☣️ UN 1564 • CLASS 6

UN 1564 — Barium compound, n.o.s.

Placard: Toxic. ERG Guide 154. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1564 is Barium compound, n.o.s., a toxic barium material assigned to ERG Guide 154. Because this is an n.o.s. entry, responders should confirm the exact barium compound before choosing cleanup or runoff controls.

Hazard overview: UN 1564 presents toxic barium dust or solution hazards. Some barium compounds may be water-soluble or oxidizing, so SDS and shipping papers should drive PPE, containment and decontamination decisions.

Response guidance: For a UN 1564 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 154. Establish incident command, isolate the area, stay upwind, prevent dust or vapor exposure, control runoff and choose entry or cleanup actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1564 should emphasize toxic metal compound exposure, dust control, PPE selection, decontamination and runoff containment. Use ERG 154, SDS and local SOP.

Regulatory context: Barium compound, n.o.s. is regulated as a toxic hazardous material. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by compound, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Barium compound, n.o.s. should be stored in tightly closed compatible containers in a secure, cool, dry, well-ventilated toxic-material area away from food, incompatible chemicals, heat and unauthorized access. Prevent dust release, leaks and contaminated runoff.

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UN 1564 Quick Details

UN 1564
Product name: Barium compound, n.o.s.
DOT Class: 6
Placard type: Toxic
ERG Guide: 154 (check current ERG)
Initial isolation: ERG 154: Initially isolate spill or leak area at least 25 meters in all directions; for large spills isolate 100+ meters; evacuate immediate area if material is on fire or involved in fire

Common Hazards of UN 1564

  • TOXIC barium compound; inhalation, ingestion or skin contact with soluble compounds may cause serious injury.
  • Dust may irritate or injure eyes, skin and respiratory tissue.
  • Some barium compounds may be oxidizers or water-soluble toxic salts; verify the exact compound from SDS.
  • Fire may produce irritating and/or toxic gases or fumes.
  • Runoff may carry toxic barium contamination to waterways.
  • Containers may rupture or fail when heated.
  • Hazards vary widely because this is a not-otherwise-specified barium entry.

Chemical Identity & Physical Properties

Physical appearance varies by compound - typically white to gray crystalline solids or powders, some may be colorless crystals. Generally odorless. Physical state at room temperature is solid for most barium compounds.

Also known asBarium salts n.o.s.Barium compounds (unspecified)Barium chemicals
AppearancePhysical appearance varies by compound - typically white to gray crystalline solids or powders, some may be colorless crystals. Generally odorless. Physical state at room temperature is solid for most barium compounds.
Flash PointNot applicable (inorganic solids)
Boiling PointVaries by compound - typically high decomposition temperatures above 800C (1472F)
Vapor DensityNot applicable (solid)
Water ReactivityVaries by compound - some barium compounds dissolve in water forming toxic solutions; barium metal reacts violently with water releasing hydrogen gas
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1564

Extinguishing Media

Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce dust only when runoff can be controlled as toxic contamination.

PPE Requirements

⚠️ Level B minimum recommended; full-face respirator with HEPA filters or SCBA; chemical-resistant suit, gloves, and boots; avoid skin contact and inhalation of dusts or fumes

Use positive-pressure SCBA for dust, vapor, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS; avoid skin contact and contaminated dust or runoff.

Isolation & Evacuation

ERG 154: Initially isolate spill or leak area at least 25 meters in all directions; for large spills isolate 100+ meters; evacuate immediate area if material is on fire or involved in fire
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 154).

First Actions for a UN 1564 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Avoid creating dust clouds; cover or contain dry material only using methods directed by SDS and incident command.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if vapor, dust, fire involvement or unknown concentration is present.
  • Use ERG Guide 154, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1564 — Barium compound, n.o.s.
HAZMAT RADIO NOTE — UN 1564 Product: Barium compound, n.o.s. Class 6 / Toxic / ERG 154 PPE: Level B minimum recommended; full-face respirator with HEPA filters or SCBA; chemical-resistant suit, gloves, and boots; avoid skin contact and inhalation of dusts or fumes ISOLATION: ERG 154: Initially isolate spill or leak area at least 25 meters in all directions; for large spills isolate 100+ meters; evacuate immediate area if material is on fire or involved in fire ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1564 — Barium compound, n.o.s. Class: 6 | Placard: Toxic | ERG Guide: 154 Appearance: Physical appearance varies by compound - typically white to gray crystalline solids or powders, some may be colorless crystals. Generally odorless. Physical state at room temperature is solid for most barium compounds. Water Reactivity: Varies by compound - some barium compounds dissolve in water forming toxic solutions; barium metal reacts violently with water releasing hydrogen gas Extinguishing: Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce dust only when runoff can be controlled as toxic contamination. PPE: Level B minimum recommended; full-face respirator with HEPA filters or SCBA; chemical-resistant suit, gloves, and boots; avoid skin contact and inhalation of dusts or fumes Isolation: ERG 154: Initially isolate spill or leak area at least 25 meters in all directions; for large spills isolate 100+ meters; evacuate immediate area if material is on fire or involved in fire — Key Hazards — • TOXIC barium compound; inhalation, ingestion or skin contact with soluble compounds may cause serious injury. • Dust may irritate or injure eyes, skin and respiratory tissue. • Some barium compounds may be oxidizers or water-soluble toxic salts; verify the exact compound from SDS. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/barium-compound-n-o-un-1564 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1564 Barium compound, n.o.s. Cls6 ERG154 | allfirefighter.com/hazmat/un/barium-compound-n-o-un-1564SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/barium-compound-n-o-un-1564

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1564

UN 1564 is Barium compound, n.o.s., a toxic hazardous material assigned to ERG Guide 154.

No. Most barium compounds in this entry are not flammable, but some may intensify fire or create toxic runoff depending on the exact compound.

ERG Guide 154 applies to UN 1564 for initial isolation, protective actions and first response guidance.

UN 1564 presents toxic barium dust or solution hazards. Some barium compounds may be water-soluble or oxidizing, so SDS and shipping papers should drive PPE, containment and decontamination decisions.

Use positive-pressure SCBA for dust, vapor, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS; avoid skin contact and contaminated dust or runoff.

This entry can cover compounds with different solubility, reactivity and toxicity, so SDS and shipping papers should guide PPE, containment and cleanup.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.