☣️ UN 2585 • CLASS 8

UN 2585 — Alkyl sulphonic acids, solid, with not more than 5% free sulphuric acid

Placard: Corrosive. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2585 covers alkyl sulphonic acids in solid form with not more than 5% free sulphuric acid. It is a variable corrosive material, so exact SDS and shipping papers are critical.

Hazard overview: This entry describes a category rather than one single pure compound. The product may release heat and acidic mist when diluted or contaminated with water, and contact can cause severe corrosive burns.

Response guidance: Keep personnel out of splash and vapor zones, protect drains and avoid direct water streams on concentrated material. Use dry chemical or CO2 for surrounding fire, cool containers from a distance and follow product-specific SDS instructions before neutralization.

Firefighter training notes: Train crews to treat this as a variable corrosive category. Emphasize SDS verification, acid dilution hazards, runoff control and splash-zone discipline.

Regulatory context: UN 2585 is a Class 8 corrosive entry for alkyl sulphonic acids in solid form. Confirm free sulfuric acid content, composition and package details from shipping papers.

Storage & handling: Store in compatible corrosion-resistant containers with secondary containment. Separate from bases, reactive metals, oxidizers, cyanides, sulfides and water-sensitive materials.

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UN 2585 Quick Details

UN 2585
Product name: Alkyl sulphonic acids, solid, with not more than 5% free sulphuric acid
DOT Class: 8
Placard type: Corrosive
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: isolate spill area minimum 25m all directions; if tank/rail car involved in fire isolate 800m all directions

Common Hazards of UN 2585

  • Corrosive solid organic sulfonic acid material; contact can burn skin and eyes.
  • Contains free sulfuric acid; concentration affects heat release, fuming and corrosivity.
  • Water contact or dilution may generate heat, splashing and acidic mist.
  • Fire may produce sulfur oxides, carbon oxides and irritating corrosive gases.
  • Some formulations may be combustible or may support burning of contaminated packaging.
  • Runoff from spills or fire control can remain strongly acidic.
  • Containers may rupture when heated.

Chemical Identity & Physical Properties

The material is described as a corrosive solid, often powder or granules, but color and odor vary by formulation.

Also known asAlkyl sulfonic acidsAlkanesulfonic acids solidSulfonic acid derivatives solid
AppearanceWhite to off-white crystalline solid or powder at room temperature. Typically odorless or with a faint acidic odor. May be hygroscopic.
Flash PointNot applicable (non-flammable solid)
Boiling PointNot applicable (decomposes before boiling)
Vapor DensityNot applicable (solid)
Water ReactivityMay dissolve or react with water with heat release; add water only under controlled SDS guidance because acid mist or splashing can occur.
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2585

Extinguishing Media

Use dry chemical or CO2 for surrounding fires; water spray may cool containers from a distance but avoid direct streams on concentrated material.

PPE Requirements

⚠️ Level B minimum; chemical-resistant suit, gloves, boots; SCBA or supplied-air respirator; face shield and eye protection mandatory

Use SCBA where mist, dust, vapor or fire gases may be present. Acid-resistant suit, gloves, boots and full face protection are required for spill entry.

Isolation & Evacuation

ERG 153: isolate spill area minimum 25m all directions; if tank/rail car involved in fire isolate 800m all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 2585 Incident

  • Call 911 and the emergency response number shown on shipping papers; confirm the material with ERG, SDS and container markings.
  • Keep unauthorized personnel away and establish hot, warm and cold zones before entry.
  • Stay upwind, uphill and upstream; avoid low areas where vapors, dust or runoff may collect.
  • Avoid breathing vapors, dust, mist or decomposition products and prevent skin or eye contact.
  • Do not touch damaged packages or containers unless properly trained and wearing suitable chemical PPE.
  • Ventilate confined spaces only after atmospheric monitoring and only with trained, equipped personnel.
  • Use ERG Guide 153, SDS, shipping papers and monitoring results for isolation, PPE and fire-control decisions.
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📋 Copy & Share Field Card

UN 2585 — Alkyl sulphonic acids, solid, with not m
HAZMAT RADIO NOTE — UN 2585 Product: Alkyl sulphonic acids, solid, with not more than 5% free sulphuric acid Class 8 / Corrosive / ERG 153 PPE: Level B minimum; chemical-resistant suit, gloves, boots; SCBA or supplied-air respirator; face shield and eye protection mandatory ISOLATION: ERG 153: isolate spill area minimum 25m all directions; if tank/rail car involved in fire isolate 800m all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2585 — Alkyl sulphonic acids, solid, with not more than 5% free sulphuric acid Class: 8 | Placard: Corrosive | ERG Guide: 153 Appearance: White to off-white crystalline solid or powder at room temperature. Typically odorless or with a faint acidic odor. May be hygroscopic. Water Reactivity: May dissolve or react with water with heat release; add water only under controlled SDS guidance because acid mist or splashing can occur. Extinguishing: Use dry chemical or CO2 for surrounding fires; water spray may cool containers from a distance but avoid direct streams on concentrated material. PPE: Level B minimum; chemical-resistant suit, gloves, boots; SCBA or supplied-air respirator; face shield and eye protection mandatory Isolation: ERG 153: isolate spill area minimum 25m all directions; if tank/rail car involved in fire isolate 800m all directions — Key Hazards — • Corrosive solid organic sulfonic acid material; contact can burn skin and eyes. • Contains free sulfuric acid; concentration affects heat release, fuming and corrosivity. • Water contact or dilution may generate heat, splashing and acidic mist. — First Actions — • Call 911 and the emergency response number shown on shipping papers; confirm the material with ERG, SDS and container markings. • Keep unauthorized personnel away and establish hot, warm and cold zones before entry. • Stay upwind, uphill and upstream; avoid low areas where vapors, dust or runoff may collect. • Avoid breathing vapors, dust, mist or decomposition products and prevent skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/alkyl-sulphonic-acids-solid-un-2585 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2585 Alkyl sulphonic acids, solid, with not more than 5% free sulphuric acid Cls8 ERG153 | allfirefighter.com/hazmat/un/alkyl-sulphonic-acids-solid-un-2585SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/alkyl-sulphonic-acids-solid-un-2585

Related UN Numbers in Class 8

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2585

It is a broad material category, not one exact formula. The SDS and shipping papers must identify the actual product.

Corrosive acid exposure is the main hazard, with possible heat and mist during dilution or water contact.

Water spray may cool containers, but direct water on concentrated material can cause heat, splashing or mist.

Fire can generate irritating sulfur oxides and other corrosive decomposition products.

SCBA plus acid-resistant chemical protective clothing, gloves, boots and face protection.

Runoff can stay acidic and may damage drains, waterways or response equipment.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.