☣️ UN 0491 • CLASS 1

UN 0491 — Charges, propelling

Placard: Explosive 1.4C. ERG Guide 114. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 0491 is Charges, propelling, a Class 1.4 propellant-related explosive entry assigned to ERG Guide 114. It presents a limited fire or deflagration hazard, but smoke, heat and nearby ammunition can increase scene risk.

Hazard overview: UN 0491 presents a limited propellant fire hazard. Heat or fire may cause localized deflagration, popping, fragments or smoke, especially if packages are damaged or quantities are larger than initially reported.

Response guidance: For a UN 0491 incident, responders should confirm the product using shipping papers, markings and ERG Guide 114. Isolate the area, keep personnel out of smoke, control ignition sources and expand the perimeter if fire involves additional ammunition or propellant.

Firefighter training notes: Training should emphasize the difference between limited-effect explosives and higher-hazard Class 1 materials. Common errors include standing too close to heated packages, dismissing smoke hazards, disturbing damaged articles and failing to check for adjacent explosives or ammunition.

Regulatory context: Charges, propelling is regulated as a Class 1 explosive hazardous material. Transportation, storage, quantity limits, fire code controls and reporting requirements may vary by jurisdiction. Responders should verify current requirements through shipping papers, SDS or product documents and applicable DOT, ATF, OSHA, NFPA, military, state or local authority guidance.

Storage & handling: Charges, propelling should be stored only in approved packaging, magazines or authorized explosive storage areas, separated from ignition sources, incompatible materials and unauthorized access. Packages should be protected from heat, impact, friction, moisture where relevant and physical damage according to product documentation and applicable explosive storage regulations.

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UN 0491 Quick Details

UN 0491
Product name: Charges, propelling
DOT Class: 1
Placard type: Explosive 1.4C
ERG Guide: 114 (check current ERG)
Initial isolation: ERG 114: isolate 500m all directions; if fire or damaged, evacuate 800m in all directions; treat as explosive hazard

Common Hazards of UN 0491

  • Limited fire and deflagration hazard from propellant or energetic material.
  • Localized burning, popping or fragment effects may occur if heated or damaged.
  • Smoke and heat from burning material may irritate the eyes and respiratory tract.
  • Low mass explosion risk under normal transport conditions for this division.
  • Heated packages may fail and scatter small articles or fragments.
  • Nearby ammunition, propellants or explosives may increase the overall incident hazard.

Chemical Identity & Physical Properties

Solid propellant material typically in bags, cartridges, or assembled charges. Often appears as cylindrical or granular forms in various colors (green, gray, or black) depending on composition. May contain nitrocellulose-based smokeless powder or composite propellants.

Also known asPropellant chargesGun propelling chargesPropelling charge assembliesArtillery propellant charges
AppearanceSolid propellant material typically in bags, cartridges, or assembled charges. Often appears as cylindrical or granular forms in various colors (green, gray, or black) depending on composition. May contain nitrocellulose-based smokeless powder or composite propellants.
Flash PointNot applicable (energetic material designed for combustion)
Boiling PointNot applicable (decomposes/deflagrates upon heating)
Vapor DensityNot applicable (solid propellant)
Water ReactivityNo significant reaction with water under normal conditions
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 0491

Extinguishing Media

Water spray, fog, dry chemical or CO2 may be appropriate for small or surrounding fires when directed by incident command; avoid close approach to heated articles.

PPE Requirements

⚠️ Structural firefighting gear with SCBA for smoke or fire exposure; maintain distance from heated packages or damaged articles.

Structural firefighting protective clothing with SCBA is appropriate for fire or smoke exposure, with distance maintained from heated packages. Approach and handling should follow incident command and local SOP.

Isolation & Evacuation

ERG 114: isolate 500m all directions; if fire or damaged, evacuate 800m in all directions; treat as explosive hazard
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 114).

First Actions for a UN 0491 Incident

  • CALL 911. Notify law enforcement if explosive articles, ordnance or blasting components are involved.
  • Keep unauthorized personnel away.
  • Stage upwind and avoid smoke from burning articles.
  • Eliminate ignition sources if it is safe to do so.
  • Isolate the area and expand the perimeter if fire grows or additional explosives are present.
  • Use ERG Guide 114, shipping papers and incident command for isolation and fire response decisions.
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📋 Copy & Share Field Card

UN 0491 — Charges, propelling
HAZMAT RADIO NOTE — UN 0491 Product: Charges, propelling Class 1 / Explosive 1.4C / ERG 114 PPE: Structural firefighting gear with SCBA for smoke or fire exposure; maintain distance from heated packages or damaged articles. ISOLATION: ERG 114: isolate 500m all directions; if fire or damaged, evacuate 800m in all directions; treat as explosive hazard ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0491 — Charges, propelling Class: 1 | Placard: Explosive 1.4C | ERG Guide: 114 Appearance: Solid propellant material typically in bags, cartridges, or assembled charges. Often appears as cylindrical or granular forms in various colors (green, gray, or black) depending on composition. May contain nitrocellulose-based smokeless powder or composite propellants. Water Reactivity: No significant reaction with water under normal conditions Extinguishing: Water spray, fog, dry chemical or CO2 may be appropriate for small or surrounding fires when directed by incident command; avoid close approach to heated articles. PPE: Structural firefighting gear with SCBA for smoke or fire exposure; maintain distance from heated packages or damaged articles. Isolation: ERG 114: isolate 500m all directions; if fire or damaged, evacuate 800m in all directions; treat as explosive hazard — Key Hazards — • Limited fire and deflagration hazard from propellant or energetic material. • Localized burning, popping or fragment effects may occur if heated or damaged. • Smoke and heat from burning material may irritate the eyes and respiratory tract. — First Actions — • CALL 911. Notify law enforcement if explosive articles, ordnance or blasting components are involved. • Keep unauthorized personnel away. • Stage upwind and avoid smoke from burning articles. • Eliminate ignition sources if it is safe to do so. SOURCE: allfirefighter.com/hazmat/un/charges-propelling-un-0491 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN0491 Charges, propelling Cls1 ERG114 | allfirefighter.com/hazmat/un/charges-propelling-un-0491SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/charges-propelling-un-0491

Related UN Numbers in Class 1

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 0491

UN 0491 is Charges, propelling, a Class 1 explosive entry assigned to ERG Guide 114.

Not normally when transported as classified, but fire can still cause localized deflagration, fragments, smoke or small projectiles.

ERG Guide 114 applies to UN 0491 and should be used for initial isolation, evacuation and first response decisions.

The main hazards are blast or projection effects, fragmentation, fire involvement, heat or shock sensitivity and secondary smoke or debris hazards.

PPE depends on division, fire involvement and product condition. Structural gear with SCBA may protect from smoke or fire exposure, but distance, cover, isolation and specialist explosive support are the key controls.

Keep people away, stage upwind and outside the isolation zone, avoid moving the material, request law enforcement or EOD support when appropriate and follow ERG 114, shipping papers and incident command.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.