☣️ UN 2699 • CLASS 8
UN 2699 — Trifluoroacetic acid
Placard: Corrosive. ERG Guide 154. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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UN 2699 Quick Details
UN 2699
Product name: Trifluoroacetic acid
DOT Class: 8
Placard type: Corrosive
ERG Guide: 154 (check current ERG)
Initial isolation: ERG 154: isolate spill 25-50m all directions; if tank/railcar involved in fire, isolate 800m all directions
Common Hazards of UN 2699
- TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury
- Contact with molten substance may cause severe burns to skin and eyes.
- Avoid any skin contact.
- Fire may produce irritating, corrosive and/or toxic gases.
- Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental
- Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive
- Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.).
- Corrosives in contact with metals may evolve flammable hydrogen gas.
Chemical Identity & Physical Properties
| Also known as | TFAPerfluoroacetic acidTrifluoroethanoic acidAcide trifluoroacétique |
| CAS Number | 76-05-1 |
| Appearance | Colorless, fuming liquid with a pungent, vinegar-like odor. Highly corrosive and hygroscopic at room temperature. |
| Flash Point | Not applicable (non-flammable) |
| Boiling Point | 72C (162F) |
| Vapor Density | 3.9 (heavier than air) |
| Water Reactivity | Miscible with water; generates heat on mixing but no violent reaction |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Fireground Response Guidance — UN 2699
Extinguishing Media
Water spray to reduce vapors, dry chemical, CO2; foam generally not required for non-flammable corrosive
PPE Requirements
⚠️ Level B minimum; SCBA required; acid-resistant suits, gloves, and face shields; avoid all skin and eye contact
Isolation & Evacuation
ERG 154: isolate spill 25-50m all directions; if tank/railcar involved in fire, isolate 800m all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 154).
First Actions for a UN 2699 Incident
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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📋 Copy & Share Field Card
UN 2699 — Trifluoroacetic acidHAZMAT RADIO NOTE — UN 2699
Product: Trifluoroacetic acid
Class 8 / Corrosive / ERG 154
PPE: Level B minimum; SCBA required; acid-resistant suits, gloves, and face shields; avoid all skin and eye contact
ISOLATION: ERG 154: isolate spill 25-50m all directions; if tank/railcar involved in fire, isolate 800m all directions
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 2699 — Trifluoroacetic acid
Class: 8 | Placard: Corrosive | ERG Guide: 154
Appearance: Colorless, fuming liquid with a pungent, vinegar-like odor. Highly corrosive and hygroscopic at room temperature.
Water Reactivity: Miscible with water; generates heat on mixing but no violent reaction
Extinguishing: Water spray to reduce vapors, dry chemical, CO2; foam generally not required for non-flammable corrosive
PPE: Level B minimum; SCBA required; acid-resistant suits, gloves, and face shields; avoid all skin and eye contact
Isolation: ERG 154: isolate spill 25-50m all directions; if tank/railcar involved in fire, isolate 800m all directions
— Key Hazards —
• TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury
• Contact with molten substance may cause severe burns to skin and eyes.
• Avoid any skin contact.
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/2699 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN2699 Trifluoroacetic acid Cls8 ERG154 | ERG 154: isolate spill 25-50m all directions; if tank/railcar involved in fire, | allfirefighter.com/hazmat/un/2699SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions.
Page: https://allfirefighter.com/hazmat/un/2699
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Frequently Asked Questions about UN 2699
TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Corrosives in contact with metals may evolve flammable hydrogen gas.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level B minimum; SCBA required; acid-resistant suits, gloves, and face shields; avoid all skin and eye contact
Water reactivity: Miscible with water; generates heat on mixing but no violent reaction. Recommended extinguishing: Water spray to reduce vapors, dry chemical, CO2; foam generally not required for non-flammable corrosive.
ERG Guide 154 recommendation: ERG 154: isolate spill 25-50m all directions; if tank/railcar involved in fire, isolate 800m all directions
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 154 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles.
This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.