☣️ UN 2000 • CLASS 4

UN 2000 — Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap

Placard: Flammable Solid. ERG Guide 133. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2000 is Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap, a flammable celluloid solid assigned to ERG Guide 133. It can burn rapidly and may re-ignite if hot material remains.

Hazard overview: FLAMMABLE SOLID; celluloid can ignite readily by heat, sparks or flame. May burn very rapidly and intensely once ignited. Heating can produce flammable vapors and pressure buildup in packages.

Response guidance: For a UN 2000 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 133. Establish incident command, isolate the area, stay upwind, control ignition or downwind hazards, cool exposed containers from a protected distance when appropriate and base entry decisions on monitoring and local SOP.

Firefighter training notes: Training for UN 2000 should emphasize fire behavior, exposure routes, air monitoring, PPE selection, evacuation, runoff control and ERG/SDS verification. Use ERG 133, SDS and local SOP.

Regulatory context: Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting and waste handling requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap should be stored in a cool, dry, ventilated area away from heat, sparks, flames, oxidizers and incompatible materials. Limit accumulation and protect from friction, impact and dust generation where applicable.

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UN 2000 Quick Details

UN 2000
Product name: Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap
DOT Class: 4
Placard type: Flammable Solid
ERG Guide: 133 (check current ERG)
Initial isolation: ERG 133: isolate 50m all directions; for large fire, consider evacuation 300m in all directions

Common Hazards of UN 2000

  • FLAMMABLE SOLID; celluloid can ignite readily by heat, sparks or flame.
  • May burn very rapidly and intensely once ignited.
  • Heating can produce flammable vapors and pressure buildup in packages.
  • Fire may produce irritating/toxic gases including nitrogen oxides and carbon monoxide.
  • May re-ignite after apparent extinguishment if hot material remains.
  • Friction, impact, heat or poor storage can increase ignition risk.
  • Runoff may carry burned plastic residues.

Chemical Identity & Physical Properties

Solid material appearing as colorless to pale yellow blocks, rods, rolls, sheets, or tubes. Characteristic camphor-like odor. Highly flammable thermoplastic.

Also known asCellulose nitrateNitrocellulose plasticPyroxylin plasticCelluloid film
CAS Number9004-70-0
AppearanceSolid material appearing as colorless to pale yellow blocks, rods, rolls, sheets, or tubes. Characteristic camphor-like odor. Highly flammable thermoplastic.
Flash PointNot applicable (solid)
Boiling PointNot applicable (decomposes)
Vapor DensityNot applicable (solid)
Water ReactivityNo significant reaction with water
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2000

Extinguishing Media

Use water spray/fog, dry chemical, CO2, sand or earth as appropriate for packaging and fire size. Overhaul carefully for hot material or re-ignition.

PPE Requirements

⚠️ Structural firefighters' protective clothing with SCBA for fire conditions; Level C minimum for handling intact material

Use structural firefighting PPE with SCBA for fire or smoke. For spill handling without fire, use gloves, eye protection and respiratory protection if dust or residues are present.

Isolation & Evacuation

ERG 133: isolate 50m all directions; for large fire, consider evacuation 300m in all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 133).

First Actions for a UN 2000 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, gas, smoke, mist or dust and avoid skin or eye contact.
  • Avoid friction, sparks, heat and dust generation; watch for rapid burning or re-ignition.
  • Do not touch damaged containers or spilled/released material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the release or spill area and expand the perimeter for fire involvement, vapor accumulation, cylinder/tank heating or unknown product identity.
  • Use ERG Guide 133, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 2000 — Celluloid, in block, rods, rolls, sheets
HAZMAT RADIO NOTE — UN 2000 Product: Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap Class 4 / Flammable Solid / ERG 133 PPE: Structural firefighters' protective clothing with SCBA for fire conditions; Level C minimum for handling intact material ISOLATION: ERG 133: isolate 50m all directions; for large fire, consider evacuation 300m in all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2000 — Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap Class: 4 | Placard: Flammable Solid | ERG Guide: 133 Appearance: Solid material appearing as colorless to pale yellow blocks, rods, rolls, sheets, or tubes. Characteristic camphor-like odor. Highly flammable thermoplastic. Water Reactivity: No significant reaction with water Extinguishing: Use water spray/fog, dry chemical, CO2, sand or earth as appropriate for packaging and fire size. Overhaul carefully for hot material or re-ignition. PPE: Structural firefighters' protective clothing with SCBA for fire conditions; Level C minimum for handling intact material Isolation: ERG 133: isolate 50m all directions; for large fire, consider evacuation 300m in all directions — Key Hazards — • FLAMMABLE SOLID; celluloid can ignite readily by heat, sparks or flame. • May burn very rapidly and intensely once ignited. • Heating can produce flammable vapors and pressure buildup in packages. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, gas, smoke, mist or dust and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/celluloid-in-block-rods-un-2000 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2000 Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap Cls4 ERG133 | allfirefighter.com/hazmat/un/celluloid-in-block-rods-un-2000SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/celluloid-in-block-rods-un-2000

Related UN Numbers in Class 4

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2000

UN 2000 is Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap, a hazardous material assigned to ERG Guide 133.

Yes. Celluloid is a flammable solid and can burn rapidly.

ERG Guide 133 applies to UN 2000 for initial isolation, protective actions and first response guidance.

FLAMMABLE SOLID; celluloid can ignite readily by heat, sparks or flame. May burn very rapidly and intensely once ignited. Heating can produce flammable vapors and pressure buildup in packages.

Use structural firefighting PPE with SCBA for fire or smoke. For spill handling without fire, use gloves, eye protection and respiratory protection if dust or residues are present.

Hot celluloid or scrap piles can retain heat after visible flames are out, so overhaul and monitoring are important.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.