☣️ UN 2573 • CLASS 5

UN 2573 — Thallium chlorate

Placard: Oxidizer. ERG Guide 141. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Thallium chlorate is a toxic oxidizing solid. The main response concern is a combination of oxidizer fire behavior, contamination sensitivity and thallium poisoning risk.

Hazard overview: This material can accelerate burning and may decompose violently if heated or contaminated with incompatible fuels or organics. Dust or residues are also a serious toxic exposure hazard because thallium compounds can affect the nervous system and other organs.

Response guidance: Isolate the area, remove ignition and fuel sources if this can be done safely, and keep combustible absorbents away from spilled material. Cool exposed containers from a protected position and base isolation decisions on ERG 141, SDS details and field monitoring.

Firefighter training notes: Train responders to treat thallium chlorate as both an oxidizer and a toxic material. Entry teams should recognize contamination hazards, avoid combustible absorbents and understand why oxidizers can worsen ordinary fires.

Regulatory context: UN 2573 is shipped as Thallium chlorate, Class 5 oxidizer. Use the shipping papers, package markings and SDS to confirm the exact product and any subsidiary toxic precautions.

Storage & handling: Store away from fuels, oils, organic materials, reducing agents and heat. Keep containers dry, closed and separated from incompatible toxic-waste streams.

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UN 2573 Quick Details

UN 2573
Product name: Thallium chlorate
DOT Class: 5
Placard type: Oxidizer
ERG Guide: 141 (check current ERG)
Initial isolation: ERG 141: isolate spill 50m all directions; if tank/rail car involved in fire isolate 800m and consider evacuation for 800m

Common Hazards of UN 2573

  • Strong oxidizer; can intensify burning of nearby combustibles even though it is not used as a fuel.
  • Heat, shock, friction or contamination may increase the risk of rapid decomposition or explosion.
  • Contact with fuels, oils, organic materials or reducing agents can create a severe fire or explosion hazard.
  • Containers may rupture or explode when heated in a fire.
  • Thallium compounds are highly toxic; ingestion, inhalation of dust or skin contamination may cause serious systemic poisoning.
  • Fire or decomposition may release irritating and toxic metal-containing fumes.
  • Contaminated runoff may spread toxic oxidizing material and should be contained when safe.

Chemical Identity & Physical Properties

Thallium chlorate is generally described as a white to colorless crystalline solid. It is an oxidizing salt, not a flammable liquid, and dust control is important during any release.

Also known asThallous chlorateThallium(I) chlorateChloric acid thallium(I) salt
CAS Number13453-30-0
AppearanceWhite to colorless crystalline solid, odorless. Moderately soluble in water.
Flash PointNot applicable (oxidizing solid)
Boiling PointDecomposes at 430C (806F)
Vapor DensityNot applicable (solid)
Water ReactivitySoluble in water; no violent water reaction is expected, but solutions remain toxic and oxidizing.
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2573

Extinguishing Media

Use water spray or flooding quantities for oxidizer fires when safe; keep fuels and organic absorbents away. Dry chemical may be used for small surrounding fires.

PPE Requirements

⚠️ SCBA and chemical protective clothing are required for fire or spill entry; prevent all skin contact with thallium salts.

Use SCBA for fire or unknown atmosphere conditions. Chemical protective clothing, gloves and eye protection should prevent any contact with dust, solution or contaminated runoff.

Isolation & Evacuation

ERG 141: isolate spill 50m all directions; if tank/rail car involved in fire isolate 800m and consider evacuation for 800m
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 141).

First Actions for a UN 2573 Incident

  • Call 911 and the emergency response number shown on shipping papers; confirm the material with ERG, SDS and container markings.
  • Keep unauthorized personnel away and establish hot, warm and cold zones before entry.
  • Stay upwind, uphill and upstream; avoid low areas where vapors, dust or runoff may collect.
  • Avoid breathing vapors, dust, mist or decomposition products and prevent skin or eye contact.
  • Do not touch damaged packages or containers unless properly trained and wearing suitable chemical PPE.
  • Ventilate confined spaces only after atmospheric monitoring and only with trained, equipped personnel.
  • Use ERG Guide 141, SDS, shipping papers and monitoring results for isolation, PPE and fire-control decisions.
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📋 Copy & Share Field Card

UN 2573 — Thallium chlorate
HAZMAT RADIO NOTE — UN 2573 Product: Thallium chlorate Class 5 / Oxidizer / ERG 141 PPE: SCBA and chemical protective clothing are required for fire or spill entry; prevent all skin contact with thallium salts. ISOLATION: ERG 141: isolate spill 50m all directions; if tank/rail car involved in fire isolate 800m and consider evacuation for 800m ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2573 — Thallium chlorate Class: 5 | Placard: Oxidizer | ERG Guide: 141 Appearance: White to colorless crystalline solid, odorless. Moderately soluble in water. Water Reactivity: Soluble in water; no violent water reaction is expected, but solutions remain toxic and oxidizing. Extinguishing: Use water spray or flooding quantities for oxidizer fires when safe; keep fuels and organic absorbents away. Dry chemical may be used for small surrounding fires. PPE: SCBA and chemical protective clothing are required for fire or spill entry; prevent all skin contact with thallium salts. Isolation: ERG 141: isolate spill 50m all directions; if tank/rail car involved in fire isolate 800m and consider evacuation for 800m — Key Hazards — • Strong oxidizer; can intensify burning of nearby combustibles even though it is not used as a fuel. • Heat, shock, friction or contamination may increase the risk of rapid decomposition or explosion. • Contact with fuels, oils, organic materials or reducing agents can create a severe fire or explosion hazard. — First Actions — • Call 911 and the emergency response number shown on shipping papers; confirm the material with ERG, SDS and container markings. • Keep unauthorized personnel away and establish hot, warm and cold zones before entry. • Stay upwind, uphill and upstream; avoid low areas where vapors, dust or runoff may collect. • Avoid breathing vapors, dust, mist or decomposition products and prevent skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/thallium-chlorate-un-2573 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2573 Thallium chlorate Cls5 ERG141 | allfirefighter.com/hazmat/un/thallium-chlorate-un-2573SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/thallium-chlorate-un-2573

Related UN Numbers in Class 5

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2573

It is an oxidizer, so it can make nearby combustibles burn faster and more intensely. Heating may also make containers fail.

It is not handled as a flammable fuel, but it can greatly increase the fire hazard of fuels, oils, paper, wood and other combustibles.

Thallium toxicity is a major concern. Dust, contaminated runoff or residue should not contact skin or be inhaled.

Avoid sawdust, paper or other combustible organic absorbents unless product-specific guidance says otherwise.

Confirm UN 2573, package condition, quantity and the SDS before choosing cleanup, isolation or disposal tactics.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.