☣️ UN 2473 • CLASS 6

UN 2473 — Sodium arsanilate

Placard: Toxic. ERG Guide 154. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2473 is Sodium arsanilate, a toxic arsenic compound assigned to ERG Guide 154. Dust, runoff and secondary contamination are key response concerns.

Hazard overview: TOXIC arsenic compound; inhalation, ingestion or skin contact may cause serious poisoning. Dust or solution can contaminate clothing, tools, soil and runoff. Non-combustible or combustible behavior depends on formulation, but fire can produce toxic arsenic fumes.

Response guidance: For UN 2473, isolate the area, avoid skin contact and use SCBA where vapor, dust, gas or fire is present. Control ignition or contamination hazards and contain runoff using SDS and ERG 154.

Firefighter training notes: Training for UN 2473 should emphasize exposure routes, SCBA use, vapor/dust monitoring, fire behavior, decontamination, runoff containment and SDS verification. Use ERG 154, SDS and local SOP.

Regulatory context: Sodium arsanilate is regulated as a hazardous material for transport and emergency response. Storage, exposure, spill reporting, waste and fire-code duties depend on quantity, concentration and jurisdiction; verify shipping papers, SDS and local authority requirements.

Storage & handling: Sodium arsanilate should be stored in tightly closed compatible containers with ventilation, secondary containment, restricted access and SDS-based segregation from incompatible materials.

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UN 2473 Quick Details

UN 2473
Product name: Sodium arsanilate
DOT Class: 6
Placard type: Toxic
ERG Guide: 154 (check current ERG)
Initial isolation: ERG 154: Initial isolation 25m in all directions; for large spills isolate 50m and consider evacuation 150m downwind; toxic arsenic compounds require containment

Common Hazards of UN 2473

  • TOXIC arsenic compound; inhalation, ingestion or skin contact may cause serious poisoning.
  • Dust or solution can contaminate clothing, tools, soil and runoff.
  • Non-combustible or combustible behavior depends on formulation, but fire can produce toxic arsenic fumes.
  • Avoid dust generation and secondary contamination.
  • Runoff may carry persistent arsenic contamination and harm waterways.
  • Containers may rupture or fail when heated.
  • Medical evaluation and controlled decontamination may be needed after exposure.

Chemical Identity & Physical Properties

White to grayish-white crystalline powder or granular solid. Odorless. Soluble in water.

Also known asArsanilic acid sodium saltSodium 4-aminophenylarsonateSodium p-arsanilate4-Aminophenylarsonic acid sodium salt
CAS Number127-85-5
AppearanceWhite to grayish-white crystalline powder or granular solid. Odorless. Soluble in water.
Flash PointNot applicable (non-combustible solid)
Boiling PointNot applicable (decomposes before boiling)
Vapor DensityNot applicable (solid)
Water ReactivitySoluble in water; forms toxic solutions but no violent reaction
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2473

Extinguishing Media

Use dry chemical, CO2, foam or water spray as compatible with the product and fire size. Cool containers from protection and contain toxic runoff.

PPE Requirements

⚠️ Level B minimum with SCBA; full chemical-resistant suit for spills; avoid all skin contact; nitrile or butyl rubber gloves required

Use positive-pressure SCBA for dust, vapor, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing.

Isolation & Evacuation

ERG 154: Initial isolation 25m in all directions; for large spills isolate 50m and consider evacuation 150m downwind; toxic arsenic compounds require containment
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 154).

First Actions for a UN 2473 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream.
  • Avoid breathing vapor, dust, gas, mist, smoke or fumes and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material without proper training and PPE.
  • Prevent contaminated dust, liquid, runoff and decontamination waste from spreading.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 154, SDS, shipping papers and monitoring to set isolation, evacuation and entry decisions.
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📋 Copy & Share Field Card

UN 2473 — Sodium arsanilate
HAZMAT RADIO NOTE — UN 2473 Product: Sodium arsanilate Class 6 / Toxic / ERG 154 PPE: Level B minimum with SCBA; full chemical-resistant suit for spills; avoid all skin contact; nitrile or butyl rubber gloves required ISOLATION: ERG 154: Initial isolation 25m in all directions; for large spills isolate 50m and consider evacuation 150m downwind; toxic arsenic compounds require containment ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2473 — Sodium arsanilate Class: 6 | Placard: Toxic | ERG Guide: 154 Appearance: White to grayish-white crystalline powder or granular solid. Odorless. Soluble in water. Water Reactivity: Soluble in water; forms toxic solutions but no violent reaction Extinguishing: Use dry chemical, CO2, foam or water spray as compatible with the product and fire size. Cool containers from protection and contain toxic runoff. PPE: Level B minimum with SCBA; full chemical-resistant suit for spills; avoid all skin contact; nitrile or butyl rubber gloves required Isolation: ERG 154: Initial isolation 25m in all directions; for large spills isolate 50m and consider evacuation 150m downwind; toxic arsenic compounds require containment — Key Hazards — • TOXIC arsenic compound; inhalation, ingestion or skin contact may cause serious poisoning. • Dust or solution can contaminate clothing, tools, soil and runoff. • Non-combustible or combustible behavior depends on formulation, but fire can produce toxic arsenic fumes. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream. • Avoid breathing vapor, dust, gas, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/sodium-arsanilate-un-2473 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2473 Sodium arsanilate Cls6 ERG154 | allfirefighter.com/hazmat/un/sodium-arsanilate-un-2473SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/sodium-arsanilate-un-2473

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2473

UN 2473 is Sodium arsanilate, assigned to ERG Guide 154.

No. Sodium arsanilate is not normally flammable, but heat or fire can produce highly toxic fumes or residues.

TOXIC arsenic compound; inhalation, ingestion or skin contact may cause serious poisoning. Dust or solution can contaminate clothing, tools, soil and runoff. Non-combustible or combustible behavior depends on formulation, but fire can produce toxic arsenic fumes.

Use positive-pressure SCBA for dust, vapor, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing.

Use dry chemical, CO2, foam or water spray as compatible with the product and fire size. Cool containers from protection and contain toxic runoff.

Toxic or reactive material can contaminate clothing, tools and runoff, extending exposure beyond the original spill area.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.