☣️ UN 2435 • CLASS 8

UN 2435 — Ethylphenyldichlorosilane

Placard: Corrosive. ERG Guide 156. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2435 is Ethylphenyldichlorosilane, a corrosive moisture-reactive chlorosilane assigned to ERG Guide 156. Water or moist air releases HCl fumes and heat.

Hazard overview: CORROSIVE moisture-reactive chlorosilane; liquid or vapor contact can cause severe burns. Reacts with water or moist air, releasing hydrogen chloride fumes and heat. Combustible material: may burn but does not ignite readily.

Response guidance: For UN 2435, isolate the spill, stay upwind and use SCBA with chemical protection. Control moisture contact, contain acidic runoff and use dry compatible agents under SDS and ERG 156 guidance.

Firefighter training notes: Training for UN 2435 should emphasize water-reactive corrosive fuming, HCl hazards, dry-agent selection, Level A/B decisions, decontamination and acidic runoff control. Use ERG 156, SDS and local SOP.

Regulatory context: Ethylphenyldichlorosilane is regulated as a hazardous material for transport and emergency response. Storage, exposure, spill reporting, waste and fire-code duties depend on quantity, concentration and jurisdiction; verify shipping papers, SDS and local authority requirements.

Storage & handling: Ethylphenyldichlorosilane should be stored dry in tightly closed compatible containers away from water, moisture, bases, oxidizers/reducing agents where incompatible, heat and unauthorized access. Provide secondary containment.

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UN 2435 Quick Details

UN 2435
Product name: Ethylphenyldichlorosilane
DOT Class: 8
Placard type: Corrosive
ERG Guide: 156 (check current ERG)
Initial isolation: ERG 156: isolate spill 25m (75ft) all directions; for large spill isolate 50m (150ft) all directions. Evacuate immediate area if fire involves containers.

Common Hazards of UN 2435

  • CORROSIVE moisture-reactive chlorosilane; liquid or vapor contact can cause severe burns.
  • Reacts with water or moist air, releasing hydrogen chloride fumes and heat.
  • Combustible material: may burn but does not ignite readily.
  • Vapors are heavier than air and may collect in low or confined areas.
  • Fire may produce hydrogen chloride, silicon oxides and other toxic/corrosive gases.
  • Runoff may be acidic, corrosive and contaminated with hydrolysis products.
  • Containers may rupture when heated or contaminated with water.

Chemical Identity & Physical Properties

Colorless to pale yellow liquid with a pungent, irritating odor. Corrosive liquid that fumes in moist air.

Also known asEthylphenylsilicon dichlorideDichloroethylphenylsilanePhenylethyldichlorosilaneEPDCS
CAS Number1125-27-5
AppearanceColorless to pale yellow liquid with a pungent, irritating odor. Corrosive liquid that fumes in moist air.
Flash Point99°C (210°F)
Boiling Point215-220°C (419-428°F)
Vapor Density7.2 (heavier than air)
Water ReactivityReacts violently with water releasing hydrochloric acid fumes and heat. Do not use water directly on material.
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2435

Extinguishing Media

Use dry chemical, CO2, dry sand or SDS-approved media. Water spray may cool exposed containers from a protected distance, but direct water can increase corrosive fuming.

PPE Requirements

⚠️ Level B minimum with full-face SCBA; Level A if vapor concentrations are high or splashing likely. Chemical-resistant suit required.

Use positive-pressure SCBA and chemical-resistant protective clothing. Level A may be needed for heavy vapor, fuming, splash risk or unknown concentrations.

Isolation & Evacuation

ERG 156: isolate spill 25m (75ft) all directions; for large spill isolate 50m (150ft) all directions. Evacuate immediate area if fire involves containers.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 156).

First Actions for a UN 2435 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream.
  • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Keep water contact controlled because moisture can increase heat release, corrosive fuming or ignition.
  • Do not touch damaged containers or spilled material without proper training and PPE.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 156, SDS, shipping papers and monitoring to set isolation, evacuation and entry decisions.
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📋 Copy & Share Field Card

UN 2435 — Ethylphenyldichlorosilane
HAZMAT RADIO NOTE — UN 2435 Product: Ethylphenyldichlorosilane Class 8 / Corrosive / ERG 156 PPE: Level B minimum with full-face SCBA; Level A if vapor concentrations are high or splashing likely. Chemical-resistant suit required. ISOLATION: ERG 156: isolate spill 25m (75ft) all directions; for large spill isolate 50m (150ft) all directions. Evacuate immediate area if fire involves containers. ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2435 — Ethylphenyldichlorosilane Class: 8 | Placard: Corrosive | ERG Guide: 156 Appearance: Colorless to pale yellow liquid with a pungent, irritating odor. Corrosive liquid that fumes in moist air. Water Reactivity: Reacts violently with water releasing hydrochloric acid fumes and heat. Do not use water directly on material. Extinguishing: Use dry chemical, CO2, dry sand or SDS-approved media. Water spray may cool exposed containers from a protected distance, but direct water can increase corrosive fuming. PPE: Level B minimum with full-face SCBA; Level A if vapor concentrations are high or splashing likely. Chemical-resistant suit required. Isolation: ERG 156: isolate spill 25m (75ft) all directions; for large spill isolate 50m (150ft) all directions. Evacuate immediate area if fire involves containers. — Key Hazards — • CORROSIVE moisture-reactive chlorosilane; liquid or vapor contact can cause severe burns. • Reacts with water or moist air, releasing hydrogen chloride fumes and heat. • Combustible material: may burn but does not ignite readily. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream. • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/ethylphenyldichlorosilane-un-2435 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2435 Ethylphenyldichlorosilane Cls8 ERG156 | allfirefighter.com/hazmat/un/ethylphenyldichlorosilane-un-2435SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/ethylphenyldichlorosilane-un-2435

Related UN Numbers in Class 8

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2435

UN 2435 is Ethylphenyldichlorosilane, assigned to ERG Guide 156.

It is combustible but does not ignite readily; toxic/corrosive exposure and fire decomposition products are the main hazards.

CORROSIVE moisture-reactive chlorosilane; liquid or vapor contact can cause severe burns. Reacts with water or moist air, releasing hydrogen chloride fumes and heat. Combustible material: may burn but does not ignite readily.

Use positive-pressure SCBA and chemical-resistant protective clothing. Level A may be needed for heavy vapor, fuming, splash risk or unknown concentrations.

Use dry chemical, CO2, dry sand or SDS-approved media. Water spray may cool exposed containers from a protected distance, but direct water can increase corrosive fuming.

Moisture can produce heat, corrosive acidic solution or toxic/corrosive fumes; water use should be controlled by incident command.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.