☣️ UN 0074 • CLASS 1

UN 0074 — Diazodinitrophenol, wetted

Placard: Explosive 1.1A. ERG Guide 112. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 0074 is Diazodinitrophenol (DDNP), wetted, a primary explosive classified as Class 1.1A with a mass explosion hazard placard. It is shipped wetted with water or alcohol specifically to reduce its extreme sensitivity to heat, shock, and friction.

Hazard overview: UN 0074 presents a mass explosion hazard in which the entire load may detonate simultaneously, producing severe blast overpressure and fragmentation. If the wetting agent has evaporated and the material has dried out, it becomes highly sensitive and must be treated as an immediate mass detonation hazard.

Response guidance: Isolate a minimum of 500 meters in all directions upon arrival, and expand the evacuation zone to 1,600 meters downwind if fire is involved or imminent. Do not apply foam or direct water streams to the material; instead, use water spray from a safe distance only to maintain wetting if approach is possible.

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UN 0074 Quick Details

UN 0074
Product name: Diazodinitrophenol, wetted
DOT Class: 1
Placard type: Explosive 1.1A
ERG Guide: 112 (check current ERG)
Initial isolation: ERG 112: isolate 500m in all directions initially; evacuate 1600m downwind if fire involved; if material has dried out, treat as mass detonation hazard and evacuate 800m minimum

Common Hazards of UN 0074

  • Mass explosion hazard — entire load may detonate simultaneously.
  • Severe blast overpressure and fragmentation.
  • Sensitive to heat, shock, and friction.
  • Secondary fire and debris hazard.

Chemical Identity & Physical Properties

Diazodinitrophenol appears as a yellow to orange crystalline solid or powder with no odor or a slight characteristic odor, and is highly sensitive to detonation when dry.

Also known asDDNPDinolDiazo dinitrophenol2-Diazo-4,6-dinitrophenolExplosive D
CAS Number87-31-0
AppearanceYellow to orange crystalline solid or powder. Odorless or slight characteristic odor. Highly sensitive explosive when dry; shipped wetted with water or alcohol to reduce sensitivity.
Flash PointNot applicable (explosive solid)
Boiling PointNot applicable (decomposes explosively)
Vapor DensityNot applicable (solid)
Water ReactivityNo significant reaction with water; wetting agent keeps material desensitized
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 0074

Extinguishing Media

Do not use foam or water streams directly on material; use water spray from distance to keep wetted if safe to approach

PPE Requirements

⚠️ Level A with SCBA required; approach only if material remains wetted; do not handle if dried out; remote operations preferred

Level A personal protective equipment with SCBA is required for UN 0074 incidents, and personnel must not handle the material if it appears dried out, with remote operations strongly preferred.

Isolation & Evacuation

ERG 112: isolate 500m in all directions initially; evacuate 1600m downwind if fire involved; if material has dried out, treat as mass detonation hazard and evacuate 800m minimum
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 112).

First Actions for a UN 0074 Incident

  • CALL 911. Then call emergency response telephone number on shipping paper.
  • Establish large isolation zone — minimum 500 meters in all directions.
  • Stage upwind, uphill; limit personnel to essential responders only.
  • Request Hazmat + law enforcement + additional resources immediately.
  • Do not fight fire — evacuate and isolate; let burn if no life safety risk.
  • Protect exposures only if safe and directed by command.
  • Consult current ERG Guide 112 and follow SOP/SOG.
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📋 Copy & Share Field Card

UN 0074 — Diazodinitrophenol, wetted
HAZMAT RADIO NOTE — UN 0074 Product: Diazodinitrophenol, wetted Class 1 / Explosive 1.1A / ERG 112 PPE: Level A with SCBA required; approach only if material remains wetted; do not handle if dried out; remote operations preferred ISOLATION: ERG 112: isolate 500m in all directions initially; evacuate 1600m downwind if fire involved; if material has dried out, treat as mass detonation hazard and evacuate 800m minimum ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0074 — Diazodinitrophenol, wetted Class: 1 | Placard: Explosive 1.1A | ERG Guide: 112 Appearance: Yellow to orange crystalline solid or powder. Odorless or slight characteristic odor. Highly sensitive explosive when dry; shipped wetted with water or alcohol to reduce sensitivity. Water Reactivity: No significant reaction with water; wetting agent keeps material desensitized Extinguishing: Do not use foam or water streams directly on material; use water spray from distance to keep wetted if safe to approach PPE: Level A with SCBA required; approach only if material remains wetted; do not handle if dried out; remote operations preferred Isolation: ERG 112: isolate 500m in all directions initially; evacuate 1600m downwind if fire involved; if material has dried out, treat as mass detonation hazard and evacuate 800m minimum — Key Hazards — • Mass explosion hazard — entire load may detonate simultaneously. • Severe blast overpressure and fragmentation. • Sensitive to heat, shock, and friction. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. • Establish large isolation zone — minimum 500 meters in all directions. • Stage upwind, uphill; limit personnel to essential responders only. • Request Hazmat + law enforcement + additional resources immediately. SOURCE: allfirefighter.com/hazmat/un/diazodinitrophenol-wetted-un-0074 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN0074 Diazodinitrophenol, wetted Cls1 ERG112 | allfirefighter.com/hazmat/un/diazodinitrophenol-wetted-un-0074SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/diazodinitrophenol-wetted-un-0074

Related UN Numbers in Class 1

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 0074

UN 0074 Diazodinitrophenol is classified as a Class 1.1A mass detonation explosive, not simply flammable, meaning the entire load can detonate simultaneously under heat, shock, or friction.

For UN 0074, isolate at least 500 meters in all directions initially, and evacuate at least 1,600 meters downwind if fire is involved, or a minimum of 800 meters if the material has dried out.

Level A protective equipment with SCBA is required for UN 0074 response, and personnel should only approach if the material is confirmed to still be wetted, with remote handling operations used whenever possible.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.