☣️ UN 0333 • CLASS 1

UN 0333 — Fireworks

Placard: Explosive 1.1G. ERG Guide 112. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 0333 Fireworks are Class 1 explosive pyrotechnic devices classified under Placard Explosive 1.1G, indicating a mass explosion hazard capable of detonating an entire shipment simultaneously. These devices contain mixtures of oxidizers, fuels, and metal compounds sensitive to heat, shock, and friction, making them among the most dangerous materials encountered in transport emergencies.

Hazard overview: The primary danger of UN 0333 is mass detonation — a single ignition event can cause the entire load to explode simultaneously, generating severe blast overpressure and high-velocity fragmentation capable of causing casualties at significant distances. Certain compositions contain water-reactive metals such as magnesium or aluminum, meaning even suppression attempts can trigger unpredictable reactions or reignition.

Response guidance: ERG Guide 112 requires immediate isolation of 500 meters (1,640 ft) in all directions; if fire or explosion occurs, evacuate a full 1,600-meter (1-mile) radius and consider larger distances for bulk quantities. Responders must not attempt close-range firefighting — withdraw immediately if fire involves the cargo and approach only from upwind, protected positions.

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UN 0333 Quick Details

UN 0333
Product name: Fireworks
DOT Class: 1
Placard type: Explosive 1.1G
ERG Guide: 112 (check current ERG)
Initial isolation: ERG 112: Isolate 500m (1640 ft) in all directions. Evacuate 1600m (1 mile) radius if fire or explosion occurs. Consider evacuation of greater distance if large quantities involved.

Common Hazards of UN 0333

  • Mass explosion hazard — entire load may detonate simultaneously.
  • Severe blast overpressure and fragmentation.
  • Sensitive to heat, shock, and friction.
  • Secondary fire and debris hazard.

Chemical Identity & Physical Properties

UN 0333 Fireworks are multi-colored solid pyrotechnic mixtures packaged in cardboard tubes, spheres, or similar consumer or display containers that may emit smoke and varied odors upon ignition.

Also known asPyrotechnicsPyrotechnic devicesRecreational fireworksConsumer fireworksDisplay fireworks
AppearanceVarious colored solid mixtures containing oxidizers, fuels, and metal compounds. Packaged in cardboard tubes, spheres, or other containers. May emit smoke and various odors when ignited.
Flash PointNot applicable (explosive composition)
Boiling PointNot applicable (decomposes/explodes when heated)
Vapor DensityNot applicable (solid)
Water ReactivitySome compositions may contain water-reactive metals (magnesium, aluminum). Water application may cause unpredictable reactions or reignition.
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 0333

Extinguishing Media

Do not use water or foam. Use dry chemical, sand, or earth from a distance. Flooding amounts of water may be used from safe location.

PPE Requirements

⚠️ Full structural firefighting gear with SCBA. Withdraw immediately if fire involves cargo. Approach from upwind/protected location due to blast and fragmentation hazard.

Full structural firefighting gear with SCBA is required as a minimum, but responders should prioritize withdrawal over engagement due to blast overpressure and fragmentation risk.

Isolation & Evacuation

ERG 112: Isolate 500m (1640 ft) in all directions. Evacuate 1600m (1 mile) radius if fire or explosion occurs. Consider evacuation of greater distance if large quantities involved.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 112).

First Actions for a UN 0333 Incident

  • CALL 911. Then call emergency response telephone number on shipping paper.
  • Establish large isolation zone — minimum 500 meters in all directions.
  • Stage upwind, uphill; limit personnel to essential responders only.
  • Request Hazmat + law enforcement + additional resources immediately.
  • Do not fight fire — evacuate and isolate; let burn if no life safety risk.
  • Protect exposures only if safe and directed by command.
  • Consult current ERG Guide 112 and follow SOP/SOG.
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📋 Copy & Share Field Card

UN 0333 — Fireworks
HAZMAT RADIO NOTE — UN 0333 Product: Fireworks Class 1 / Explosive 1.1G / ERG 112 PPE: Full structural firefighting gear with SCBA. Withdraw immediately if fire involves cargo. Approach from upwind/protected location due to blast and fragmentation hazard. ISOLATION: ERG 112: Isolate 500m (1640 ft) in all directions. Evacuate 1600m (1 mile) radius if fire or explosion occurs. Consider evacuation of greater distance if large quantities involved. ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0333 — Fireworks Class: 1 | Placard: Explosive 1.1G | ERG Guide: 112 Appearance: Various colored solid mixtures containing oxidizers, fuels, and metal compounds. Packaged in cardboard tubes, spheres, or other containers. May emit smoke and various odors when ignited. Water Reactivity: Some compositions may contain water-reactive metals (magnesium, aluminum). Water application may cause unpredictable reactions or reignition. Extinguishing: Do not use water or foam. Use dry chemical, sand, or earth from a distance. Flooding amounts of water may be used from safe location. PPE: Full structural firefighting gear with SCBA. Withdraw immediately if fire involves cargo. Approach from upwind/protected location due to blast and fragmentation hazard. Isolation: ERG 112: Isolate 500m (1640 ft) in all directions. Evacuate 1600m (1 mile) radius if fire or explosion occurs. Consider evacuation of greater distance if large quantities involved. — Key Hazards — • Mass explosion hazard — entire load may detonate simultaneously. • Severe blast overpressure and fragmentation. • Sensitive to heat, shock, and friction. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. • Establish large isolation zone — minimum 500 meters in all directions. • Stage upwind, uphill; limit personnel to essential responders only. • Request Hazmat + law enforcement + additional resources immediately. SOURCE: allfirefighter.com/hazmat/un/fireworks-un-0333 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN0333 Fireworks Cls1 ERG112 | ERG 112: Isolate 500m (1640 ft) in all directions. Evacuate 1600m (1 mile) radiu | allfirefighter.com/hazmat/un/fireworks-un-0333SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/fireworks-un-0333

Related UN Numbers in Class 1

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 0333

Yes — UN 0333 is classified Explosive 1.1G, meaning the entire load can detonate simultaneously in a single mass explosion event.

Full structural firefighting gear with SCBA is required, though immediate withdrawal is strongly preferred over close-range intervention when fire involves the cargo.

Water and foam should generally not be used because certain fireworks compositions contain water-reactive metals like magnesium or aluminum that can cause unpredictable reactions or reignition.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.