☣️ UN 2679 • CLASS 8
UN 2679 — Lithium hydroxide, solution
Placard: Corrosive. ERG Guide 154. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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UN 2679 Quick Details
UN 2679
Product name: Lithium hydroxide, solution
DOT Class: 8
Placard type: Corrosive
ERG Guide: 154 (check current ERG)
Initial isolation: ERG 154: isolate spill 25-50m all directions; for large spills consider evacuation 300m downwind
Common Hazards of UN 2679
- TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury
- Contact with molten substance may cause severe burns to skin and eyes.
- Avoid any skin contact.
- Fire may produce irritating, corrosive and/or toxic gases.
- Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental
- Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive
- Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.).
- Corrosives in contact with metals may evolve flammable hydrogen gas.
Chemical Identity & Physical Properties
| Also known as | Lithium hydroxide solutionLithium hydrate solutionLiOH solutionCaustic lithium solution |
| CAS Number | 1310-65-2 |
| Appearance | Clear to slightly turbid colorless aqueous solution. Odorless. Strongly alkaline with soapy feel. |
| Flash Point | Not applicable (aqueous solution) |
| Boiling Point | Approximately 100C (212F), varies with concentration |
| Vapor Density | Not applicable (aqueous solution) |
| Water Reactivity | Already dissolved in water; dilution generates heat |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Fireground Response Guidance — UN 2679
Extinguishing Media
Water spray, fog, or mist for cooling; avoid direct water stream on spills
PPE Requirements
⚠️ Level B minimum; chemical-resistant suit, gloves, and boots required; SCBA for confined spaces or large spills
Isolation & Evacuation
ERG 154: isolate spill 25-50m all directions; for large spills consider evacuation 300m downwind
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 154).
First Actions for a UN 2679 Incident
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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📋 Copy & Share Field Card
UN 2679 — Lithium hydroxide, solutionHAZMAT RADIO NOTE — UN 2679
Product: Lithium hydroxide, solution
Class 8 / Corrosive / ERG 154
PPE: Level B minimum; chemical-resistant suit, gloves, and boots required; SCBA for confined spaces or large spills
ISOLATION: ERG 154: isolate spill 25-50m all directions; for large spills consider evacuation 300m downwind
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 2679 — Lithium hydroxide, solution
Class: 8 | Placard: Corrosive | ERG Guide: 154
Appearance: Clear to slightly turbid colorless aqueous solution. Odorless. Strongly alkaline with soapy feel.
Water Reactivity: Already dissolved in water; dilution generates heat
Extinguishing: Water spray, fog, or mist for cooling; avoid direct water stream on spills
PPE: Level B minimum; chemical-resistant suit, gloves, and boots required; SCBA for confined spaces or large spills
Isolation: ERG 154: isolate spill 25-50m all directions; for large spills consider evacuation 300m downwind
— Key Hazards —
• TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury
• Contact with molten substance may cause severe burns to skin and eyes.
• Avoid any skin contact.
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/2679 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN2679 Lithium hydroxide, solution Cls8 ERG154 | allfirefighter.com/hazmat/un/2679SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions.
Page: https://allfirefighter.com/hazmat/un/2679
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Frequently Asked Questions about UN 2679
TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Corrosives in contact with metals may evolve flammable hydrogen gas.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level B minimum; chemical-resistant suit, gloves, and boots required; SCBA for confined spaces or large spills
Water reactivity: Already dissolved in water; dilution generates heat. Recommended extinguishing: Water spray, fog, or mist for cooling; avoid direct water stream on spills.
ERG Guide 154 recommendation: ERG 154: isolate spill 25-50m all directions; for large spills consider evacuation 300m downwind
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 154 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles.
This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.