☣️ UN 1372 • CLASS 4

UN 1372 — Fibers, animal or vegetable, burnt, wet or damp

Placard: Spontaneously Combustible. ERG Guide 133. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1372 is Fibers, animal or vegetable, burnt, wet or damp, a self-heating or spontaneously combustible material assigned to ERG Guide 133. The main hazard is hidden heat buildup that can lead to smoldering, open flame or re-ignition.

Hazard overview: UN 1372 presents self-heating, smoldering fire and re-ignition hazards. Disturbing hot material can introduce oxygen and intensify burning, while smoke may contain carbon monoxide and irritating combustion products.

Response guidance: For a UN 1372 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 133. Establish incident command, isolate the area, stay upwind, avoid unnecessary disturbance of powder, piles or damaged packaging, and use only extinguishing agents compatible with the specific material.

Firefighter training notes: Training for UN 1372 should emphasize self-heating, smoldering piles, oxygen exposure during overhaul, thermal monitoring and re-ignition. Common errors include opening hot piles too aggressively and ending operations before deep-seated heat is controlled.

Regulatory context: Fibers, animal or vegetable, burnt, wet or damp is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Fibers, animal or vegetable, burnt, wet or damp should be stored to prevent self-heating, oil/moisture contamination where relevant, compacted hot spots and ignition exposure. Keep piles, bales or packages ventilated where appropriate and inspect for heat, odor or smoke according to facility procedures.

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UN 1372 Quick Details

UN 1372
Product name: Fibers, animal or vegetable, burnt, wet or damp
DOT Class: 4
Placard type: Spontaneously Combustible
ERG Guide: 133 (check current ERG)
Initial isolation: ERG 133: isolate spill area minimum 25m in all directions; if material is dry or smoldering, treat as active fire hazard with extended isolation

Common Hazards of UN 1372

  • May self-heat and ignite when damp, oily, contaminated, compacted or stored in bulk.
  • Piles, sacks, bales or rolls may retain heat and smolder internally before open flame is visible.
  • Disturbing hot material may introduce oxygen and intensify smoldering or flame spread.
  • Fire may produce irritating or toxic smoke including carbon monoxide.
  • Runoff from fire control may carry organic or oily contamination.
  • Large quantities may require prolonged overhaul and thermal monitoring.
  • Material may re-ignite after apparent extinguishment.

Chemical Identity & Physical Properties

Blackened or darkened fibrous material from animal sources (wool, hair, silk) or plant sources (cotton, jute, hemp) that has been partially burned and is wet or damp. Appears as charred, friable mass with residual moisture.

Also known asburnt animal fibersburnt vegetable fiberswet animal fibersdamp plant fiberscharred organic fibersscorched textile waste
AppearanceBlackened or darkened fibrous material from animal sources (wool, hair, silk) or plant sources (cotton, jute, hemp) that has been partially burned and is wet or damp. Appears as charred, friable mass with residual moisture.
Flash PointNot applicable (already partially combusted material)
Boiling PointNot applicable (solid fibrous material)
Vapor DensityNot applicable (solid material)
Water ReactivityNo significant reaction with water; moisture actually reduces fire hazard by lowering ignitability
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1372

Extinguishing Media

Use water spray, fog, foam, dry chemical, CO2 or sand only when compatible with the specific material and incident command; avoid spreading dust, oil or burning material.

PPE Requirements

⚠️ Level D minimum for handling wet material; Level C with SCBA if dry or smoldering; avoid inhalation of dust from charred fibers

Use SCBA for smoke, smoldering material, dust or confined-space operations. Wear protective clothing and gloves appropriate for hot organic material, contaminated runoff and extended overhaul conditions.

Isolation & Evacuation

ERG 133: isolate spill area minimum 25m in all directions; if material is dry or smoldering, treat as active fire hazard with extended isolation
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 133).

First Actions for a UN 1372 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Check for heat, smoke, odor or smoldering before disturbing piles, bales, sacks or containers.
  • Avoid breaking apart hot material unless incident command has a controlled plan for exposure, extinguishment and overhaul.
  • Isolate the area and remove ignition sources if it is safe to do so.
  • Use thermal imaging, monitoring and extended overhaul where available.
  • Use ERG Guide 133, shipping papers, SDS and local SOP for protective actions and fire-control decisions.
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📋 Copy & Share Field Card

UN 1372 — Fibers, animal or vegetable, burnt, wet
HAZMAT RADIO NOTE — UN 1372 Product: Fibers, animal or vegetable, burnt, wet or damp Class 4 / Spontaneously Combustible / ERG 133 PPE: Level D minimum for handling wet material; Level C with SCBA if dry or smoldering; avoid inhalation of dust from charred fibers ISOLATION: ERG 133: isolate spill area minimum 25m in all directions; if material is dry or smoldering, treat as active fire hazard with extended isolation ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1372 — Fibers, animal or vegetable, burnt, wet or damp Class: 4 | Placard: Spontaneously Combustible | ERG Guide: 133 Appearance: Blackened or darkened fibrous material from animal sources (wool, hair, silk) or plant sources (cotton, jute, hemp) that has been partially burned and is wet or damp. Appears as charred, friable mass with residual moisture. Water Reactivity: No significant reaction with water; moisture actually reduces fire hazard by lowering ignitability Extinguishing: Use water spray, fog, foam, dry chemical, CO2 or sand only when compatible with the specific material and incident command; avoid spreading dust, oil or burning material. PPE: Level D minimum for handling wet material; Level C with SCBA if dry or smoldering; avoid inhalation of dust from charred fibers Isolation: ERG 133: isolate spill area minimum 25m in all directions; if material is dry or smoldering, treat as active fire hazard with extended isolation — Key Hazards — • May self-heat and ignite when damp, oily, contaminated, compacted or stored in bulk. • Piles, sacks, bales or rolls may retain heat and smolder internally before open flame is visible. • Disturbing hot material may introduce oxygen and intensify smoldering or flame spread. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Check for heat, smoke, odor or smoldering before disturbing piles, bales, sacks or containers. SOURCE: allfirefighter.com/hazmat/un/fibers-animal-or-vegetable-un-1372 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1372 Fibers, animal or vegetable, burnt, wet or damp Cls4 ERG133 | allfirefighter.com/hazmat/un/fibers-animal-or-vegetable-un-1372SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/fibers-animal-or-vegetable-un-1372

Related UN Numbers in Class 4

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1372

UN 1372 is Fibers, animal or vegetable, burnt, wet or damp, a hazardous material assigned to ERG Guide 133.

Yes, it can become a fire hazard through self-heating, drying, oil contamination or smoldering conditions.

ERG Guide 133 applies to UN 1372 for initial isolation, protective actions and first response guidance.

UN 1372 presents self-heating, smoldering fire and re-ignition hazards. Disturbing hot material can introduce oxygen and intensify burning, while smoke may contain carbon monoxide and irritating combustion products.

Self-heating or deep smoldering can remain inside piles, sacks, bales or rolls after visible flame is gone, so overhaul and thermal monitoring matter.

Use water spray, fog, foam, dry chemical, CO2 or sand only when compatible with the specific material and incident command; avoid spreading dust, oil or burning material.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.