☣️ UN 2001 • CLASS 4

UN 2001 — Cobalt naphthenates, powder

Placard: Flammable Solid. ERG Guide 133. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2001 is Cobalt naphthenates, powder, a flammable solid/powder entry assigned to ERG Guide 133. Dust generation can increase fire and exposure hazards.

Hazard overview: FLAMMABLE/combustible powder; dust may ignite by heat, sparks or flame. Dust generation may increase fire and inhalation hazards. Cobalt compound dust can irritate respiratory tract, skin and eyes and may create toxic exposure concerns.

Response guidance: For a UN 2001 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 133. Establish incident command, isolate the area, stay upwind, control ignition or downwind hazards, cool exposed containers from a protected distance when appropriate and base entry decisions on monitoring and local SOP.

Firefighter training notes: Training for UN 2001 should emphasize fire behavior, exposure routes, air monitoring, PPE selection, evacuation, runoff control and ERG/SDS verification. Use ERG 133, SDS and local SOP.

Regulatory context: Cobalt naphthenates, powder is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting and waste handling requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Cobalt naphthenates, powder should be stored in a cool, dry, ventilated area away from heat, sparks, flames, oxidizers and incompatible materials. Limit accumulation and protect from friction, impact and dust generation where applicable.

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UN 2001 Quick Details

UN 2001
Product name: Cobalt naphthenates, powder
DOT Class: 4
Placard type: Flammable Solid
ERG Guide: 133 (check current ERG)
Initial isolation: ERG 133: isolate spill area at least 25m in all directions; for large fire evacuate 800m radius

Common Hazards of UN 2001

  • FLAMMABLE/combustible powder; dust may ignite by heat, sparks or flame.
  • Dust generation may increase fire and inhalation hazards.
  • Cobalt compound dust can irritate respiratory tract, skin and eyes and may create toxic exposure concerns.
  • Fire may produce irritating/toxic smoke and metal-containing residues.
  • Runoff may carry cobalt-containing contamination.
  • Containers may rupture or fail when heated.
  • Exact dust explosibility and toxicity should be confirmed from SDS.

Chemical Identity & Physical Properties

Purple to reddish-brown powder or solid mass with a mild hydrocarbon odor. Combustible solid at room temperature.

Also known asCobalt naphthenateNaphthenic acids, cobalt saltsCobalt(II) naphthenateCobalt 2-ethylhexanoate
CAS Number61789-51-3
AppearancePurple to reddish-brown powder or solid mass with a mild hydrocarbon odor. Combustible solid at room temperature.
Flash PointNot applicable (combustible solid)
Boiling PointNot applicable (decomposes)
Vapor DensityNot applicable (solid)
Water ReactivityNo significant reaction with water, but may release heat upon dissolution
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2001

Extinguishing Media

Use water spray/fog, dry chemical, CO2, sand or earth as appropriate for packaging and fire size. Overhaul carefully for hot material or re-ignition.

PPE Requirements

⚠️ Level C minimum; SCBA if involved in fire; avoid dust inhalation; chemical-resistant gloves and protective clothing

Use structural firefighting PPE with SCBA for fire or smoke. For spill handling without fire, use gloves, eye protection and respiratory protection if dust or residues are present.

Isolation & Evacuation

ERG 133: isolate spill area at least 25m in all directions; for large fire evacuate 800m radius
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 133).

First Actions for a UN 2001 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, gas, smoke, mist or dust and avoid skin or eye contact.
  • Avoid friction, sparks, heat and dust generation; watch for rapid burning or re-ignition.
  • Do not touch damaged containers or spilled/released material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the release or spill area and expand the perimeter for fire involvement, vapor accumulation, cylinder/tank heating or unknown product identity.
  • Use ERG Guide 133, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 2001 — Cobalt naphthenates, powder
HAZMAT RADIO NOTE — UN 2001 Product: Cobalt naphthenates, powder Class 4 / Flammable Solid / ERG 133 PPE: Level C minimum; SCBA if involved in fire; avoid dust inhalation; chemical-resistant gloves and protective clothing ISOLATION: ERG 133: isolate spill area at least 25m in all directions; for large fire evacuate 800m radius ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2001 — Cobalt naphthenates, powder Class: 4 | Placard: Flammable Solid | ERG Guide: 133 Appearance: Purple to reddish-brown powder or solid mass with a mild hydrocarbon odor. Combustible solid at room temperature. Water Reactivity: No significant reaction with water, but may release heat upon dissolution Extinguishing: Use water spray/fog, dry chemical, CO2, sand or earth as appropriate for packaging and fire size. Overhaul carefully for hot material or re-ignition. PPE: Level C minimum; SCBA if involved in fire; avoid dust inhalation; chemical-resistant gloves and protective clothing Isolation: ERG 133: isolate spill area at least 25m in all directions; for large fire evacuate 800m radius — Key Hazards — • FLAMMABLE/combustible powder; dust may ignite by heat, sparks or flame. • Dust generation may increase fire and inhalation hazards. • Cobalt compound dust can irritate respiratory tract, skin and eyes and may create toxic exposure concerns. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, gas, smoke, mist or dust and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/cobalt-naphthenates-powder-un-2001 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2001 Cobalt naphthenates, powder Cls4 ERG133 | allfirefighter.com/hazmat/un/cobalt-naphthenates-powder-un-2001SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/cobalt-naphthenates-powder-un-2001

Related UN Numbers in Class 4

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2001

UN 2001 is Cobalt naphthenates, powder, a hazardous material assigned to ERG Guide 133.

It may burn as a flammable/combustible powder; dust and fire behavior should be checked from SDS.

ERG Guide 133 applies to UN 2001 for initial isolation, protective actions and first response guidance.

FLAMMABLE/combustible powder; dust may ignite by heat, sparks or flame. Dust generation may increase fire and inhalation hazards. Cobalt compound dust can irritate respiratory tract, skin and eyes and may create toxic exposure concerns.

Use structural firefighting PPE with SCBA for fire or smoke. For spill handling without fire, use gloves, eye protection and respiratory protection if dust or residues are present.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.