☣️ UN 1725 • CLASS 8
UN 1725 — Aluminum bromide, anhydrous
Placard: Corrosive. ERG Guide 137. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
Aluminum bromide, anhydrous is a highly corrosive and toxic substance that poses significant risks to people and the environment. It is essential to handle this substance with extreme caution and follow proper emergency procedures.
Hazard overview: Aluminum bromide, anhydrous is corrosive and toxic, and can cause severe health effects upon inhalation, ingestion, or contact with vapors, dusts, or the substance itself.
Response guidance: In case of an emergency, evacuate the area immediately and call the local emergency number. Use dry chemical, soda ash, or lime to extinguish fires, and do not use water or water-based agents.
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UN 1725 Quick Details
UN 1725
Product name: Aluminum bromide, anhydrous
DOT Class: 8
Placard type: Corrosive
ERG Guide: 137 (check current ERG)
Initial isolation: ERG 137: isolate spill 25-50m all directions; if tank/rail car involved in fire, isolate 800m and consider evacuation
Common Hazards of UN 1725
- CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance
- Fire will produce irritating, corrosive and/or toxic gases.
- Reaction with water may generate much heat that will increase the concentration of fumes in the air.
- Contact with molten substance may cause severe burns to skin and eyes.
- Runoff from fire control or dilution water may cause environmental contamination.
- EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these materials may
- May ignite combustibles (wood, paper, oil, clothing, etc.).
- Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff.
Chemical Identity & Physical Properties
Aluminum bromide, anhydrous is a white to yellowish-gray crystalline solid or powder with a pungent, acrid odor.
| Also known as | Aluminum tribromideAluminium bromideTribromoaluminumAlBr3 |
| CAS Number | 7727-15-3 |
| Appearance | White to yellowish-gray crystalline solid or powder. Pungent, acrid odor. Hygroscopic and fumes in moist air. |
| Flash Point | Not applicable (non-flammable solid) |
| Boiling Point | 263C (505F) with decomposition |
| Vapor Density | Not applicable (solid, but vapors heavier than air when heated) |
| Water Reactivity | Reacts violently with water, generating heat and corrosive hydrogen bromide fumes |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Fireground Response Guidance — UN 1725
Extinguishing Media
Dry chemical, soda ash, lime; do NOT use water or water-based agents
PPE Requirements
⚠️ Level B minimum; full face SCBA, chemical-resistant suit, gloves and boots required due to corrosive vapors
Wear Level B minimum personal protective equipment (PPE), including a full face SCBA, chemical-resistant suit, gloves, and boots, due to corrosive vapors.
Isolation & Evacuation
ERG 137: isolate spill 25-50m all directions; if tank/rail car involved in fire, isolate 800m and consider evacuation
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 137).
First Actions for a UN 1725 Incident
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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📋 Copy & Share Field Card
UN 1725 — Aluminum bromide, anhydrousHAZMAT RADIO NOTE — UN 1725
Product: Aluminum bromide, anhydrous
Class 8 / Corrosive / ERG 137
PPE: Level B minimum; full face SCBA, chemical-resistant suit, gloves and boots required due to corrosive vapors
ISOLATION: ERG 137: isolate spill 25-50m all directions; if tank/rail car involved in fire, isolate 800m and consider evacuation
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 1725 — Aluminum bromide, anhydrous
Class: 8 | Placard: Corrosive | ERG Guide: 137
Appearance: White to yellowish-gray crystalline solid or powder. Pungent, acrid odor. Hygroscopic and fumes in moist air.
Water Reactivity: Reacts violently with water, generating heat and corrosive hydrogen bromide fumes
Extinguishing: Dry chemical, soda ash, lime; do NOT use water or water-based agents
PPE: Level B minimum; full face SCBA, chemical-resistant suit, gloves and boots required due to corrosive vapors
Isolation: ERG 137: isolate spill 25-50m all directions; if tank/rail car involved in fire, isolate 800m and consider evacuation
— Key Hazards —
• CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance
• Fire will produce irritating, corrosive and/or toxic gases.
• Reaction with water may generate much heat that will increase the concentration of fumes in the air.
— First Actions —
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
• Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
SOURCE: allfirefighter.com/hazmat/un/1725 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.
UN1725 Aluminum bromide, anhydrous Cls8 ERG137 | allfirefighter.com/hazmat/un/1725SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions.
Page: https://allfirefighter.com/hazmat/un/aluminum-bromide-anhydrous-un-1725
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Frequently Asked Questions about UN 1725
Yes, Aluminum bromide, anhydrous is highly corrosive and can cause severe health effects.
Aluminum bromide, anhydrous reacts violently with water, producing heat and corrosive hydrogen bromide fumes.
Wear Level B minimum PPE, including a full face SCBA, chemical-resistant suit, gloves, and boots, due to corrosive vapors.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles.
This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.