☣️ UN 0146 • CLASS 1

UN 0146 — Nitrostarch, dry or wetted

Placard: Explosive 1.1D. ERG Guide 112. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 0146, Nitrostarch, is a highly explosive solid classified as Class 1.1D, capable of mass detonation of an entire load simultaneously under heat, shock, or friction. Emergency responders must treat any incident involving this material as a potential mass explosion event and maintain safe distances at all times.

Hazard overview: UN 0146 Nitrostarch presents a mass explosion hazard with severe blast overpressure and fragmentation capable of affecting a wide area simultaneously. The material is sensitive to heat, shock, and friction, meaning even wetted transport forms remain explosive and must be handled with extreme caution.

Response guidance: Per ERG Guide 112, responders must isolate a minimum of 500 meters in all directions and evacuate at least 1600 meters if fire is present or if dry Nitrostarch is involved. Water may be applied from a safe distance to cool unexploded material, but no foam, CO2, or dry chemical agents should be used on burning explosive material.

Advertisement

UN 0146 Quick Details

UN 0146
Product name: Nitrostarch, dry or wetted
DOT Class: 1
Placard type: Explosive 1.1D
ERG Guide: 112 (check current ERG)
Initial isolation: ERG 112: isolate 500m minimum all directions; evacuate 1600m if fire or if dry material involved; treat as mass explosion hazard

Common Hazards of UN 0146

  • Mass explosion hazard — entire load may detonate simultaneously.
  • Severe blast overpressure and fragmentation.
  • Sensitive to heat, shock, and friction.
  • Secondary fire and debris hazard.

Chemical Identity & Physical Properties

UN 0146 Nitrostarch appears as a white to yellowish powder or granular solid with no odor or a faint ester-like odor, closely resembling ordinary starch in appearance despite being highly explosive.

Also known asStarch nitrateNitrated starchExplosive starchStarch dinitrate
AppearanceWhite to yellowish powder or granular solid, odorless or slight ester-like odor. Appears similar to ordinary starch but is highly explosive.
Flash PointNot applicable (explosive solid)
Boiling PointNot applicable (decomposes explosively before boiling)
Vapor DensityNot applicable (solid)
Water ReactivityMay be wetted with water for transport safety; wetting reduces sensitivity but material remains explosive
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 0146

Extinguishing Media

Water only for cooling unexploded material from distance; no foam, CO2, or dry chemical on burning explosive

PPE Requirements

⚠️ Level A with blast-resistant gear if approaching; full structural firefighting gear minimum for fire; SCBA mandatory; withdraw immediately if fire involves explosive

Responders approaching UN 0146 must wear Level A protection with blast-resistant gear at minimum, with SCBA mandatory and full structural firefighting gear required for any fire scenario, with immediate withdrawal ordered if explosives are directly involved in fire.

Isolation & Evacuation

ERG 112: isolate 500m minimum all directions; evacuate 1600m if fire or if dry material involved; treat as mass explosion hazard
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 112).

First Actions for a UN 0146 Incident

  • CALL 911. Then call emergency response telephone number on shipping paper.
  • Establish large isolation zone — minimum 500 meters in all directions.
  • Stage upwind, uphill; limit personnel to essential responders only.
  • Request Hazmat + law enforcement + additional resources immediately.
  • Do not fight fire — evacuate and isolate; let burn if no life safety risk.
  • Protect exposures only if safe and directed by command.
  • Consult current ERG Guide 112 and follow SOP/SOG.
Advertisement

📋 Copy & Share Field Card

UN 0146 — Nitrostarch, dry or wetted
HAZMAT RADIO NOTE — UN 0146 Product: Nitrostarch, dry or wetted Class 1 / Explosive 1.1D / ERG 112 PPE: Level A with blast-resistant gear if approaching; full structural firefighting gear minimum for fire; SCBA mandatory; withdraw immediately if fire involves explosive ISOLATION: ERG 112: isolate 500m minimum all directions; evacuate 1600m if fire or if dry material involved; treat as mass explosion hazard ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0146 — Nitrostarch, dry or wetted Class: 1 | Placard: Explosive 1.1D | ERG Guide: 112 Appearance: White to yellowish powder or granular solid, odorless or slight ester-like odor. Appears similar to ordinary starch but is highly explosive. Water Reactivity: May be wetted with water for transport safety; wetting reduces sensitivity but material remains explosive Extinguishing: Water only for cooling unexploded material from distance; no foam, CO2, or dry chemical on burning explosive PPE: Level A with blast-resistant gear if approaching; full structural firefighting gear minimum for fire; SCBA mandatory; withdraw immediately if fire involves explosive Isolation: ERG 112: isolate 500m minimum all directions; evacuate 1600m if fire or if dry material involved; treat as mass explosion hazard — Key Hazards — • Mass explosion hazard — entire load may detonate simultaneously. • Severe blast overpressure and fragmentation. • Sensitive to heat, shock, and friction. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. • Establish large isolation zone — minimum 500 meters in all directions. • Stage upwind, uphill; limit personnel to essential responders only. • Request Hazmat + law enforcement + additional resources immediately. SOURCE: allfirefighter.com/hazmat/un/0146 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN0146 Nitrostarch, dry or wetted Cls1 ERG112 | allfirefighter.com/hazmat/un/0146SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/nitrostarch-dry-or-wetted-un-0146

Related UN Numbers in Class 1

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

Frequently Asked Questions about UN 0146

UN 0146 Nitrostarch is classified as a Class 1.1D explosive, meaning it poses a mass explosion hazard capable of detonating an entire load simultaneously, which is far more dangerous than ordinary flammable materials.

ERG Guide 112 requires a minimum isolation distance of 500 meters in all directions, expanding to an evacuation of at least 1600 meters if fire is present or if dry Nitrostarch is involved.

Responders must use Level A protection with blast-resistant gear when approaching UN 0146, with SCBA mandatory at all times and full structural firefighting gear as the absolute minimum for any fire-related scenario.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.