☣️ UN 0411 • CLASS 1

UN 0411 — PETN, with not less than 7% wax

Placard: Explosive 1.1D. ERG Guide 112. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 0411 is pentaerythritol tetranitrate (PETN) desensitized with not less than 7% wax, classified as Explosive 1.1D. The wax coating reduces initiation sensitivity, but the material retains a mass explosion hazard under fire or shock conditions.

Hazard overview: UN 0411 presents a mass explosion risk in which the entire shipment can detonate simultaneously, generating severe blast overpressure and fragmentation. The addition of wax lowers shock sensitivity but does not eliminate the explosive hazard under fire exposure or strong initiation stimulus.

Response guidance: Responders must isolate a minimum of 500 meters in all directions and evacuate 1600 meters downwind if fire is involved. Water and foam must not be used, as they can increase mass and shock sensitivity; withdrawal rather than active firefighting is strongly preferred.

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UN 0411 Quick Details

UN 0411
Product name: PETN, with not less than 7% wax
DOT Class: 1
Placard type: Explosive 1.1D
ERG Guide: 112 (check current ERG)
Initial isolation: ERG 112: isolate 500m minimum all directions; evacuate 1600m downwind if fire; consider withdrawal rather than firefighting; mass detonation risk

Common Hazards of UN 0411

  • Mass explosion hazard — entire load may detonate simultaneously.
  • Severe blast overpressure and fragmentation.
  • Sensitive to heat, shock, and friction.
  • Secondary fire and debris hazard.

Chemical Identity & Physical Properties

UN 0411 appears as a white odorless crystalline powder or granular solid, desensitized with wax to form a less impact-sensitive mixture suitable for controlled transport.

Also known asPentaerythritol tetranitratePenthritePETNNitropentaPentrite
CAS Number78-11-5
AppearanceWhite crystalline powder or granular solid, odorless. Desensitized with wax to reduce sensitivity to initiation.
Flash PointNot applicable (explosive solid)
Boiling PointNot applicable (decomposes explosively at 205-215C)
Vapor DensityNot applicable (solid)
Water ReactivityNo significant reaction with water, insoluble
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 0411

Extinguishing Media

Do not use water or foam — increases mass and shock sensitivity. Use distance and protective shielding.

PPE Requirements

⚠️ Level A required for fire involvement; structural firefighting gear inadequate; SCBA mandatory; minimum approach distance; no direct contact with material

Level A protection is required when fire is involved; structural firefighting gear is inadequate, SCBA is mandatory, and no direct contact with the material should occur under any circumstances.

Isolation & Evacuation

ERG 112: isolate 500m minimum all directions; evacuate 1600m downwind if fire; consider withdrawal rather than firefighting; mass detonation risk
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 112).

First Actions for a UN 0411 Incident

  • CALL 911. Then call emergency response telephone number on shipping paper.
  • Establish large isolation zone — minimum 500 meters in all directions.
  • Stage upwind, uphill; limit personnel to essential responders only.
  • Request Hazmat + law enforcement + additional resources immediately.
  • Do not fight fire — evacuate and isolate; let burn if no life safety risk.
  • Protect exposures only if safe and directed by command.
  • Consult current ERG Guide 112 and follow SOP/SOG.
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📋 Copy & Share Field Card

UN 0411 — PETN, with not less than 7% wax
HAZMAT RADIO NOTE — UN 0411 Product: PETN, with not less than 7% wax Class 1 / Explosive 1.1D / ERG 112 PPE: Level A required for fire involvement; structural firefighting gear inadequate; SCBA mandatory; minimum approach distance; no direct contact with material ISOLATION: ERG 112: isolate 500m minimum all directions; evacuate 1600m downwind if fire; consider withdrawal rather than firefighting; mass detonation risk ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0411 — PETN, with not less than 7% wax Class: 1 | Placard: Explosive 1.1D | ERG Guide: 112 Appearance: White crystalline powder or granular solid, odorless. Desensitized with wax to reduce sensitivity to initiation. Water Reactivity: No significant reaction with water, insoluble Extinguishing: Do not use water or foam — increases mass and shock sensitivity. Use distance and protective shielding. PPE: Level A required for fire involvement; structural firefighting gear inadequate; SCBA mandatory; minimum approach distance; no direct contact with material Isolation: ERG 112: isolate 500m minimum all directions; evacuate 1600m downwind if fire; consider withdrawal rather than firefighting; mass detonation risk — Key Hazards — • Mass explosion hazard — entire load may detonate simultaneously. • Severe blast overpressure and fragmentation. • Sensitive to heat, shock, and friction. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. • Establish large isolation zone — minimum 500 meters in all directions. • Stage upwind, uphill; limit personnel to essential responders only. • Request Hazmat + law enforcement + additional resources immediately. SOURCE: allfirefighter.com/hazmat/un/petn-with-not-less-un-0411 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN0411 PETN, with not less than 7% wax Cls1 ERG112 | allfirefighter.com/hazmat/un/petn-with-not-less-un-0411SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/petn-with-not-less-un-0411

Related UN Numbers in Class 1

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 0411

Yes. The wax in UN 0411 reduces sensitivity to accidental initiation but does not remove the explosive property. PETN remains a high explosive capable of mass detonation under fire or strong shock.

Water and foam are prohibited on UN 0411 because they can increase the effective mass of explosive material and may heighten shock sensitivity, raising the risk of mass detonation during firefighting efforts.

UN 0411 is Class 1.1D, meaning it is a mass explosion hazard explosive that does not contain a means of initiation or propelling charge — such as a secondary explosive in bulk or sheet form.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.