☣️ UN 3244 • CLASS 8

UN 3244 — Solids containing corrosive liquid, n.o.s.

Placard: Corrosive. ERG Guide 154. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 3244 is Solids containing corrosive liquid, n.o.s., a broad corrosive liquid-in-solid entry assigned to ERG Guide 154. Hidden free liquid and corrosive runoff are key hazards.

Hazard overview: CORROSIVE liquid absorbed or contained in solid material, n.o.s.; contact can burn eyes, skin and respiratory tissue. Damaged packages can leak corrosive liquid from absorbent, matrix or article contents. Solid carrier may hide the amount of free liquid present.

Response guidance: For UN 3244, isolate damaged packages, prevent leakage spread and use PPE for the contained liquid. Contain runoff and verify exact contents with SDS and ERG 154.

Firefighter training notes: Training for UN 3244 should emphasize product verification, SCBA use, dust/vapor control, decontamination, runoff containment and SDS/package review. Use ERG 154, SDS and local SOP.

Regulatory context: Solids containing corrosive liquid, n.o.s. is regulated as a hazardous material for transport and emergency response. Storage, reporting, exposure, waste and incident-notification duties depend on quantity, formulation, package type and jurisdiction; verify shipping papers, SDS and authority guidance.

Storage & handling: Solids containing corrosive liquid, n.o.s. should be stored in intact compatible packages with secondary containment, restricted access and segregation based on the contained liquid's SDS and incompatibilities.

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UN 3244 Quick Details

UN 3244
Product name: Solids containing corrosive liquid, n.o.s.
DOT Class: 8
Placard type: Corrosive
ERG Guide: 154 (check current ERG)
Initial isolation: ERG 154: isolate spill/leak area immediately for at least 25-50 meters in all directions; if tank/rail car involved in fire, isolate 800 meters in all directions and consider initial evacuation for 800 meters

Common Hazards of UN 3244

  • CORROSIVE liquid absorbed or contained in solid material, n.o.s.; contact can burn eyes, skin and respiratory tissue.
  • Damaged packages can leak corrosive liquid from absorbent, matrix or article contents.
  • Solid carrier may hide the amount of free liquid present.
  • Some contained liquids may react with metals, water or incompatible materials depending on identity.
  • Fire may release corrosive/toxic smoke or acidic/alkaline runoff.
  • Runoff may spread corrosive contamination.
  • Exact corrosive liquid, pH, carrier and leakage potential must be verified from SDS and shipping papers.

Chemical Identity & Physical Properties

Variable appearance depending on specific formulation. Solid material impregnated with or containing corrosive liquid components. May be granular, powder, or formed solid. Corrosive properties derived from absorbed or encapsulated liquid phase.

Also known asCorrosive solid mixtureSolid corrosive n.o.s.Corrosive solid preparationSolid containing corrosive liquid NOS
AppearanceVariable appearance depending on specific formulation. Solid material impregnated with or containing corrosive liquid components. May be granular, powder, or formed solid. Corrosive properties derived from absorbed or encapsulated liquid phase.
Flash PointVariable depending on specific components; refer to SDS for individual formulation
Boiling PointNot applicable (solid mixture with liquid components)
Vapor DensityNot applicable (solid material; vapor properties vary by liquid component)
Water ReactivityMay react depending on corrosive component; contact may release corrosive liquids or fumes; use caution with water
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3244

Extinguishing Media

Use agents compatible with the contained liquid and solid carrier. Cool packages from protection and contain toxic/corrosive runoff.

PPE Requirements

⚠️ Level B minimum recommended; full face SCBA required; chemical-resistant suit with boots and gloves; avoid all skin contact; eye protection mandatory

Use positive-pressure SCBA where mist, vapor, dust or fire is present. Wear chemical-resistant splash protection, gloves, boots and eye/face protection.

Isolation & Evacuation

ERG 154: isolate spill/leak area immediately for at least 25-50 meters in all directions; if tank/rail car involved in fire, isolate 800 meters in all directions and consider initial evacuation for 800 meters
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 154).

First Actions for a UN 3244 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream.
  • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Do not touch damaged containers, spilled material or residue without proper training and PPE.
  • Prevent contaminated runoff, dust, liquid and decontamination waste from spreading.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 154, SDS, shipping papers and monitoring to set isolation, evacuation and entry decisions.
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📋 Copy & Share Field Card

UN 3244 — Solids containing corrosive liquid, n.o.
HAZMAT RADIO NOTE — UN 3244 Product: Solids containing corrosive liquid, n.o.s. Class 8 / Corrosive / ERG 154 PPE: Level B minimum recommended; full face SCBA required; chemical-resistant suit with boots and gloves; avoid all skin contact; eye protection mandatory ISOLATION: ERG 154: isolate spill/leak area immediately for at least 25-50 meters in all directions; if tank/rail car involved in fire, isolate 800 meters in all directions and consider initial evacuation for 800 meters ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3244 — Solids containing corrosive liquid, n.o.s. Class: 8 | Placard: Corrosive | ERG Guide: 154 Appearance: Variable appearance depending on specific formulation. Solid material impregnated with or containing corrosive liquid components. May be granular, powder, or formed solid. Corrosive properties derived from absorbed or encapsulated liquid phase. Water Reactivity: May react depending on corrosive component; contact may release corrosive liquids or fumes; use caution with water Extinguishing: Use agents compatible with the contained liquid and solid carrier. Cool packages from protection and contain toxic/corrosive runoff. PPE: Level B minimum recommended; full face SCBA required; chemical-resistant suit with boots and gloves; avoid all skin contact; eye protection mandatory Isolation: ERG 154: isolate spill/leak area immediately for at least 25-50 meters in all directions; if tank/rail car involved in fire, isolate 800 meters in all directions and consider initial evacuation for 800 meters — Key Hazards — • CORROSIVE liquid absorbed or contained in solid material, n.o.s.; contact can burn eyes, skin and respiratory tissue. • Damaged packages can leak corrosive liquid from absorbent, matrix or article contents. • Solid carrier may hide the amount of free liquid present. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream. • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/solids-containing-corrosive-liquid-un-3244 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3244 Solids containing corrosive liquid, n.o.s. Cls8 ERG154 | allfirefighter.com/hazmat/un/solids-containing-corrosive-liquid-un-3244SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/solids-containing-corrosive-liquid-un-3244

Related UN Numbers in Class 8

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3244

UN 3244 is Solids containing corrosive liquid, n.o.s., assigned to ERG Guide 154.

Flammability depends on the contained material or package; verify SDS and shipping papers.

CORROSIVE liquid absorbed or contained in solid material, n.o.s.; contact can burn eyes, skin and respiratory tissue. Damaged packages can leak corrosive liquid from absorbent, matrix or article contents. Solid carrier may hide the amount of free liquid present.

Use positive-pressure SCBA where mist, vapor, dust or fire is present. Wear chemical-resistant splash protection, gloves, boots and eye/face protection.

Use agents compatible with the contained liquid and solid carrier. Cool packages from protection and contain toxic/corrosive runoff.

The solid carrier may hide free liquid, so damaged packages can leak toxic or corrosive contents unexpectedly.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.