☣️ UN 1840 • CLASS 8

UN 1840 — Zinc chloride, solution

Placard: Corrosive. ERG Guide 154. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1840 is Zinc chloride, solution, a corrosive hazardous material assigned to ERG Guide 154. Responders should verify the exact product with shipping papers, package markings and SDS before close action.

Hazard overview: UN 1840 presents corrosive exposure hazards and may create toxic/corrosive gases or runoff in fire or incompatible contact. Use ERG, SDS and incident command to set isolation, PPE and control actions.

Response guidance: For a UN 1840 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 154. Establish incident command, isolate the area, stay upwind, prevent incompatible contact, control runoff and choose entry or fire-control actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1840 should emphasize corrosive/toxic exposure routes, water incompatibility where applicable, air monitoring, PPE selection, decontamination and runoff containment. Use ERG 154, SDS and local SOP.

Regulatory context: Zinc chloride, solution is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by concentration, formulation, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Zinc chloride, solution should be stored in tightly closed compatible containers in a secure, cool, dry, well-ventilated hazardous-material area according to SDS and local procedures.

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UN 1840 Quick Details

UN 1840
Product name: Zinc chloride, solution
DOT Class: 8
Placard type: Corrosive
ERG Guide: 154 (check current ERG)
Initial isolation: ERG 154: isolate spill 25-50m in all directions; for large spills isolate 800m downwind

Common Hazards of UN 1840

  • CORROSIVE material; inhalation, ingestion or skin/eye contact may cause severe injury.
  • Fire may produce irritating, corrosive and/or toxic gases.
  • Runoff may be corrosive and may pollute waterways.
  • Containers may rupture or fail when heated.
  • Specific hazards depend on the exact product, concentration and SDS.

Chemical Identity & Physical Properties

Colorless to white crystalline solid dissolved in water, forming a clear to slightly cloudy solution. Odorless. Highly hygroscopic.

Also known asButter of zincZinc dichlorideZinc butterChloride of zinc
CAS Number7646-85-7
AppearanceColorless to white crystalline solid dissolved in water, forming a clear to slightly cloudy solution. Odorless. Highly hygroscopic.
Flash PointNot applicable (non-flammable aqueous solution)
Boiling PointApproximately 100C (212F) for dilute solutions, higher for concentrated solutions
Vapor DensityNot applicable (aqueous solution)
Water ReactivityAlready in solution; dissolves readily in water with heat generation when concentrated
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1840

Extinguishing Media

Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce vapors only when splashing and corrosive/toxic runoff can be controlled.

PPE Requirements

⚠️ Level B minimum; chemical-resistant suit, gloves, and boots required; SCBA for vapor exposure; face shield and eye protection mandatory

Use positive-pressure SCBA for dust, vapor, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing selected from SDS for corrosive contact.

Isolation & Evacuation

ERG 154: isolate spill 25-50m in all directions; for large spills isolate 800m downwind
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 154).

First Actions for a UN 1840 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust, mist or spray and avoid skin or eye contact.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if vapor, dust, fire involvement, water reaction or unknown concentration is present.
  • Use ERG Guide 154, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1840 — Zinc chloride, solution
HAZMAT RADIO NOTE — UN 1840 Product: Zinc chloride, solution Class 8 / Corrosive / ERG 154 PPE: Level B minimum; chemical-resistant suit, gloves, and boots required; SCBA for vapor exposure; face shield and eye protection mandatory ISOLATION: ERG 154: isolate spill 25-50m in all directions; for large spills isolate 800m downwind ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1840 — Zinc chloride, solution Class: 8 | Placard: Corrosive | ERG Guide: 154 Appearance: Colorless to white crystalline solid dissolved in water, forming a clear to slightly cloudy solution. Odorless. Highly hygroscopic. Water Reactivity: Already in solution; dissolves readily in water with heat generation when concentrated Extinguishing: Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce vapors only when splashing and corrosive/toxic runoff can be controlled. PPE: Level B minimum; chemical-resistant suit, gloves, and boots required; SCBA for vapor exposure; face shield and eye protection mandatory Isolation: ERG 154: isolate spill 25-50m in all directions; for large spills isolate 800m downwind — Key Hazards — • CORROSIVE material; inhalation, ingestion or skin/eye contact may cause severe injury. • Fire may produce irritating, corrosive and/or toxic gases. • Runoff may be corrosive and may pollute waterways. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust, mist or spray and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/zinc-chloride-solution-un-1840 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1840 Zinc chloride, solution Cls8 ERG154 | allfirefighter.com/hazmat/un/zinc-chloride-solution-un-1840SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/zinc-chloride-solution-un-1840

Related UN Numbers in Class 8

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1840

UN 1840 is Zinc chloride, solution, a hazardous material assigned to ERG Guide 154.

Flammability depends on the exact material and SDS; corrosive exposure is the main concern.

ERG Guide 154 applies to UN 1840 for initial isolation, protective actions and first response guidance.

UN 1840 presents corrosive exposure hazards and may create toxic/corrosive gases or runoff in fire or incompatible contact. Use ERG, SDS and incident command to set isolation, PPE and control actions.

Use positive-pressure SCBA for dust, vapor, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing selected from SDS for corrosive contact.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.