UN 1806 — Phosphorus pentachloride
Placard: Corrosive. ERG Guide 137. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
UN 1806 is Phosphorus pentachloride, a toxic corrosive phosphorus halide assigned to ERG Guide 137. Water or moist air can trigger strong heat release and dense corrosive hydrogen halide fumes.
Hazard overview: UN 1806 presents violent water reaction, toxic/corrosive fume, heavy vapor and acidic-runoff hazards. Avoid water and foam on the product unless specialist guidance confirms a safe use.
Response guidance: For a UN 1806 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 137. Establish incident command, isolate the area, stay upwind, prevent incompatible contact, control runoff and choose entry or fire-control actions based on monitoring, SDS and local SOP.
Firefighter training notes: Training for UN 1806 should emphasize violent water reaction, hydrogen halide/phosphoric acid fuming, dry-agent selection, downwind vapor control and decontamination. Use ERG 137, SDS and hazmat SOP.
Regulatory context: Phosphorus pentachloride is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by concentration, formulation, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.
Storage & handling: Phosphorus pentachloride should be stored in tightly closed compatible containers in a cool, dry, well-ventilated area away from water, moisture, bases, oxidizers/reducing agents where incompatible, heat and unauthorized access. Protect containers from corrosion, leakage and contamination.
UN 1806 Quick Details
Common Hazards of UN 1806
- TOXIC and CORROSIVE phosphorus halide; inhalation, ingestion or skin/eye contact may cause severe injury.
- Reacts violently with water or moist air, releasing heat, hydrogen chloride and phosphoric acid fumes.
- Vapors or fumes are heavier than air and may collect in low or confined areas.
- Liquid, dust, vapor or fumes can burn eyes, skin and respiratory tissue.
- Fire may produce irritating, corrosive and/or toxic gases.
- Runoff may spread acidic phosphorus/halide contamination.
- Containers may rupture or fail when heated or contaminated with water.
Chemical Identity & Physical Properties
White to pale yellow crystalline solid with a pungent, irritating odor. Fumes in moist air due to reaction with atmospheric moisture.
| Also known as | PCl5Phosphoric chloridePhosphorus(V) chloridePentachlorophosphorus |
| CAS Number | 10026-13-8 |
| Appearance | White to pale yellow crystalline solid with a pungent, irritating odor. Fumes in moist air due to reaction with atmospheric moisture. |
| Flash Point | Not applicable (non-flammable solid) |
| Boiling Point | 160C (320F) sublimes |
| Vapor Density | Not applicable (solid, but hydrolyzes to form HCl gas which is heavier than air) |
| Water Reactivity | Reacts violently with water, producing heat and toxic/corrosive hydrogen chloride and phosphoric acid fumes. Do not use water directly on material. |
Fireground Response Guidance — UN 1806
Extinguishing Media
PPE Requirements
Use positive-pressure SCBA for vapor, fume, dust, fire or confined-space exposure. Chemical-resistant gloves, boots, eye/face protection and protective clothing should be selected from SDS; Level A may be needed for close entry or unknown concentrations.
Isolation & Evacuation
First Actions for a UN 1806 Incident
- CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Avoid breathing vapors, fumes, dust, mist or spray and avoid skin or eye contact.
- Keep water and moisture away from released product unless incident command confirms a compatible cooling or control use.
- Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
- Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
- Isolate the spill or leak area and expand the perimeter if vapor, dust, fire involvement, water reaction or unknown concentration is present.
- Use ERG Guide 137, shipping papers, SDS, air monitoring and incident command for protective actions.
📋 Copy & Share Field Card
UN 1806 — Phosphorus pentachlorideUse for: Quick radio or face-to-face size-up. Short, structured, field-ready.
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.
Use for: Quick text to command or incoming units. Fits in a single SMS.