☣️ UN 0196 • CLASS 1

UN 0196 — Signals, smoke

Placard: Explosive 1.1G. ERG Guide 112. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 0196 Signals, smoke are solid pyrotechnic devices in cylindrical or canister form containing chemical mixtures that produce colored smoke upon ignition. These devices present a mass explosion hazard, meaning the entire load can detonate simultaneously under adverse conditions.

Hazard overview: UN 0196 poses a mass explosion hazard with potential for severe blast overpressure and fragmentation, and the entire cargo load may detonate simultaneously. These devices are highly sensitive to heat, shock, and friction, making any disturbance during an incident extremely dangerous.

Response guidance: Emergency responders must isolate UN 0196 incidents in all directions for a minimum of 500 meters (1,600 feet), expanding to a 1,600-meter (1-mile) evacuation radius if the cargo is involved in fire. Water and foam must never be used to extinguish burning UN 0196 devices; dry sand or earth should be used to smother flames from maximum possible distance.

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UN 0196 Quick Details

UN 0196
Product name: Signals, smoke
DOT Class: 1
Placard type: Explosive 1.1G
ERG Guide: 112 (check current ERG)
Initial isolation: ERG 112: isolate 500m (1600 ft) all directions; if fire or cargo involved in fire, evacuate 1600m (1 mile) radius; mass explosion hazard requires maximum evacuation distances

Common Hazards of UN 0196

  • Mass explosion hazard — entire load may detonate simultaneously.
  • Severe blast overpressure and fragmentation.
  • Sensitive to heat, shock, and friction.
  • Secondary fire and debris hazard.

Chemical Identity & Physical Properties

UN 0196 devices are solid pyrotechnic canisters or cylinders containing color-producing chemical compositions available in red, orange, white, or other formulations depending on intended use.

Also known asSmoke signalsPyrotechnic smoke signalsMarine smoke signalsDistress smoke signalsSignal flares (smoke type)
AppearanceSolid pyrotechnic devices typically in cylindrical or canister form, containing chemical mixtures that produce colored smoke when ignited. May be red, orange, white, or other colors depending on formulation.
Flash PointNot applicable (pyrotechnic composition)
Boiling PointNot applicable (pyrotechnic composition)
Vapor DensityNot applicable (solid pyrotechnic device)
Water ReactivityMay contain water-reactive components; keep dry to prevent degradation or unintended ignition
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 0196

Extinguishing Media

Do not use water or foam; use dry sand or earth to smother; fight fire from maximum distance

PPE Requirements

⚠️ Level B minimum with SCBA required; full protective clothing due to explosion and fragmentation hazard; maintain safe distance

Responders handling UN 0196 incidents must wear Level B protection minimum with SCBA and full protective clothing to guard against explosion, fragmentation, and toxic smoke exposure.

Isolation & Evacuation

ERG 112: isolate 500m (1600 ft) all directions; if fire or cargo involved in fire, evacuate 1600m (1 mile) radius; mass explosion hazard requires maximum evacuation distances
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 112).

First Actions for a UN 0196 Incident

  • CALL 911. Then call emergency response telephone number on shipping paper.
  • Establish large isolation zone — minimum 500 meters in all directions.
  • Stage upwind, uphill; limit personnel to essential responders only.
  • Request Hazmat + law enforcement + additional resources immediately.
  • Do not fight fire — evacuate and isolate; let burn if no life safety risk.
  • Protect exposures only if safe and directed by command.
  • Consult current ERG Guide 112 and follow SOP/SOG.
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📋 Copy & Share Field Card

UN 0196 — Signals, smoke
HAZMAT RADIO NOTE — UN 0196 Product: Signals, smoke Class 1 / Explosive 1.1G / ERG 112 PPE: Level B minimum with SCBA required; full protective clothing due to explosion and fragmentation hazard; maintain safe distance ISOLATION: ERG 112: isolate 500m (1600 ft) all directions; if fire or cargo involved in fire, evacuate 1600m (1 mile) radius; mass explosion hazard requires maximum evacuation distances ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0196 — Signals, smoke Class: 1 | Placard: Explosive 1.1G | ERG Guide: 112 Appearance: Solid pyrotechnic devices typically in cylindrical or canister form, containing chemical mixtures that produce colored smoke when ignited. May be red, orange, white, or other colors depending on formulation. Water Reactivity: May contain water-reactive components; keep dry to prevent degradation or unintended ignition Extinguishing: Do not use water or foam; use dry sand or earth to smother; fight fire from maximum distance PPE: Level B minimum with SCBA required; full protective clothing due to explosion and fragmentation hazard; maintain safe distance Isolation: ERG 112: isolate 500m (1600 ft) all directions; if fire or cargo involved in fire, evacuate 1600m (1 mile) radius; mass explosion hazard requires maximum evacuation distances — Key Hazards — • Mass explosion hazard — entire load may detonate simultaneously. • Severe blast overpressure and fragmentation. • Sensitive to heat, shock, and friction. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. • Establish large isolation zone — minimum 500 meters in all directions. • Stage upwind, uphill; limit personnel to essential responders only. • Request Hazmat + law enforcement + additional resources immediately. SOURCE: allfirefighter.com/hazmat/un/signals-smoke-un-0196 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN0196 Signals, smoke Cls1 ERG112 | allfirefighter.com/hazmat/un/signals-smoke-un-0196SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/signals-smoke-un-0196

Related UN Numbers in Class 1

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 0196

UN 0196 Signals, smoke are classified as Explosive 1.1G, presenting a mass explosion hazard where the entire cargo load can detonate simultaneously rather than simply burning.

Responders must use a minimum of Level B personal protective equipment including SCBA and full protective clothing to protect against blast, fragmentation, and toxic smoke from UN 0196 devices.

For UN 0196 incidents involving fire, responders must evacuate all persons within a 1,600-meter (approximately 1-mile) radius in all directions due to the mass explosion hazard.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.