☣️ UN 1940 • CLASS 8

UN 1940 — Thioglycolic acid

Placard: Corrosive. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1940 is Thioglycolic acid, a hazardous material assigned to ERG Guide 153. Responders should verify the exact product with shipping papers, package markings and SDS before close action.

Hazard overview: UN 1940 presents hazards that depend on formulation, packaging and incident conditions. Use ERG, SDS and incident command to set isolation, PPE and control actions.

Response guidance: For a UN 1940 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 153. Establish incident command, isolate the area, stay upwind, control ignition or incompatibility hazards, prevent runoff or vapor spread and choose entry/fire-control actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1940 should emphasize exposure routes, air monitoring, PPE selection, decontamination, runoff containment and ERG/SDS verification. Use ERG 153, SDS and local SOP.

Regulatory context: Thioglycolic acid is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Thioglycolic acid should be stored in tightly closed compatible containers in a secure, cool, dry, well-ventilated hazardous-material area according to SDS and local procedures.

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UN 1940 Quick Details

UN 1940
Product name: Thioglycolic acid
DOT Class: 8
Placard type: Corrosive
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: isolate spill 25-50m all directions; for large spills isolate 100m and consider evacuation 300m downwind

Common Hazards of UN 1940

  • CORROSIVE material; inhalation, ingestion or skin/eye contact may cause severe injury.
  • Fire may produce irritating, corrosive and/or toxic gases.
  • Runoff may be corrosive and may pollute waterways.
  • Containers may rupture or fail when heated.
  • Specific hazards depend on the exact product, concentration and SDS.

Chemical Identity & Physical Properties

Clear to slightly yellow liquid with a strong, unpleasant sulfur-like or rotten egg odor. Corrosive and toxic organic acid.

Also known asMercaptoacetic acid2-Mercaptoacetic acidTGAThioglycollic acid2-Sulfanylacetic acid
CAS Number68-11-1
AppearanceClear to slightly yellow liquid with a strong, unpleasant sulfur-like or rotten egg odor. Corrosive and toxic organic acid.
Flash Point129C (264F)
Boiling Point123C (253F) at 29 mmHg; decomposes at higher temperatures
Vapor Density3.2 (heavier than air)
Water ReactivitySoluble in water; no violent reaction but solution is corrosive and toxic
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1940

Extinguishing Media

Use extinguishing agents compatible with the exact product and SDS; cool exposed containers from a protected position when safe.

PPE Requirements

⚠️ Level B minimum with full face respirator; nitrile or butyl rubber gloves required; SCBA recommended in confined spaces or significant releases

Use protective equipment selected from SDS, monitoring results and incident command.

Isolation & Evacuation

ERG 153: isolate spill 25-50m all directions; for large spills isolate 100m and consider evacuation 300m downwind
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 1940 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust, mist, smoke or gas and avoid skin or eye contact.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if vapor, dust, fire involvement, gas accumulation or unknown concentration is present.
  • Use ERG Guide 153, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1940 — Thioglycolic acid
HAZMAT RADIO NOTE — UN 1940 Product: Thioglycolic acid Class 8 / Corrosive / ERG 153 PPE: Level B minimum with full face respirator; nitrile or butyl rubber gloves required; SCBA recommended in confined spaces or significant releases ISOLATION: ERG 153: isolate spill 25-50m all directions; for large spills isolate 100m and consider evacuation 300m downwind ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1940 — Thioglycolic acid Class: 8 | Placard: Corrosive | ERG Guide: 153 Appearance: Clear to slightly yellow liquid with a strong, unpleasant sulfur-like or rotten egg odor. Corrosive and toxic organic acid. Water Reactivity: Soluble in water; no violent reaction but solution is corrosive and toxic Extinguishing: Use extinguishing agents compatible with the exact product and SDS; cool exposed containers from a protected position when safe. PPE: Level B minimum with full face respirator; nitrile or butyl rubber gloves required; SCBA recommended in confined spaces or significant releases Isolation: ERG 153: isolate spill 25-50m all directions; for large spills isolate 100m and consider evacuation 300m downwind — Key Hazards — • CORROSIVE material; inhalation, ingestion or skin/eye contact may cause severe injury. • Fire may produce irritating, corrosive and/or toxic gases. • Runoff may be corrosive and may pollute waterways. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust, mist, smoke or gas and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/thioglycolic-acid-un-1940 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1940 Thioglycolic acid Cls8 ERG153 | allfirefighter.com/hazmat/un/thioglycolic-acid-un-1940SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/thioglycolic-acid-un-1940

Related UN Numbers in Class 8

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1940

UN 1940 is Thioglycolic acid, a hazardous material assigned to ERG Guide 153.

Flammability depends on the exact material and SDS; verify before action.

ERG Guide 153 applies to UN 1940 for initial isolation, protective actions and first response guidance.

UN 1940 presents hazards that depend on formulation, packaging and incident conditions. Use ERG, SDS and incident command to set isolation, PPE and control actions.

Use protective equipment selected from SDS, monitoring results and incident command.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.