☣️ UN 2269 • CLASS 8
UN 2269 — 3,3'-Iminodipropylamine
Placard: Corrosive. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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UN 2269 Quick Details
UN 2269
Product name: 3,3'-Iminodipropylamine
DOT Class: 8
Placard type: Corrosive
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: isolate spill 25-50m all directions; if tank/rail car involved in fire, isolate 800m and evacuate 1600m downwind
Common Hazards of UN 2269
- TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury
- Methyl bromoacetate (UN2643) is an eye irritant/lachrymator (causes flow of tears).
- Contact with molten substance may cause severe burns to skin and eyes.
- Avoid any skin contact.
- Fire may produce irritating, corrosive and/or toxic gases.
- Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental
- Combustible material: may burn but does not ignite readily.
- When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion
Chemical Identity & Physical Properties
| Also known as | Bis(3-aminopropyl)amineDPTADipropylenetriamineN-(3-aminopropyl)-1,3-propanediamine3,3'-Diaminodipropylamine |
| CAS Number | 56-18-8 |
| Appearance | Clear to pale yellow liquid with ammonia-like or amine odor. Viscous consistency at room temperature. |
| Flash Point | 124°C (255°F) |
| Boiling Point | 240-243°C (464-469°F) |
| Vapor Density | 4.5 (heavier than air) |
| Water Reactivity | Soluble in water; may generate heat but no violent reaction |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Fireground Response Guidance — UN 2269
Extinguishing Media
Alcohol-resistant foam, dry chemical, CO2; avoid direct water streams
PPE Requirements
⚠️ Level B minimum; SCBA required; full face shield and chemical-resistant gloves; avoid skin contact - severe burns likely
Isolation & Evacuation
ERG 153: isolate spill 25-50m all directions; if tank/rail car involved in fire, isolate 800m and evacuate 1600m downwind
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).
First Actions for a UN 2269 Incident
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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📋 Copy & Share Field Card
UN 2269 — 3,3'-IminodipropylamineHAZMAT RADIO NOTE — UN 2269
Product: 3,3'-Iminodipropylamine
Class 8 / Corrosive / ERG 153
PPE: Level B minimum; SCBA required; full face shield and chemical-resistant gloves; avoid skin contact - severe burns likely
ISOLATION: ERG 153: isolate spill 25-50m all directions; if tank/rail car involved in fire, isolate 800m and evacuate 1600m downwind
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 2269 — 3,3'-Iminodipropylamine
Class: 8 | Placard: Corrosive | ERG Guide: 153
Appearance: Clear to pale yellow liquid with ammonia-like or amine odor. Viscous consistency at room temperature.
Water Reactivity: Soluble in water; may generate heat but no violent reaction
Extinguishing: Alcohol-resistant foam, dry chemical, CO2; avoid direct water streams
PPE: Level B minimum; SCBA required; full face shield and chemical-resistant gloves; avoid skin contact - severe burns likely
Isolation: ERG 153: isolate spill 25-50m all directions; if tank/rail car involved in fire, isolate 800m and evacuate 1600m downwind
— Key Hazards —
• TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury
• Methyl bromoacetate (UN2643) is an eye irritant/lachrymator (causes flow of tears).
• Contact with molten substance may cause severe burns to skin and eyes.
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/2269 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN2269 3,3'-Iminodipropylamine Cls8 ERG153 | allfirefighter.com/hazmat/un/2269SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions.
Page: https://allfirefighter.com/hazmat/un/2269
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Frequently Asked Questions about UN 2269
TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury Methyl bromoacetate (UN2643) is an eye irritant/lachrymator (causes flow of tears). Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level B minimum; SCBA required; full face shield and chemical-resistant gloves; avoid skin contact - severe burns likely
Water reactivity: Soluble in water; may generate heat but no violent reaction. Recommended extinguishing: Alcohol-resistant foam, dry chemical, CO2; avoid direct water streams.
ERG Guide 153 recommendation: ERG 153: isolate spill 25-50m all directions; if tank/rail car involved in fire, isolate 800m and evacuate 1600m downwind
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 153 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles.
This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.