☣️ UN 0075 • CLASS 1

UN 0075 — Diethyleneglycol dinitrate, desensitized

Placard: Explosive 1.1D. ERG Guide 112. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 0075, Diethyleneglycol dinitrate (DEGN) desensitized, is a Class 1 explosive liquid placarded as Explosive 1.1D, indicating a mass explosion hazard. This desensitized formulation contains phlegmatizing agents to reduce sensitivity, but it remains capable of simultaneous full-load detonation under adverse conditions.

Hazard overview: UN 0075 presents a mass explosion hazard in which the entire load may detonate simultaneously, producing severe blast overpressure and fragmentation. The material is sensitive to heat, shock, and friction, making any ignition source or mechanical disturbance in its vicinity extremely dangerous.

Response guidance: Per ERG Guide 112, isolate the incident area a minimum of 800 meters (0.5 miles) in all directions and evacuate at least 1,600 meters (1 mile) downwind if the material is involved in fire. Do not use water or foam to fight fires involving UN 0075, as these agents may spread the material; apply dry chemical or sand only from a safe standoff distance.

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UN 0075 Quick Details

UN 0075
Product name: Diethyleneglycol dinitrate, desensitized
DOT Class: 1
Placard type: Explosive 1.1D
ERG Guide: 112 (check current ERG)
Initial isolation: ERG 112: Isolate 800m (0.5 miles) all directions; evacuate 1600m (1 mile) downwind if material involved in fire; treat as mass explosion hazard

Common Hazards of UN 0075

  • Mass explosion hazard — entire load may detonate simultaneously.
  • Severe blast overpressure and fragmentation.
  • Sensitive to heat, shock, and friction.
  • Secondary fire and debris hazard.

Chemical Identity & Physical Properties

Diethyleneglycol dinitrate desensitized is a colorless to pale yellow oily liquid with a weak, sweet odor, rendered less shock-sensitive by incorporated phlegmatizing agents.

Also known asDEGNDiglycol dinitrate2,2'-Oxybis(ethanol) dinitrateDiethylene glycol dinitrate desensitizedNitroglycol dinitrate
CAS Number693-21-0
AppearanceColorless to pale yellow oily liquid with a weak, sweet odor. Desensitized formulation contains phlegmatizing agents to reduce sensitivity.
Flash PointNot applicable (explosive liquid)
Boiling PointDecomposes at approximately 159C (318F) before boiling
Vapor Density2.4 (heavier than air)
Water ReactivitySlightly soluble in water; no violent reaction but contamination may affect stability
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 0075

Extinguishing Media

DO NOT USE WATER OR FOAM — may spread fire; use dry chemical or sand at safe distance only

PPE Requirements

⚠️ Level A mandatory; full explosive ordnance disposal (EOD) protective gear recommended; SCBA required; avoid all static, friction, and shock

Responders must don Level A chemical protective suits with SCBA and full explosive ordnance disposal (EOD) protective gear, while strictly eliminating all sources of static, friction, and shock.

Isolation & Evacuation

ERG 112: Isolate 800m (0.5 miles) all directions; evacuate 1600m (1 mile) downwind if material involved in fire; treat as mass explosion hazard
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 112).

First Actions for a UN 0075 Incident

  • CALL 911. Then call emergency response telephone number on shipping paper.
  • Establish large isolation zone — minimum 500 meters in all directions.
  • Stage upwind, uphill; limit personnel to essential responders only.
  • Request Hazmat + law enforcement + additional resources immediately.
  • Do not fight fire — evacuate and isolate; let burn if no life safety risk.
  • Protect exposures only if safe and directed by command.
  • Consult current ERG Guide 112 and follow SOP/SOG.
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📋 Copy & Share Field Card

UN 0075 — Diethyleneglycol dinitrate, desensitized
HAZMAT RADIO NOTE — UN 0075 Product: Diethyleneglycol dinitrate, desensitized Class 1 / Explosive 1.1D / ERG 112 PPE: Level A mandatory; full explosive ordnance disposal (EOD) protective gear recommended; SCBA required; avoid all static, friction, and shock ISOLATION: ERG 112: Isolate 800m (0.5 miles) all directions; evacuate 1600m (1 mile) downwind if material involved in fire; treat as mass explosion hazard ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0075 — Diethyleneglycol dinitrate, desensitized Class: 1 | Placard: Explosive 1.1D | ERG Guide: 112 Appearance: Colorless to pale yellow oily liquid with a weak, sweet odor. Desensitized formulation contains phlegmatizing agents to reduce sensitivity. Water Reactivity: Slightly soluble in water; no violent reaction but contamination may affect stability Extinguishing: DO NOT USE WATER OR FOAM — may spread fire; use dry chemical or sand at safe distance only PPE: Level A mandatory; full explosive ordnance disposal (EOD) protective gear recommended; SCBA required; avoid all static, friction, and shock Isolation: ERG 112: Isolate 800m (0.5 miles) all directions; evacuate 1600m (1 mile) downwind if material involved in fire; treat as mass explosion hazard — Key Hazards — • Mass explosion hazard — entire load may detonate simultaneously. • Severe blast overpressure and fragmentation. • Sensitive to heat, shock, and friction. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. • Establish large isolation zone — minimum 500 meters in all directions. • Stage upwind, uphill; limit personnel to essential responders only. • Request Hazmat + law enforcement + additional resources immediately. SOURCE: allfirefighter.com/hazmat/un/diethyleneglycol-dinitrate-desensitized-un-0075 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN0075 Diethyleneglycol dinitrate, desensitized Cls1 ERG112 | allfirefighter.com/hazmat/un/diethyleneglycol-dinitrate-desensitized-un-0075SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/diethyleneglycol-dinitrate-desensitized-un-0075

Related UN Numbers in Class 1

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 0075

UN 0075 Diethyleneglycol dinitrate desensitized is classified as a Class 1.1D explosive, meaning it presents a mass explosion hazard rather than a conventional flammability hazard, and the entire load may detonate simultaneously if initiated.

Level A full encapsulation suits with SCBA and explosive ordnance disposal (EOD) protective gear are mandatory for responders handling or approaching an incident involving UN 0075.

ERG Guide 112 directs responders to isolate at least 800 meters (0.5 miles) in all directions and to evacuate a minimum of 1,600 meters (1 mile) downwind if UN 0075 is involved in fire.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.