UN 1599 — Dinitrophenol, solution
Placard: Toxic. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
UN 1599 is Dinitrophenol, solution, a toxic nitroaromatic material assigned to ERG Guide 153. It may be solid, liquid, solution or molten, so skin absorption, toxic smoke and runoff are the main responder concerns.
Hazard overview: UN 1599 presents toxic skin, inhalation and ingestion hazards. It may burn or decompose under fire conditions, producing toxic nitrogen oxide smoke; molten material can also cause thermal burns.
Response guidance: For a UN 1599 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 153. Establish incident command, isolate the area, stay upwind, prevent dust or vapor exposure, control runoff and choose entry or cleanup actions based on monitoring, SDS and local SOP.
Firefighter training notes: Training for UN 1599 should emphasize toxic nitroaromatic exposure, skin absorption, molten/liquid burn potential, toxic smoke and runoff containment. Use ERG 153, SDS and local SOP.
Regulatory context: Dinitrophenol, solution is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.
Storage & handling: Dinitrophenol, solution should be stored in tightly closed compatible containers in a secure toxic-material area according to SDS and local hazardous materials procedures.
UN 1599 Quick Details
Common Hazards of UN 1599
- TOXIC nitroaromatic material; inhalation, ingestion or skin absorption may cause severe injury.
- Combustible material: may burn but does not ignite readily.
- Dust, vapor, solution or molten/liquid contact may injure eyes, skin and respiratory tissue.
- Heating or fire may produce toxic nitrogen oxides and irritating smoke.
- Runoff may carry toxic contamination to drains or waterways.
- Containers may rupture or fail when heated.
- Avoid skin contact because absorption may be significant for some nitroaromatic compounds.
- Phenolic nitro compounds can be systemically toxic through skin exposure; do not rely only on visible burns.
Chemical Identity & Physical Properties
Yellow crystalline solid dissolved in solution, typically water or organic solvent. Characteristic sweet, musty odor. Solution may be yellow to amber colored.
| Also known as | 2,4-DinitrophenolDNP2,4-DNPDinitrophenol solutionAldifen |
| CAS Number | 51-28-5 |
| Appearance | Yellow crystalline solid dissolved in solution, typically water or organic solvent. Characteristic sweet, musty odor. Solution may be yellow to amber colored. |
| Flash Point | Depends on solvent; aqueous solutions may be non-flammable, organic solvent solutions vary |
| Boiling Point | Decomposes before boiling at approximately 108C (226F) |
| Vapor Density | Not applicable (solution) |
| Water Reactivity | Soluble in water; no violent reaction but solution is toxic |
Fireground Response Guidance — UN 1599
Extinguishing Media
PPE Requirements
Use positive-pressure SCBA for vapor, dust, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS because skin absorption may be significant.
Isolation & Evacuation
First Actions for a UN 1599 Incident
- CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact.
- Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
- Avoid creating dust clouds or spreading contaminated liquid, powder, molten material or runoff.
- Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
- Isolate the spill or leak area and expand the perimeter if vapor, dust, fire involvement or unknown concentration is present.
- Use ERG Guide 153, shipping papers, SDS, air monitoring and incident command for protective actions.
📋 Copy & Share Field Card
UN 1599 — Dinitrophenol, solutionUse for: Quick radio or face-to-face size-up. Short, structured, field-ready.
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.
Use for: Quick text to command or incoming units. Fits in a single SMS.