☣️ UN 0146 • CLASS 1

UN 0146 — Nitrostarch, dry or wetted

Placard: Explosive 1.1D. ERG Guide 112. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 0146 is Nitrostarch, dry or wetted, a Class 1 explosive substance assigned to ERG Guide 112. It is shipped wetted or desensitized to reduce sensitivity, but it can become much more dangerous if it dries, heats or is contaminated.

Hazard overview: UN 0146 presents a mass explosion hazard if initiated. The wetting or desensitizing liquid reduces sensitivity during normal transport, but drying, fire exposure, shock, friction or contamination can increase detonation risk. Damaged, leaking or drying material should be treated as extremely hazardous.

Response guidance: For a UN 0146 incident, responders should verify the product and wetting/desensitizing condition using shipping papers, package markings, SDS and ERG Guide 112. Establish isolation, deny entry, request EOD or explosive specialist support and withdraw immediately if fire, drying or package damage is suspected.

Firefighter training notes: Training should emphasize recognizing Class 1 explosive placards, establishing command early, using standoff distance, denying entry and requesting bomb squad or EOD support. Common tactical errors include approaching packages for identification, moving damaged items, fighting fire too close and underestimating fragmentation distance. Use ERG 112, shipping papers and local explosive incident SOP.

Regulatory context: Nitrostarch, dry or wetted is regulated as a Class 1 explosive hazardous material. Transport, storage, reporting and scene-control requirements may involve DOT, ATF, OSHA, military, state or local authorities depending on ownership and quantity. Responders should verify requirements through shipping papers, facility documents, law enforcement and current regulations.

Storage & handling: Nitrostarch, dry or wetted should be stored only in approved explosive magazines or authorized storage areas, separated from ignition sources, incompatible materials and unauthorized access. Packages should be protected from heat, impact, friction, moisture where relevant and physical damage according to product documentation and applicable explosive storage regulations.

Advertisement

UN 0146 Quick Details

UN 0146
Product name: Nitrostarch, dry or wetted
DOT Class: 1
Placard type: Explosive 1.1D
ERG Guide: 112 (check current ERG)
Initial isolation: ERG 112: isolate 500m minimum all directions; evacuate 1600m if fire or if dry material involved; treat as mass explosion hazard

Common Hazards of UN 0146

  • Mass explosion hazard; the entire load may detonate simultaneously if initiated.
  • Severe blast overpressure, fragmentation and debris may extend far beyond the immediate container or vehicle.
  • Explosive articles or substances may be sensitive to heat, shock, friction, impact or fire exposure.
  • Fire involving the material can transition rapidly to detonation without reliable warning.
  • Secondary fires, projectiles and container fragments may create hazards after an initial event.
  • Smoke from fire may contain irritating or toxic combustion products.

Chemical Identity & Physical Properties

White to yellowish powder or granular solid, odorless or slight ester-like odor. Appears similar to ordinary starch but is highly explosive.

Also known asStarch nitrateNitrated starchExplosive starchStarch dinitrate
AppearanceWhite to yellowish powder or granular solid, odorless or slight ester-like odor. Appears similar to ordinary starch but is highly explosive.
Flash PointNot applicable (explosive solid)
Boiling PointNot applicable (decomposes explosively before boiling)
Vapor DensityNot applicable (solid)
Water ReactivityMay be wetted with water for transport safety; wetting reduces sensitivity but material remains explosive
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 0146

Extinguishing Media

Do not fight fire involving explosives at close range. Use unmanned master streams or remote cooling only if directed by incident command and safe under local SOP.

PPE Requirements

⚠️ No standard PPE protects against blast and fragmentation. Use distance, cover, evacuation, SCBA for smoke exposure and EOD/bomb squad support for any approach.

For UN 0146, distance, cover and evacuation are more important than close-range PPE. Structural firefighting gear and SCBA may be used only for remote exposure protection or support roles; direct approach or handling should be limited to qualified EOD or explosive specialists under incident command.

Isolation & Evacuation

ERG 112: isolate 500m minimum all directions; evacuate 1600m if fire or if dry material involved; treat as mass explosion hazard
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 112).

First Actions for a UN 0146 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away and deny entry to the hazard area.
  • Stage responders upwind, uphill and outside the recommended isolation distance.
  • Request law enforcement, bomb squad or EOD, hazmat and additional command resources immediately.
  • Do not handle, move or disturb explosive articles unless directed by qualified explosive ordnance personnel.
  • Do not fight fire involving explosives at close range; withdraw and protect life safety first.
  • Protect exposures only from a safe, remote position if directed by incident command and local SOP.
  • Use ERG Guide 112, shipping papers and incident command to set isolation and evacuation distances.
Advertisement

📋 Copy & Share Field Card

UN 0146 — Nitrostarch, dry or wetted
HAZMAT RADIO NOTE — UN 0146 Product: Nitrostarch, dry or wetted Class 1 / Explosive 1.1D / ERG 112 PPE: No standard PPE protects against blast and fragmentation. Use distance, cover, evacuation, SCBA for smoke exposure and EOD/bomb squad support for any approach. ISOLATION: ERG 112: isolate 500m minimum all directions; evacuate 1600m if fire or if dry material involved; treat as mass explosion hazard ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0146 — Nitrostarch, dry or wetted Class: 1 | Placard: Explosive 1.1D | ERG Guide: 112 Appearance: White to yellowish powder or granular solid, odorless or slight ester-like odor. Appears similar to ordinary starch but is highly explosive. Water Reactivity: May be wetted with water for transport safety; wetting reduces sensitivity but material remains explosive Extinguishing: Do not fight fire involving explosives at close range. Use unmanned master streams or remote cooling only if directed by incident command and safe under local SOP. PPE: No standard PPE protects against blast and fragmentation. Use distance, cover, evacuation, SCBA for smoke exposure and EOD/bomb squad support for any approach. Isolation: ERG 112: isolate 500m minimum all directions; evacuate 1600m if fire or if dry material involved; treat as mass explosion hazard — Key Hazards — • Mass explosion hazard; the entire load may detonate simultaneously if initiated. • Severe blast overpressure, fragmentation and debris may extend far beyond the immediate container or vehicle. • Explosive articles or substances may be sensitive to heat, shock, friction, impact or fire exposure. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away and deny entry to the hazard area. • Stage responders upwind, uphill and outside the recommended isolation distance. • Request law enforcement, bomb squad or EOD, hazmat and additional command resources immediately. SOURCE: allfirefighter.com/hazmat/un/nitrostarch-dry-or-wetted-un-0146 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN0146 Nitrostarch, dry or wetted Cls1 ERG112 | allfirefighter.com/hazmat/un/nitrostarch-dry-or-wetted-un-0146SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/nitrostarch-dry-or-wetted-un-0146

Related UN Numbers in Class 1

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

Frequently Asked Questions about UN 0146

UN 0146 is Nitrostarch, dry or wetted, a Class 1 explosive assigned to ERG Guide 112.

Yes. UN 0146 should be treated as capable of severe blast and fragmentation; some conditions may allow the entire load to detonate.

ERG Guide 112 applies to UN 0146 and should be used for initial isolation, evacuation and first response decisions.

The main hazards are blast overpressure, fragmentation, fire involvement, shock or heat sensitivity and secondary debris or smoke hazards.

No standard firefighter PPE protects against a close-range detonation. Responders should use distance, cover and evacuation, with EOD or explosive specialists handling any approach.

Keep people away, stage upwind and outside the isolation zone, request law enforcement and EOD support, avoid moving the material and follow ERG 112, shipping papers and incident command.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.