions; if fire or cargo fire, isolate 800m and consider evacuation

Common Hazards of UN 0405

  • Minor blast or fire hazard — limited effect.
  • Localized burning or deflagration possible.
  • Smoke and heat from burning.
  • Low mass explosion risk under normal conditions.

Chemical Identity & Physical Properties

Signal cartridges are small solid-state devices at ambient temperature, constructed of metal or plastic casings enclosing pyrotechnic compositions formulated to emit colored smoke, flame, or light on activation.

Also known asSignal cartridgesPyrotechnic signal devicesFlare cartridgesDistress signal cartridges
AppearanceSmall cylindrical devices containing pyrotechnic compositions, typically metal or plastic cased. Designed to produce colored smoke, flame, or light signals. Solid at room temperature.
Flash PointNot applicable (pyrotechnic device)
Boiling PointNot applicable (pyrotechnic solid)
Vapor DensityNot applicable (solid device)
Water ReactivityMay contain water-reactive pyrotechnic compounds; avoid water contact during fire
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 0405

Extinguishing Media

Dry chemical, sand, or smothering agents preferred; avoid water on burning cartridges

PPE Requirements

⚠️ Structural firefighters' protective clothing and SCBA for fire conditions; eye and hand protection for handling

Structural firefighters' protective clothing with SCBA is required under fire conditions; eye protection and chemical-resistant gloves are the minimum for routine handling operations.

Isolation & Evacuation

ERG 114: isolate 25m in all directions; if fire or cargo fire, isolate 800m and consider evacuation
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 114).

First Actions for a UN 0405 Incident

  • CALL 911. Notify law enforcement.
  • Isolate area; keep unauthorized personnel away.
  • Stage upwind; eliminate ignition sources.
  • Request Hazmat + law enforcement.
  • Consult current ERG Guide 114 and follow SOP/SOG.
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📋 Copy & Share Field Card

UN 0405 — Cartridges, signal
HAZMAT RADIO NOTE — UN 0405 Product: Cartridges, signal Class 1 / Explosive 1.4S / ERG 114 PPE: Structural firefighters' protective clothing and SCBA for fire conditions; eye and hand protection for handling ISOLATION: ERG 114: isolate 25m in all directions; if fire or cargo fire, isolate 800m and consider evacuation ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0405 — Cartridges, signal Class: 1 | Placard: Explosive 1.4S | ERG Guide: 114 Appearance: Small cylindrical devices containing pyrotechnic compositions, typically metal or plastic cased. Designed to produce colored smoke, flame, or light signals. Solid at room temperature. Water Reactivity: May contain water-reactive pyrotechnic compounds; avoid water contact during fire Extinguishing: Dry chemical, sand, or smothering agents preferred; avoid water on burning cartridges PPE: Structural firefighters' protective clothing and SCBA for fire conditions; eye and hand protection for handling Isolation: ERG 114: isolate 25m in all directions; if fire or cargo fire, isolate 800m and consider evacuation — Key Hazards — • Minor blast or fire hazard — limited effect. • Localized burning or deflagration possible. • Smoke and heat from burning. — First Actions — • CALL 911. Notify law enforcement. • Isolate area; keep unauthorized personnel away. • Stage upwind; eliminate ignition sources. • Request Hazmat + law enforcement. SOURCE: allfirefighter.com/hazmat/un/cartridges-signal-un-0405 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN0405 Cartridges, signal Cls1 ERG114 | allfirefighter.com/hazmat/un/cartridges-signal-un-0405SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/cartridges-signal-un-0405

Related UN Numbers in Class 1

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 0405

UN 0405 carries a 1.4S classification, meaning hazardous effects are expected to be confined to the package under most scenarios, making it among the safest explosive classifications for transport, though standard explosive handling protocols still apply.

Mass detonation is not anticipated for Division 1.4S devices; however, individual cartridges can deflagrate and project burning debris or hot fragments, and bulk quantities in a cargo fire warrant an 800-meter isolation as a precaution.

Some signal cartridge compositions contain water-reactive pyrotechnic compounds such as magnesium-based fuels; applying water can trigger a reactive exothermic response, scatter burning material, and intensify the fire rather than extinguishing it.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.