☣️ UN 1719 • CLASS 8

UN 1719 — Caustic alkali liquid, n.o.s.

Placard: Corrosive. ERG Guide 154. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1719 is Caustic alkali liquid, n.o.s., a corrosive strong-base liquid assigned to ERG Guide 154. Exact composition varies, but skin, eye and respiratory burns are the primary hazards.

Hazard overview: UN 1719 presents caustic burn, alkaline mist and corrosive runoff hazards. Dilution can generate heat, and contact with some metals may release flammable hydrogen gas.

Response guidance: For a UN 1719 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 154. Establish incident command, isolate the area, stay upwind, prevent incompatible contact, control runoff and choose entry or fire-control actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1719 should emphasize caustic burn hazards, heat from dilution, mist control, eye protection, runoff containment and metal/hydrogen incompatibility. Use ERG 154, SDS and local SOP.

Regulatory context: Caustic alkali liquid, n.o.s. is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by concentration, formulation, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Caustic alkali liquid, n.o.s. should be stored in compatible corrosion-resistant containers with secondary containment, away from acids, reactive metals where incompatible, ammonium salts where incompatible and unauthorized access. Keep containers closed and protected from impact or heat.

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UN 1719 Quick Details

UN 1719
Product name: Caustic alkali liquid, n.o.s.
DOT Class: 8
Placard type: Corrosive
ERG Guide: 154 (check current ERG)
Initial isolation: ERG 154: Isolate spill area immediately for at least 50 meters in all directions. If tank/rail car involved in fire, isolate 800 meters in all directions.

Common Hazards of UN 1719

  • CORROSIVE caustic liquid; skin, eye or respiratory contact may cause severe burns.
  • Mist or spray can damage eyes, skin and respiratory tissue.
  • Generally non-flammable, but may react with some metals to release flammable hydrogen gas.
  • Dilution with water may generate heat and splattering, especially with concentrated solutions.
  • Runoff may be strongly alkaline and corrosive.
  • Containers may rupture or fail when heated.
  • Exact hazards depend on the specific caustic alkali and concentration.

Chemical Identity & Physical Properties

Clear to colored liquid, variable odor depending on specific alkali. Corrosive solution of various alkaline substances such as sodium hydroxide, potassium hydroxide, or other strong bases.

AppearanceClear to colored liquid, variable odor depending on specific alkali. Corrosive solution of various alkaline substances such as sodium hydroxide, potassium hydroxide, or other strong bases.
Flash PointNot applicable (aqueous solution, non-flammable)
Boiling PointVariable, typically above 100C (212F) depending on concentration and specific alkali
Vapor DensityNot applicable (low volatility aqueous solution)
Water ReactivityGenerally miscible with water; may generate heat on dilution. Do not add water directly to concentrated solutions.
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1719

Extinguishing Media

Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce vapors only when runoff can be controlled as corrosive or toxic contamination.

PPE Requirements

⚠️ Level B minimum; SCBA required in confined spaces or high vapor concentration; full face shield, chemical-resistant gloves, boots, and protective suit; rubber or neoprene materials preferred

Use positive-pressure SCBA for mist, vapor, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing selected from SDS for corrosive liquid contact.

Isolation & Evacuation

ERG 154: Isolate spill area immediately for at least 50 meters in all directions. If tank/rail car involved in fire, isolate 800 meters in all directions.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 154).

First Actions for a UN 1719 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust or mist and avoid skin or eye contact.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if vapor, dust, fire involvement, water reaction or unknown concentration is present.
  • Use ERG Guide 154, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1719 — Caustic alkali liquid, n.o.s.
HAZMAT RADIO NOTE — UN 1719 Product: Caustic alkali liquid, n.o.s. Class 8 / Corrosive / ERG 154 PPE: Level B minimum; SCBA required in confined spaces or high vapor concentration; full face shield, chemical-resistant gloves, boots, and protective suit; rubber or neoprene materials preferred ISOLATION: ERG 154: Isolate spill area immediately for at least 50 meters in all directions. If tank/rail car involved in fire, isolate 800 meters in all directions. ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1719 — Caustic alkali liquid, n.o.s. Class: 8 | Placard: Corrosive | ERG Guide: 154 Appearance: Clear to colored liquid, variable odor depending on specific alkali. Corrosive solution of various alkaline substances such as sodium hydroxide, potassium hydroxide, or other strong bases. Water Reactivity: Generally miscible with water; may generate heat on dilution. Do not add water directly to concentrated solutions. Extinguishing: Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce vapors only when runoff can be controlled as corrosive or toxic contamination. PPE: Level B minimum; SCBA required in confined spaces or high vapor concentration; full face shield, chemical-resistant gloves, boots, and protective suit; rubber or neoprene materials preferred Isolation: ERG 154: Isolate spill area immediately for at least 50 meters in all directions. If tank/rail car involved in fire, isolate 800 meters in all directions. — Key Hazards — • CORROSIVE caustic liquid; skin, eye or respiratory contact may cause severe burns. • Mist or spray can damage eyes, skin and respiratory tissue. • Generally non-flammable, but may react with some metals to release flammable hydrogen gas. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust or mist and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/caustic-alkali-liquid-n-un-1719 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1719 Caustic alkali liquid, n.o.s. Cls8 ERG154 | allfirefighter.com/hazmat/un/caustic-alkali-liquid-n-un-1719SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/caustic-alkali-liquid-n-un-1719

Related UN Numbers in Class 8

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1719

UN 1719 is Caustic alkali liquid, n.o.s., a hazardous material assigned to ERG Guide 154.

No. It is generally not flammable, but contact with some metals may release flammable hydrogen gas.

ERG Guide 154 applies to UN 1719 for initial isolation, protective actions and first response guidance.

UN 1719 presents caustic burn, alkaline mist and corrosive runoff hazards. Dilution can generate heat, and contact with some metals may release flammable hydrogen gas.

Use positive-pressure SCBA for mist, vapor, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing selected from SDS for corrosive liquid contact.

Dilution of concentrated caustic liquid can generate heat and splattering, increasing burn and runoff hazards.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.