☣️ UN 2716 • CLASS 6

UN 2716 — Butynediol

Placard: Toxic. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Butynediol is a toxic material that may be shipped as solid, viscous liquid or solution. Avoid skin contact, ingestion and inhalation exposure.

Hazard overview: Butynediol is a toxic material requiring control of inhalation, ingestion and skin exposure. Fire or heating can increase toxic vapor, dust or smoke hazards.

Response guidance: Isolate the release, keep personnel upwind and prevent contact with liquid, solid or runoff. Use Alcohol-resistant foam, CO2, dry chemical and water spray for cooling as appropriate for fire, while protecting waterways.

Firefighter training notes: Train crews to identify Butynediol by UN number, placard, ERG guide and SDS before choosing entry, isolation or extinguishment tactics.

Regulatory context: Use UN 2716, ERG 153, SDS, container labels and shipping papers to confirm the exact hazard profile and protective action distances.

Storage & handling: Store in closed, compatible containers away from heat, ignition sources and incompatible materials; keep the area ventilated and protected from damage.

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UN 2716 Quick Details

UN 2716
Product name: Butynediol
DOT Class: 6
Placard type: Toxic
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: isolate spill or leak area immediately for at least 25-50m in all directions; for large spills consider initial evacuation for 100m downwind

Common Hazards of UN 2716

  • Toxic exposure by inhalation, ingestion or skin contact may cause serious injury.
  • Contact can irritate or burn skin and eyes; avoid all unnecessary contact.
  • Fire may generate irritating, corrosive or toxic gases.
  • Combustible material may burn, although it may not ignite readily.
  • Contaminated runoff may be toxic or corrosive and should be contained.
  • Vapors, dust or aerosols can be more hazardous in confined or poorly ventilated areas.
  • Heated containers may rupture or release hazardous vapors.

Chemical Identity & Physical Properties

White to pale yellow crystalline solid or viscous liquid depending on temperature; slight characteristic odor.

Also known asbutyne-diolbutynedioldihydroxy-butynebishydroxymethylacetylene
CAS Number110-65-6
AppearanceWhite to pale yellow crystalline solid or viscous liquid at room temperature with a slight characteristic odor. May appear as a syrupy liquid or solid depending on temperature.
Flash Point152C (306F)
Boiling Point238C (460F) with decomposition
Vapor Density3.0 (heavier than air)
Water ReactivitySoluble in water; aqueous solutions may be corrosive
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2716

Extinguishing Media

Alcohol-resistant foam, CO2, dry chemical and water spray for cooling

PPE Requirements

⚠️ Use SCBA with chemical-resistant gloves, boots and protective clothing; upgrade to full chemical protection when contact or vapor levels are uncertain.

Use SCBA with chemical-resistant gloves, boots and protective clothing; upgrade to full chemical protection when contact or vapor levels are uncertain.

Isolation & Evacuation

ERG 153: isolate spill or leak area immediately for at least 25-50m in all directions; for large spills consider initial evacuation for 100m downwind
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 2716 Incident

  • Call 911 and the emergency response number shown on shipping papers or container documents.
  • Keep unauthorized personnel away and establish an initial isolation perimeter.
  • Stay upwind, uphill and upstream; avoid low areas where vapors or runoff may collect.
  • Avoid breathing vapors, dust, smoke or mist and prevent skin and eye contact.
  • Do not touch damaged containers or spilled material without appropriate chemical PPE.
  • Ventilate confined spaces only when personnel are trained, monitored and properly equipped.
  • Use ERG guidance, SDS, shipping papers and air monitoring before committing crews.
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📋 Copy & Share Field Card

UN 2716 — Butynediol
HAZMAT RADIO NOTE — UN 2716 Product: Butynediol Class 6 / Toxic / ERG 153 PPE: Use SCBA with chemical-resistant gloves, boots and protective clothing; upgrade to full chemical protection when contact or vapor levels are uncertain. ISOLATION: ERG 153: isolate spill or leak area immediately for at least 25-50m in all directions; for large spills consider initial evacuation for 100m downwind ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2716 — Butynediol Class: 6 | Placard: Toxic | ERG Guide: 153 Appearance: White to pale yellow crystalline solid or viscous liquid at room temperature with a slight characteristic odor. May appear as a syrupy liquid or solid depending on temperature. Water Reactivity: Soluble in water; aqueous solutions may be corrosive Extinguishing: Alcohol-resistant foam, CO2, dry chemical and water spray for cooling PPE: Use SCBA with chemical-resistant gloves, boots and protective clothing; upgrade to full chemical protection when contact or vapor levels are uncertain. Isolation: ERG 153: isolate spill or leak area immediately for at least 25-50m in all directions; for large spills consider initial evacuation for 100m downwind — Key Hazards — • Toxic exposure by inhalation, ingestion or skin contact may cause serious injury. • Contact can irritate or burn skin and eyes; avoid all unnecessary contact. • Fire may generate irritating, corrosive or toxic gases. — First Actions — • Call 911 and the emergency response number shown on shipping papers or container documents. • Keep unauthorized personnel away and establish an initial isolation perimeter. • Stay upwind, uphill and upstream; avoid low areas where vapors or runoff may collect. • Avoid breathing vapors, dust, smoke or mist and prevent skin and eye contact. SOURCE: allfirefighter.com/hazmat/un/butynediol-un-2716 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2716 Butynediol Cls6 ERG153 | allfirefighter.com/hazmat/un/butynediol-un-2716SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/butynediol-un-2716

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2716

The main hazard is described by its toxic classification; responders should also check SDS details for the exact product.

Yes. Fire risk depends on the material: flammable liquids and solids can ignite, while oxidizers can intensify other fires.

Isolate the area, stay upwind, deny entry and verify the ERG guide, SDS and shipping papers before close approach.

Use SCBA when vapors, dust, smoke or unknown concentrations are present, with chemical-resistant clothing as the product requires.

Yes. Fire water or spill runoff may be contaminated, corrosive, toxic or capable of spreading the hazard.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.