☣️ UN 2264 • CLASS 8

UN 2264 — N,N-Dimethylcyclohexylamine

Placard: Corrosive. ERG Guide 132. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2264 is N,N-Dimethylcyclohexylamine, a hazardous material assigned to ERG Guide 132. Verify exact hazards from shipping papers, markings and SDS.

Hazard overview: Hazards depend on the exact product, packaging and incident conditions. Verify the material using shipping papers, labels and SDS before close action. Fire may produce irritating or toxic smoke or gases.

Response guidance: For a UN 2264 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 132. Establish incident command, isolate the area, stay upwind, control ignition or incompatibility hazards, prevent runoff, dust or vapor spread and base entry/fire-control actions on monitoring and local SOP.

Firefighter training notes: Training for UN 2264 should emphasize exposure routes, air monitoring, PPE selection, fire behavior, decontamination, runoff containment and ERG/SDS verification. Use ERG 132, SDS and local SOP.

Regulatory context: N,N-Dimethylcyclohexylamine is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting, waste handling and environmental requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: N,N-Dimethylcyclohexylamine should be stored in compatible containers in a secure, cool, ventilated hazardous-material area according to SDS and local procedures.

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UN 2264 Quick Details

UN 2264
Product name: N,N-Dimethylcyclohexylamine
DOT Class: 8
Placard type: Corrosive
ERG Guide: 132 (check current ERG)
Initial isolation: ERG 132: Isolate spill 50m in all directions; for large spill isolate 150m initially, evacuate downwind as needed

Common Hazards of UN 2264

  • Hazards depend on the exact product, packaging and incident conditions.
  • Verify the material using shipping papers, labels and SDS before close action.
  • Fire may produce irritating or toxic smoke or gases.
  • Containers may fail or rupture when heated.

Chemical Identity & Physical Properties

Clear to pale yellow liquid with an amine-like, fishy odor. Corrosive liquid at room temperature.

Also known asN,N-DimethylcyclohexanamineDimethylcyclohexylamineDMCHAN-Cyclohexyl-N,N-dimethylamine
CAS Number98-94-2
AppearanceClear to pale yellow liquid with an amine-like, fishy odor. Corrosive liquid at room temperature.
Flash Point36°C (97°F)
Boiling Point159-160°C (318-320°F)
Vapor Density4.4 (heavier than air)
Water ReactivityReacts exothermically with water; may produce heat and corrosive solutions
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2264

Extinguishing Media

Use extinguishing agents compatible with the exact product and SDS; cool exposed containers from a protected position when safe.

PPE Requirements

⚠️ Level B minimum with chemical-resistant suit; SCBA required; neoprene or butyl rubber gloves

Use protective equipment selected from SDS, monitoring results and incident command.

Isolation & Evacuation

ERG 132: Isolate spill 50m in all directions; for large spill isolate 150m initially, evacuate downwind as needed
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 132).

First Actions for a UN 2264 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or release area and expand the perimeter for fire involvement, vapor spread, dust generation, water reaction or unknown product identity.
  • Use ERG Guide 132, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 2264 — N,N-Dimethylcyclohexylamine
HAZMAT RADIO NOTE — UN 2264 Product: N,N-Dimethylcyclohexylamine Class 8 / Corrosive / ERG 132 PPE: Level B minimum with chemical-resistant suit; SCBA required; neoprene or butyl rubber gloves ISOLATION: ERG 132: Isolate spill 50m in all directions; for large spill isolate 150m initially, evacuate downwind as needed ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2264 — N,N-Dimethylcyclohexylamine Class: 8 | Placard: Corrosive | ERG Guide: 132 Appearance: Clear to pale yellow liquid with an amine-like, fishy odor. Corrosive liquid at room temperature. Water Reactivity: Reacts exothermically with water; may produce heat and corrosive solutions Extinguishing: Use extinguishing agents compatible with the exact product and SDS; cool exposed containers from a protected position when safe. PPE: Level B minimum with chemical-resistant suit; SCBA required; neoprene or butyl rubber gloves Isolation: ERG 132: Isolate spill 50m in all directions; for large spill isolate 150m initially, evacuate downwind as needed — Key Hazards — • Hazards depend on the exact product, packaging and incident conditions. • Verify the material using shipping papers, labels and SDS before close action. • Fire may produce irritating or toxic smoke or gases. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/n-n-dimethylcyclohexylamine-un-2264 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2264 N,N-Dimethylcyclohexylamine Cls8 ERG132 | allfirefighter.com/hazmat/un/n-n-dimethylcyclohexylamine-un-2264SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/n-n-dimethylcyclohexylamine-un-2264

Related UN Numbers in Class 8

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2264

UN 2264 is N,N-Dimethylcyclohexylamine, a hazardous material assigned to ERG Guide 132.

Flammability depends on the exact material and SDS; verify before action.

ERG Guide 132 applies to UN 2264 for initial isolation, protective actions and first response guidance.

Hazards depend on the exact product, packaging and incident conditions. Verify the material using shipping papers, labels and SDS before close action. Fire may produce irritating or toxic smoke or gases.

Use protective equipment selected from SDS, monitoring results and incident command.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.