☣️ UN 2501 • CLASS 6

UN 2501 — Tris-(1-aziridinyl)phosphine oxide, solution

Placard: Toxic. ERG Guide 152. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2501 is Tris-(1-aziridinyl)phosphine oxide, solution, a highly toxic solution assigned to ERG Guide 152. Exact concentration/solvent must be verified from SDS.

Hazard overview: HIGHLY TOXIC aziridine/phosphoramide solution; inhalation, ingestion or skin absorption may be fatal. Skin contact and contaminated clothing can extend exposure. Combustible material: may burn but does not ignite readily.

Response guidance: For UN 2501, isolate the area, avoid skin contact and use SCBA where vapor, dust, mist or fire is present. Contain toxic/corrosive runoff and verify product controls with SDS and ERG 152.

Firefighter training notes: Training for UN 2501 should emphasize toxic/corrosive exposure routes, skin absorption, SCBA use, decontamination, runoff containment and SDS verification. Use ERG 152, SDS and local SOP.

Regulatory context: Tris-(1-aziridinyl)phosphine oxide, solution is regulated as a hazardous material for transport and emergency response. Storage, exposure, spill reporting, waste and fire-code duties depend on quantity, concentration and jurisdiction; verify shipping papers, SDS and local authority requirements.

Storage & handling: Tris-(1-aziridinyl)phosphine oxide, solution should be stored in tightly closed compatible containers with ventilation, secondary containment, restricted access and SDS-based segregation from incompatible materials.

Advertisement

UN 2501 Quick Details

UN 2501
Product name: Tris-(1-aziridinyl)phosphine oxide, solution
DOT Class: 6
Placard type: Toxic
ERG Guide: 152 (check current ERG)
Initial isolation: ERG 152: isolate spill 25m all directions; if tank/rail car involved in fire, isolate 800m all directions and consider evacuation

Common Hazards of UN 2501

  • HIGHLY TOXIC aziridine/phosphoramide solution; inhalation, ingestion or skin absorption may be fatal.
  • Skin contact and contaminated clothing can extend exposure.
  • Combustible material: may burn but does not ignite readily.
  • May be reactive or unstable under heat or contamination depending on solution composition.
  • Fire may produce nitrogen oxides, phosphorus oxides and other toxic gases.
  • Runoff may carry toxic solution contamination.
  • Exact solvent/concentration must be verified from SDS and shipping papers.

Chemical Identity & Physical Properties

Colorless to pale yellow liquid solution. Odorless or slight amine-like odor. Highly toxic organic compound used historically as a chemotherapy agent and insect chemosterilant.

Also known asTEPATris(1-aziridinyl)phosphine oxideTriethylenephosphoramideAPOTris(ethylenimino)phosphine oxide
CAS Number545-55-1
AppearanceColorless to pale yellow liquid solution. Odorless or slight amine-like odor. Highly toxic organic compound used historically as a chemotherapy agent and insect chemosterilant.
Flash PointNot available for solution; base compound is combustible
Boiling PointDecomposes before boiling at approximately 80-100°C (176-212°F)
Vapor DensityHeavier than air (MW ~173)
Water ReactivitySoluble in water; no violent reaction but releases toxic vapors
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2501

Extinguishing Media

Use dry chemical, CO2, foam or water spray as compatible with fire size. Cool containers from protection and contain runoff as toxic contamination.

PPE Requirements

⚠️ Level A required; full encapsulation, SCBA, chemical-resistant suit; avoid all skin contact - causes severe burns and systemic toxicity

Use positive-pressure SCBA for vapor, dust, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing.

Isolation & Evacuation

ERG 152: isolate spill 25m all directions; if tank/rail car involved in fire, isolate 800m all directions and consider evacuation
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 152).

First Actions for a UN 2501 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream.
  • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material without proper training and PPE.
  • Prevent contaminated dust, liquid, runoff and decontamination waste from spreading.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 152, SDS, shipping papers and monitoring to set isolation, evacuation and entry decisions.
Advertisement

📋 Copy & Share Field Card

UN 2501 — Tris-(1-aziridinyl)phosphine oxide, solu
HAZMAT RADIO NOTE — UN 2501 Product: Tris-(1-aziridinyl)phosphine oxide, solution Class 6 / Toxic / ERG 152 PPE: Level A required; full encapsulation, SCBA, chemical-resistant suit; avoid all skin contact - causes severe burns and systemic toxicity ISOLATION: ERG 152: isolate spill 25m all directions; if tank/rail car involved in fire, isolate 800m all directions and consider evacuation ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2501 — Tris-(1-aziridinyl)phosphine oxide, solution Class: 6 | Placard: Toxic | ERG Guide: 152 Appearance: Colorless to pale yellow liquid solution. Odorless or slight amine-like odor. Highly toxic organic compound used historically as a chemotherapy agent and insect chemosterilant. Water Reactivity: Soluble in water; no violent reaction but releases toxic vapors Extinguishing: Use dry chemical, CO2, foam or water spray as compatible with fire size. Cool containers from protection and contain runoff as toxic contamination. PPE: Level A required; full encapsulation, SCBA, chemical-resistant suit; avoid all skin contact - causes severe burns and systemic toxicity Isolation: ERG 152: isolate spill 25m all directions; if tank/rail car involved in fire, isolate 800m all directions and consider evacuation — Key Hazards — • HIGHLY TOXIC aziridine/phosphoramide solution; inhalation, ingestion or skin absorption may be fatal. • Skin contact and contaminated clothing can extend exposure. • Combustible material: may burn but does not ignite readily. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream. • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/tris-phosphine-oxide-solution-un-2501 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2501 Tris-(1-aziridinyl)phosphine oxide, solution Cls6 ERG152 | allfirefighter.com/hazmat/un/tris-phosphine-oxide-solution-un-2501SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/tris-phosphine-oxide-solution-un-2501

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

Frequently Asked Questions about UN 2501

UN 2501 is Tris-(1-aziridinyl)phosphine oxide, solution, assigned to ERG Guide 152.

It is combustible but does not ignite readily; toxic/corrosive exposure is the main hazard.

HIGHLY TOXIC aziridine/phosphoramide solution; inhalation, ingestion or skin absorption may be fatal. Skin contact and contaminated clothing can extend exposure. Combustible material: may burn but does not ignite readily.

Use positive-pressure SCBA for vapor, dust, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing.

Use dry chemical, CO2, foam or water spray as compatible with fire size. Cool containers from protection and contain runoff as toxic contamination.

Toxic or corrosive material can contaminate clothing, tools and runoff, extending exposure beyond the original spill area.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.