☣️ UN 0340 • CLASS 1

UN 0340 — Nitrocellulose, dry

Placard: Explosive 1.1D. ERG Guide 112. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 0340 is dry nitrocellulose classified as a Class 1.1D explosive, meaning the entire load presents a mass explosion hazard capable of simultaneous detonation with devastating blast overpressure and fragmentation effects. This white to slightly yellow fibrous or cottony solid is highly flammable and shock-sensitive when dry, making it one of the most hazardous materials encountered in transport incidents.

Hazard overview: Dry nitrocellulose under UN 0340 can detonate as a mass explosion, generating severe blast overpressure and high-velocity fragmentation that endangers responders and the public across a wide radius. Its extreme sensitivity to heat, friction, and shock requires that all ignition sources and mechanical disturbance be eliminated immediately upon identification.

Response guidance: ERG Guide 112 mandates a 500-meter all-direction isolation immediately, with evacuation extending to 1,600 meters downwind if material is on fire; mass evacuation should be considered for large quantities. Only water fog applied from maximum standoff distance is appropriate for fire suppression — CO2 and dry chemical are ineffective on bulk fires of this material.

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UN 0340 Quick Details

UN 0340
Product name: Nitrocellulose, dry
DOT Class: 1
Placard type: Explosive 1.1D
ERG Guide: 112 (check current ERG)
Initial isolation: ERG 112: isolate 500m all directions initially; evacuate 1600m downwind if fire; consider mass evacuation for large quantities

Common Hazards of UN 0340

  • Mass explosion hazard — entire load may detonate simultaneously.
  • Severe blast overpressure and fragmentation.
  • Sensitive to heat, shock, and friction.
  • Secondary fire and debris hazard.

Chemical Identity & Physical Properties

UN 0340 dry nitrocellulose appears as a white to slightly yellow fibrous solid or cottony mass, odorless or with a faint ether-like odor, and is dangerously flammable and explosive in its dry state.

Also known asCellulose nitrateGuncottonPyroxylinCollodion cottonFlash paper
CAS Number9004-70-0
AppearanceWhite to slightly yellow fibrous solid or cottony mass. Odorless or slight ether-like odor. Highly flammable and explosive when dry.
Flash PointNot applicable (explosive solid)
Boiling PointNot applicable (decomposes explosively)
Vapor DensityNot applicable (solid)
Water ReactivityNo significant reaction with water, but wetting with water or alcohol is used as stabilizer to reduce explosion hazard
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 0340

Extinguishing Media

Water fog only from distance; do not use CO2 or dry chemical on bulk fires

PPE Requirements

⚠️ Level A minimum for explosive materials; full structural firefighting gear with SCBA; avoid all ignition sources and friction

Level A minimum protection with full structural firefighting gear and SCBA is required; eliminate all ignition sources and avoid any friction or impact with the material.

Isolation & Evacuation

ERG 112: isolate 500m all directions initially; evacuate 1600m downwind if fire; consider mass evacuation for large quantities
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 112).

First Actions for a UN 0340 Incident

  • CALL 911. Then call emergency response telephone number on shipping paper.
  • Establish large isolation zone — minimum 500 meters in all directions.
  • Stage upwind, uphill; limit personnel to essential responders only.
  • Request Hazmat + law enforcement + additional resources immediately.
  • Do not fight fire — evacuate and isolate; let burn if no life safety risk.
  • Protect exposures only if safe and directed by command.
  • Consult current ERG Guide 112 and follow SOP/SOG.
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📋 Copy & Share Field Card

UN 0340 — Nitrocellulose, dry
HAZMAT RADIO NOTE — UN 0340 Product: Nitrocellulose, dry Class 1 / Explosive 1.1D / ERG 112 PPE: Level A minimum for explosive materials; full structural firefighting gear with SCBA; avoid all ignition sources and friction ISOLATION: ERG 112: isolate 500m all directions initially; evacuate 1600m downwind if fire; consider mass evacuation for large quantities ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0340 — Nitrocellulose, dry Class: 1 | Placard: Explosive 1.1D | ERG Guide: 112 Appearance: White to slightly yellow fibrous solid or cottony mass. Odorless or slight ether-like odor. Highly flammable and explosive when dry. Water Reactivity: No significant reaction with water, but wetting with water or alcohol is used as stabilizer to reduce explosion hazard Extinguishing: Water fog only from distance; do not use CO2 or dry chemical on bulk fires PPE: Level A minimum for explosive materials; full structural firefighting gear with SCBA; avoid all ignition sources and friction Isolation: ERG 112: isolate 500m all directions initially; evacuate 1600m downwind if fire; consider mass evacuation for large quantities — Key Hazards — • Mass explosion hazard — entire load may detonate simultaneously. • Severe blast overpressure and fragmentation. • Sensitive to heat, shock, and friction. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. • Establish large isolation zone — minimum 500 meters in all directions. • Stage upwind, uphill; limit personnel to essential responders only. • Request Hazmat + law enforcement + additional resources immediately. SOURCE: allfirefighter.com/hazmat/un/nitrocellulose-dry-un-0340 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN0340 Nitrocellulose, dry Cls1 ERG112 | allfirefighter.com/hazmat/un/nitrocellulose-dry-un-0340SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/nitrocellulose-dry-un-0340

Related UN Numbers in Class 1

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 0340

Yes. UN 0340 is Class 1.1D, meaning the entire shipment can detonate simultaneously. This distinguishes it from lower-division nitrocellulose and demands the most aggressive isolation and evacuation measures.

Wetting dry nitrocellulose with water or alcohol significantly reduces its sensitivity and explosion hazard. This is why wetted nitrocellulose is assigned separate, lower-hazard UN numbers compared to dry UN 0340.

Water fog applied from a safe standoff distance is the only recommended agent for bulk UN 0340 fires. CO2 and dry chemical are not effective at controlling large fires involving this material.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.