☣️ UN 0118 • CLASS 1

UN 0118 — Hexolite; Hexotol

Placard: Explosive 1.1D. ERG Guide 112. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 0118 identifies Hexolite and Hexotol, a military-grade RDX/TNT composite explosive classified as a Division 1.1D mass explosion hazard. The entire load may detonate simultaneously when exposed to heat, shock, or friction, making this one of the most dangerous materials encountered in transport emergencies.

Hazard overview: UN 0118 presents a mass explosion hazard with the potential for simultaneous detonation of the entire load, producing severe blast overpressure and high-velocity fragmentation. The composition is sensitive to heat, mechanical shock, and friction, meaning that firefighting efforts or physical contact can trigger catastrophic detonation.

Response guidance: If UN 0118 is involved in a fire or exposed to heat, evacuate all personnel a minimum of 1,600 meters in all directions immediately and do not attempt suppression. Isolation of at least 500 meters in all directions is required at all times, and no personnel should approach the material under any circumstances if detonation is possible.

Advertisement

UN 0118 Quick Details

UN 0118
Product name: Hexolite; Hexotol
DOT Class: 1
Placard type: Explosive 1.1D
ERG Guide: 112 (check current ERG)
Initial isolation: ERG 112: isolate 500m minimum all directions. Evacuate 1600m in all directions if material is on fire or exposed to heat. Mass explosion hazard — do not approach.

Common Hazards of UN 0118

  • Mass explosion hazard — entire load may detonate simultaneously.
  • Severe blast overpressure and fragmentation.
  • Sensitive to heat, shock, and friction.
  • Secondary fire and debris hazard.

Chemical Identity & Physical Properties

UN 0118 Hexolite appears as a pale yellow to tan granular or pressed solid explosive composition with no odor or a faint aromatic smell that remains solid at room temperature.

Also known asHexoliteHexotolRDX/TNT mixtureComposition B variantHexogen-TNT explosive
AppearancePale yellow to tan granular or pressed solid explosive composition. Odorless or faint aromatic odor. Remains solid at room temperature.
Flash PointNot applicable (explosive solid)
Boiling PointNot applicable (decomposes violently upon heating)
Vapor DensityNot applicable (solid)
Water ReactivityNo significant reaction with water, but water should not be used for fire suppression
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 0118

Extinguishing Media

DO NOT use water, foam, or CO2. Fighting fire may cause detonation. Evacuate area immediately if involved in fire.

PPE Requirements

⚠️ Full structural firefighting gear with SCBA required if approach is absolutely necessary. Level A with blast-resistant cover strongly recommended.

Full structural firefighting gear with SCBA is the minimum required if approach is absolutely necessary, though Level A protection with blast-resistant cover is strongly recommended for any personnel near UN 0118.

Isolation & Evacuation

ERG 112: isolate 500m minimum all directions. Evacuate 1600m in all directions if material is on fire or exposed to heat. Mass explosion hazard — do not approach.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 112).

First Actions for a UN 0118 Incident

  • CALL 911. Then call emergency response telephone number on shipping paper.
  • Establish large isolation zone — minimum 500 meters in all directions.
  • Stage upwind, uphill; limit personnel to essential responders only.
  • Request Hazmat + law enforcement + additional resources immediately.
  • Do not fight fire — evacuate and isolate; let burn if no life safety risk.
  • Protect exposures only if safe and directed by command.
  • Consult current ERG Guide 112 and follow SOP/SOG.
Advertisement

📋 Copy & Share Field Card

UN 0118 — Hexolite; Hexotol
HAZMAT RADIO NOTE — UN 0118 Product: Hexolite; Hexotol Class 1 / Explosive 1.1D / ERG 112 PPE: Full structural firefighting gear with SCBA required if approach is absolutely necessary. Level A with blast-resistant cover strongly recommended. ISOLATION: ERG 112: isolate 500m minimum all directions. Evacuate 1600m in all directions if material is on fire or exposed to heat. Mass explosion hazard — do not approach. ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0118 — Hexolite; Hexotol Class: 1 | Placard: Explosive 1.1D | ERG Guide: 112 Appearance: Pale yellow to tan granular or pressed solid explosive composition. Odorless or faint aromatic odor. Remains solid at room temperature. Water Reactivity: No significant reaction with water, but water should not be used for fire suppression Extinguishing: DO NOT use water, foam, or CO2. Fighting fire may cause detonation. Evacuate area immediately if involved in fire. PPE: Full structural firefighting gear with SCBA required if approach is absolutely necessary. Level A with blast-resistant cover strongly recommended. Isolation: ERG 112: isolate 500m minimum all directions. Evacuate 1600m in all directions if material is on fire or exposed to heat. Mass explosion hazard — do not approach. — Key Hazards — • Mass explosion hazard — entire load may detonate simultaneously. • Severe blast overpressure and fragmentation. • Sensitive to heat, shock, and friction. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. • Establish large isolation zone — minimum 500 meters in all directions. • Stage upwind, uphill; limit personnel to essential responders only. • Request Hazmat + law enforcement + additional resources immediately. SOURCE: allfirefighter.com/hazmat/un/hexolite-hexotol-un-0118 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN0118 Hexolite; Hexotol Cls1 ERG112 | allfirefighter.com/hazmat/un/hexolite-hexotol-un-0118SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/hexolite-hexotol-un-0118

Related UN Numbers in Class 1

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

Frequently Asked Questions about UN 0118

UN 0118 Hexolite is classified as a Division 1.1D explosive, meaning it poses a mass explosion hazard rather than a simple flammability risk, and the entire load can detonate simultaneously when exposed to heat, shock, or friction.

At minimum, full structural firefighting gear with SCBA is required if approach is absolutely necessary, but Level A protection with blast-resistant cover is strongly recommended for any personnel responding to a UN 0118 incident.

ERG Guide 112 requires isolating a minimum of 500 meters in all directions at all times, and if UN 0118 Hexolite is on fire or exposed to heat, all persons must be evacuated at least 1,600 meters in all directions immediately.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.