☣️ UN 2079 • CLASS 8

UN 2079 — Diethylenetriamine

Placard: Corrosive. ERG Guide 154. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2079 is Diethylenetriamine, a corrosive amine liquid assigned to ERG Guide 154. It can cause severe burns and produce alkaline contaminated runoff.

Hazard overview: CORROSIVE amine liquid; skin, eye or respiratory contact may cause severe burns. May be combustible and burn under fire conditions. Mixing with water can generate heat and spread alkaline contamination.

Response guidance: For a UN 2079 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 154. Establish incident command, isolate the area, stay upwind, control ignition or incompatibility hazards, prevent runoff or vapor spread and base entry/fire-control actions on monitoring and local SOP.

Firefighter training notes: Training for UN 2079 should emphasize exposure routes, air monitoring, PPE selection, fire behavior, decontamination, runoff containment and ERG/SDS verification. Use ERG 154, SDS and local SOP.

Regulatory context: Diethylenetriamine is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting, waste handling and environmental requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Diethylenetriamine should be stored in tightly closed compatible containers in a secure, ventilated toxic/corrosive area with secondary containment, restricted access and segregation from incompatible chemicals according to SDS.

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UN 2079 Quick Details

UN 2079
Product name: Diethylenetriamine
DOT Class: 8
Placard type: Corrosive
ERG Guide: 154 (check current ERG)
Initial isolation: ERG 154: isolate spill 25-50m; for large spills consider 300m initial downwind evacuation; if tank/railcar involved in fire, isolate 800m all directions

Common Hazards of UN 2079

  • CORROSIVE amine liquid; skin, eye or respiratory contact may cause severe burns.
  • May be combustible and burn under fire conditions.
  • Mixing with water can generate heat and spread alkaline contamination.
  • Vapors or mist can irritate or injure respiratory tissue.
  • Contact with acids or oxidizers may react strongly.
  • Fire may produce nitrogen oxides and irritating/toxic smoke.
  • Runoff may be alkaline, corrosive and environmentally harmful.

Chemical Identity & Physical Properties

Clear to yellow viscous liquid with an ammonia-like odor. Corrosive and hygroscopic at room temperature.

Also known asDETA2,2'-Diaminodiethylamine3-Azapentane-1,5-diamineAminoethylethanediamineBis(2-aminoethyl)amine
CAS Number111-40-0
AppearanceClear to yellow viscous liquid with an ammonia-like odor. Corrosive and hygroscopic at room temperature.
Flash Point98C (208F)
Boiling Point207C (405F)
Vapor Density3.6 (heavier than air)
Water ReactivitySoluble in water; exothermic reaction generates heat but not violent
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2079

Extinguishing Media

Use dry chemical, CO2, foam or water spray as compatible with the product and fire size. Cool containers from a protected position and contain runoff as toxic/corrosive contamination.

PPE Requirements

⚠️ Level B minimum; SCBA required; full chemical-resistant suit, neoprene or butyl rubber gloves; severe skin and eye contact hazard

Use positive-pressure SCBA for dust, vapor, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing selected from SDS; avoid skin contact.

Isolation & Evacuation

ERG 154: isolate spill 25-50m; for large spills consider 300m initial downwind evacuation; if tank/railcar involved in fire, isolate 800m all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 154).

First Actions for a UN 2079 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, gas, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Do not touch damaged containers or spilled/released material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or release area and expand the perimeter for fire involvement, vapor spread, gas accumulation, cylinder heating or unknown product identity.
  • Use ERG Guide 154, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 2079 — Diethylenetriamine
HAZMAT RADIO NOTE — UN 2079 Product: Diethylenetriamine Class 8 / Corrosive / ERG 154 PPE: Level B minimum; SCBA required; full chemical-resistant suit, neoprene or butyl rubber gloves; severe skin and eye contact hazard ISOLATION: ERG 154: isolate spill 25-50m; for large spills consider 300m initial downwind evacuation; if tank/railcar involved in fire, isolate 800m all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2079 — Diethylenetriamine Class: 8 | Placard: Corrosive | ERG Guide: 154 Appearance: Clear to yellow viscous liquid with an ammonia-like odor. Corrosive and hygroscopic at room temperature. Water Reactivity: Soluble in water; exothermic reaction generates heat but not violent Extinguishing: Use dry chemical, CO2, foam or water spray as compatible with the product and fire size. Cool containers from a protected position and contain runoff as toxic/corrosive contamination. PPE: Level B minimum; SCBA required; full chemical-resistant suit, neoprene or butyl rubber gloves; severe skin and eye contact hazard Isolation: ERG 154: isolate spill 25-50m; for large spills consider 300m initial downwind evacuation; if tank/railcar involved in fire, isolate 800m all directions — Key Hazards — • CORROSIVE amine liquid; skin, eye or respiratory contact may cause severe burns. • May be combustible and burn under fire conditions. • Mixing with water can generate heat and spread alkaline contamination. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, gas, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/diethylenetriamine-un-2079 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2079 Diethylenetriamine Cls8 ERG154 | allfirefighter.com/hazmat/un/diethylenetriamine-un-2079SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/diethylenetriamine-un-2079

Related UN Numbers in Class 8

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2079

UN 2079 is Diethylenetriamine, a hazardous material assigned to ERG Guide 154.

It is combustible and may burn under fire conditions; corrosive exposure is the main hazard.

ERG Guide 154 applies to UN 2079 for initial isolation, protective actions and first response guidance.

CORROSIVE amine liquid; skin, eye or respiratory contact may cause severe burns. May be combustible and burn under fire conditions. Mixing with water can generate heat and spread alkaline contamination.

Use positive-pressure SCBA for dust, vapor, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing selected from SDS; avoid skin contact.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.