☣️ UN 2720 • CLASS 5

UN 2720 — Chromium nitrate

Placard: Oxidizer. ERG Guide 141. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Chromium nitrate is an oxidizing chromium salt, often encountered as hydrated crystals. It can accelerate burning and create contaminated runoff.

Hazard overview: Chromium nitrate is an oxidizing solid. The main fire problem is intensification of burning when it contacts fuels or combustible contamination.

Response guidance: Remove combustibles from the area, keep contaminated runoff contained and cool exposed containers from a protected location. Do not let product mix with oils, fuels or organics.

Firefighter training notes: Train crews to identify Chromium nitrate by UN number, placard, ERG guide and SDS before choosing entry, isolation or extinguishment tactics.

Regulatory context: Use UN 2720, ERG 141, SDS, container labels and shipping papers to confirm the exact hazard profile and protective action distances.

Storage & handling: Store in closed, compatible containers away from heat, ignition sources and incompatible materials; keep the area ventilated and protected from damage.

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UN 2720 Quick Details

UN 2720
Product name: Chromium nitrate
DOT Class: 5
Placard type: Oxidizer
ERG Guide: 141 (check current ERG)
Initial isolation: ERG 141: isolate spill 25-50m all directions. If fire or large spill, initial isolation 100m, protective action distance 300m downwind.

Common Hazards of UN 2720

  • Oxidizer; it can intensify fire even though the material itself is not fuel.
  • Contact with combustibles, organics, oils, fuels or reducing agents may cause ignition or rapid burning.
  • Fire may produce irritating and toxic fumes.
  • Dust or solution contact may irritate skin, eyes and respiratory tract.
  • Runoff can carry toxic metal or oxidizing contamination into waterways.
  • Containers exposed to heat may rupture.
  • Contamination can make the material unstable or more reactive.

Chemical Identity & Physical Properties

Purple to violet hygroscopic crystalline solid; commonly encountered as a hydrate and odorless.

Also known asChromic nitrateChromium(III) nitrateChromium trinitrateNitric acid chromium(III) salt
CAS Number13548-38-4
AppearancePurple to violet crystalline solid or hygroscopic crystals. May be encountered as nonahydrate form. Odorless.
Flash PointNot applicable (oxidizing solid)
Boiling PointDecomposes at 100-125C (212-257F)
Vapor DensityNot applicable (solid)
Water ReactivitySoluble in water with heat release during dissolution
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2720

Extinguishing Media

Dry chemical or CO2 for surrounding fires; water fog for cooling containers

PPE Requirements

⚠️ Use SCBA for fire or dust conditions with chemical-resistant gloves, eye protection and protective clothing.

Use SCBA for fire or dust conditions with chemical-resistant gloves, eye protection and protective clothing.

Isolation & Evacuation

ERG 141: isolate spill 25-50m all directions. If fire or large spill, initial isolation 100m, protective action distance 300m downwind.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 141).

First Actions for a UN 2720 Incident

  • Call 911 and the emergency response number shown on shipping papers or container documents.
  • Keep unauthorized personnel away and establish an initial isolation perimeter.
  • Stay upwind, uphill and upstream; avoid low areas where vapors or runoff may collect.
  • Avoid breathing vapors, dust, smoke or mist and prevent skin and eye contact.
  • Keep combustibles, fuels, organic material, oils and reducing agents away from the release area.
  • Do not touch damaged containers or spilled material without appropriate chemical PPE.
  • Ventilate confined spaces only when personnel are trained, monitored and properly equipped.
  • Use ERG guidance, SDS, shipping papers and air monitoring before committing crews.
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📋 Copy & Share Field Card

UN 2720 — Chromium nitrate
HAZMAT RADIO NOTE — UN 2720 Product: Chromium nitrate Class 5 / Oxidizer / ERG 141 PPE: Use SCBA for fire or dust conditions with chemical-resistant gloves, eye protection and protective clothing. ISOLATION: ERG 141: isolate spill 25-50m all directions. If fire or large spill, initial isolation 100m, protective action distance 300m downwind. ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2720 — Chromium nitrate Class: 5 | Placard: Oxidizer | ERG Guide: 141 Appearance: Purple to violet crystalline solid or hygroscopic crystals. May be encountered as nonahydrate form. Odorless. Water Reactivity: Soluble in water with heat release during dissolution Extinguishing: Dry chemical or CO2 for surrounding fires; water fog for cooling containers PPE: Use SCBA for fire or dust conditions with chemical-resistant gloves, eye protection and protective clothing. Isolation: ERG 141: isolate spill 25-50m all directions. If fire or large spill, initial isolation 100m, protective action distance 300m downwind. — Key Hazards — • Oxidizer; it can intensify fire even though the material itself is not fuel. • Contact with combustibles, organics, oils, fuels or reducing agents may cause ignition or rapid burning. • Fire may produce irritating and toxic fumes. — First Actions — • Call 911 and the emergency response number shown on shipping papers or container documents. • Keep unauthorized personnel away and establish an initial isolation perimeter. • Stay upwind, uphill and upstream; avoid low areas where vapors or runoff may collect. • Avoid breathing vapors, dust, smoke or mist and prevent skin and eye contact. SOURCE: allfirefighter.com/hazmat/un/chromium-nitrate-un-2720 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2720 Chromium nitrate Cls5 ERG141 | allfirefighter.com/hazmat/un/chromium-nitrate-un-2720SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/chromium-nitrate-un-2720

Related UN Numbers in Class 5

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2720

No. It is an oxidizer that can intensify burning of other materials.

Keep fuels, oils, paper, wood, organics and reducing agents away from the material.

Runoff may carry chromium compounds and oxidizing salts into drains or waterways.

Water fog may cool containers, but avoid uncontrolled contact or runoff unless response guidance allows it.

SCBA for fire or dust with chemical-resistant gloves, eye and skin protection.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.