☣️ UN 2016 • CLASS 6

UN 2016 — Ammunition, poisonous, non-explosive

Placard: Toxic. ERG Guide 151. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2016 is Ammunition, poisonous, non-explosive, a toxic non-explosive ammunition entry assigned to ERG Guide 151. The fill material controls toxicity, decontamination and isolation decisions.

Hazard overview: HIGHLY TOXIC non-explosive ammunition; released agent may be fatal by inhalation, ingestion or skin absorption. Exact hazard depends on the toxic agent or fill material in the ammunition. Damaged items may contaminate clothing, tools, soil and runoff.

Response guidance: For a UN 2016 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 151. Establish incident command, isolate the area, stay upwind, prevent incompatible contact, control runoff or dust spread and base entry/fire-control actions on monitoring and local SOP.

Firefighter training notes: Training for UN 2016 should emphasize toxic-agent identification, residue control, decontamination, law-enforcement/ordnance coordination, respiratory protection and downwind isolation. Use ERG 151, SDS and local SOP.

Regulatory context: Ammunition, poisonous, non-explosive is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting, waste handling and environmental requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Ammunition, poisonous, non-explosive should be stored in a secure, ventilated toxic-material/ordnance area with restricted access, intact packaging, segregation from heat and incompatible materials, and emergency/decontamination planning.

Advertisement

UN 2016 Quick Details

UN 2016
Product name: Ammunition, poisonous, non-explosive
DOT Class: 6
Placard type: Toxic
ERG Guide: 151 (check current ERG)
Initial isolation: ERG 151: isolate 25m all directions initially; protect persons downwind; evacuate immediate area if leaking; large spill: consider evacuation 100m downwind

Common Hazards of UN 2016

  • HIGHLY TOXIC non-explosive ammunition; released agent may be fatal by inhalation, ingestion or skin absorption.
  • Exact hazard depends on the toxic agent or fill material in the ammunition.
  • Damaged items may contaminate clothing, tools, soil and runoff.
  • Fire may produce irritating, corrosive and/or toxic gases.
  • Containers or rounds may rupture when heated even if classified non-explosive.
  • Runoff may carry toxic contamination and pollute waterways.
  • Avoid all skin contact and treat unidentified contents as highly toxic.

Chemical Identity & Physical Properties

Varies by specific munition type; typically solid munitions containing toxic chemical agents or materials. May be cylindrical cartridges, shells, or other ammunition forms at room temperature.

Also known asPoisonous ammunitionToxic ammunition non-explosiveChemical ammunitionToxic ordnance
AppearanceVaries by specific munition type; typically solid munitions containing toxic chemical agents or materials. May be cylindrical cartridges, shells, or other ammunition forms at room temperature.
Flash PointNot applicable (non-explosive ammunition)
Boiling PointNot applicable (solid munitions)
Vapor DensityNot applicable (solid munitions; vapor density depends on released agent)
Water ReactivityVaries by toxic agent contained; assume potential reactivity and contamination risk
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2016

Extinguishing Media

Use extinguishing agents appropriate for the packaging and surrounding fire while minimizing spread of toxic residues. Water spray may suppress vapors/particles when compatible and runoff can be contained.

PPE Requirements

⚠️ Level A required due to unknown toxic agents; SCBA mandatory; full chemical protective suit; avoid any contact

Use positive-pressure SCBA and fully encapsulating chemical protection for leaking, damaged or unknown toxic-agent ammunition. Avoid all skin contact and follow hazmat/ordnance procedures.

Isolation & Evacuation

ERG 151: isolate 25m all directions initially; protect persons downwind; evacuate immediate area if leaking; large spill: consider evacuation 100m downwind
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 151).

First Actions for a UN 2016 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing dust, vapor, fumes, mist or smoke and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material unless properly trained and wearing appropriate protective equipment.
  • Prevent residues, fragments, runoff and decontamination waste from spreading.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or release area and expand the perimeter for fire involvement, water reaction, vapor generation, dust spread or unknown product identity.
  • Use ERG Guide 151, shipping papers, SDS, air monitoring and incident command for protective actions.
Advertisement

📋 Copy & Share Field Card

UN 2016 — Ammunition, poisonous, non-explosive
HAZMAT RADIO NOTE — UN 2016 Product: Ammunition, poisonous, non-explosive Class 6 / Toxic / ERG 151 PPE: Level A required due to unknown toxic agents; SCBA mandatory; full chemical protective suit; avoid any contact ISOLATION: ERG 151: isolate 25m all directions initially; protect persons downwind; evacuate immediate area if leaking; large spill: consider evacuation 100m downwind ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2016 — Ammunition, poisonous, non-explosive Class: 6 | Placard: Toxic | ERG Guide: 151 Appearance: Varies by specific munition type; typically solid munitions containing toxic chemical agents or materials. May be cylindrical cartridges, shells, or other ammunition forms at room temperature. Water Reactivity: Varies by toxic agent contained; assume potential reactivity and contamination risk Extinguishing: Use extinguishing agents appropriate for the packaging and surrounding fire while minimizing spread of toxic residues. Water spray may suppress vapors/particles when compatible and runoff can be contained. PPE: Level A required due to unknown toxic agents; SCBA mandatory; full chemical protective suit; avoid any contact Isolation: ERG 151: isolate 25m all directions initially; protect persons downwind; evacuate immediate area if leaking; large spill: consider evacuation 100m downwind — Key Hazards — • HIGHLY TOXIC non-explosive ammunition; released agent may be fatal by inhalation, ingestion or skin absorption. • Exact hazard depends on the toxic agent or fill material in the ammunition. • Damaged items may contaminate clothing, tools, soil and runoff. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing dust, vapor, fumes, mist or smoke and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/ammunition-poisonous-non-explosive-un-2016 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2016 Ammunition, poisonous, non-explosive Cls6 ERG151 | allfirefighter.com/hazmat/un/ammunition-poisonous-non-explosive-un-2016SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/ammunition-poisonous-non-explosive-un-2016

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

Frequently Asked Questions about UN 2016

UN 2016 is Ammunition, poisonous, non-explosive, a hazardous material assigned to ERG Guide 151.

It is not classified for explosive behavior here, but fire or heating can release toxic gases and may rupture items.

ERG Guide 151 applies to UN 2016 for initial isolation, protective actions and first response guidance.

HIGHLY TOXIC non-explosive ammunition; released agent may be fatal by inhalation, ingestion or skin absorption. Exact hazard depends on the toxic agent or fill material in the ammunition. Damaged items may contaminate clothing, tools, soil and runoff.

Use positive-pressure SCBA and fully encapsulating chemical protection for leaking, damaged or unknown toxic-agent ammunition. Avoid all skin contact and follow hazmat/ordnance procedures.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.