☣️ UN 1639 • CLASS 6

UN 1639 — Mercury nucleate

Placard: Toxic. ERG Guide 151. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1639 is Mercury nucleate, a toxic mercury compound assigned to ERG Guide 151. It is usually a solid salt where dust, solution and runoff contamination are the major responder concerns.

Hazard overview: UN 1639 presents toxic mercury dust, ingestion, skin contact and contaminated-runoff hazards. Heating or fire may release mercury-containing fumes, and dry powder can contaminate clothing and equipment.

Response guidance: For a UN 1639 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 151. Establish incident command, isolate the area, stay upwind, prevent dust or vapor exposure, control runoff and choose entry or cleanup actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1639 should emphasize mercury salt toxicity, dust or solution contamination, SCBA use, runoff containment, decontamination and waste-control coordination. Use ERG 151, SDS and local SOP.

Regulatory context: Mercury nucleate is regulated as a toxic mercury hazardous material. Transportation, occupational exposure, spill reporting, waste handling, storage and environmental controls may vary by compound, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Mercury nucleate should be stored in tightly closed compatible containers in a secure, cool, dry, well-ventilated toxic-material area away from food, incompatible chemicals, heat and unauthorized access. Prevent dust release, solution leaks and mercury-contaminated runoff.

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UN 1639 Quick Details

UN 1639
Product name: Mercury nucleate
DOT Class: 6
Placard type: Toxic
ERG Guide: 151 (check current ERG)
Initial isolation: ERG 151: Isolate spill area immediately for at least 25-50 meters in all directions; increase isolation distance for large spills; evacuate area if fire involves material

Common Hazards of UN 1639

  • HIGHLY TOXIC mercury compound; may be harmful or fatal if inhaled, ingested or absorbed through skin.
  • Dust or solution can contaminate clothing, tools, equipment and runoff.
  • Fire or heating may produce toxic mercury fumes and irritating decomposition products.
  • Runoff may pollute waterways and create persistent contamination.
  • Containers may rupture or fail when heated.
  • Specific toxicity, solubility and reactivity depend on the exact mercury compound.
  • Avoid skin contact and prevent dust from becoming airborne.

Chemical Identity & Physical Properties

Appearance and physical state vary depending on specific nucleate formulation; typically solid or powder form at room temperature. Color may range from white to yellowish. Organomercury compounds often have characteristic odors.

Also known asMercury nucleateNucleated mercuryMercury nucleate complexOrganomercury nucleate compound
AppearanceAppearance and physical state vary depending on specific nucleate formulation; typically solid or powder form at room temperature. Color may range from white to yellowish. Organomercury compounds often have characteristic odors.
Flash PointNot applicable (inorganic/organometallic compound, not typically flammable)
Boiling PointNot applicable (decomposes before boiling)
Vapor DensityNot applicable (solid form under normal conditions)
Water ReactivityNo significant violent reaction with water, but may slowly hydrolyze or dissolve releasing toxic mercury species
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1639

Extinguishing Media

Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce dust only when runoff can be controlled as toxic contamination.

PPE Requirements

⚠️ Level B minimum required; SCBA mandatory; chemical-resistant suit, gloves, and boots essential to prevent any skin contact with highly toxic mercury compound

Use positive-pressure SCBA for dust, vapor, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS; prevent skin contact and mercury-contaminated dust or runoff spread.

Isolation & Evacuation

ERG 151: Isolate spill area immediately for at least 25-50 meters in all directions; increase isolation distance for large spills; evacuate area if fire involves material
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 151).

First Actions for a UN 1639 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Avoid creating dust clouds or spreading contaminated powder, solution, runoff or debris.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if dust, vapor, fire involvement or unknown concentration is present.
  • Use ERG Guide 151, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1639 — Mercury nucleate
HAZMAT RADIO NOTE — UN 1639 Product: Mercury nucleate Class 6 / Toxic / ERG 151 PPE: Level B minimum required; SCBA mandatory; chemical-resistant suit, gloves, and boots essential to prevent any skin contact with highly toxic mercury compound ISOLATION: ERG 151: Isolate spill area immediately for at least 25-50 meters in all directions; increase isolation distance for large spills; evacuate area if fire involves material ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1639 — Mercury nucleate Class: 6 | Placard: Toxic | ERG Guide: 151 Appearance: Appearance and physical state vary depending on specific nucleate formulation; typically solid or powder form at room temperature. Color may range from white to yellowish. Organomercury compounds often have characteristic odors. Water Reactivity: No significant violent reaction with water, but may slowly hydrolyze or dissolve releasing toxic mercury species Extinguishing: Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers or reduce dust only when runoff can be controlled as toxic contamination. PPE: Level B minimum required; SCBA mandatory; chemical-resistant suit, gloves, and boots essential to prevent any skin contact with highly toxic mercury compound Isolation: ERG 151: Isolate spill area immediately for at least 25-50 meters in all directions; increase isolation distance for large spills; evacuate area if fire involves material — Key Hazards — • HIGHLY TOXIC mercury compound; may be harmful or fatal if inhaled, ingested or absorbed through skin. • Dust or solution can contaminate clothing, tools, equipment and runoff. • Fire or heating may produce toxic mercury fumes and irritating decomposition products. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/mercury-nucleate-un-1639 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1639 Mercury nucleate Cls6 ERG151 | allfirefighter.com/hazmat/un/mercury-nucleate-un-1639SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/mercury-nucleate-un-1639

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1639

UN 1639 is Mercury nucleate, a hazardous material assigned to ERG Guide 151.

No. It is generally not flammable, but fire or heating can produce toxic mercury fumes.

ERG Guide 151 applies to UN 1639 for initial isolation, protective actions and first response guidance.

UN 1639 presents toxic mercury dust, ingestion, skin contact and contaminated-runoff hazards. Heating or fire may release mercury-containing fumes, and dry powder can contaminate clothing and equipment.

Use positive-pressure SCBA for dust, vapor, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS; prevent skin contact and mercury-contaminated dust or runoff spread.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.