☣️ UN 2757 • CLASS 6
Carbamate pesticide, solid, poisonous
Placard: Toxic. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 2757
Class: 6
Placard type: Toxic
ERG: Guide 151 (check current ERG)
Isolation: ERG 151: Initial isolation 25m in all directions; protect persons downwind; if tank/rail car involved in fire isolate 800m and consider evacuation
Chemical & Response Details
| Also known as | Carbamate insecticideCarbamic acid ester pesticideN-methyl carbamate pesticideCarbaryl-type compoundsAldicarb-type compounds |
| Appearance | Typically appears as white to tan crystalline powder or granular solid with mild to no odor at room temperature. Various carbamate pesticides exist under this classification. |
| Flash Point | Varies by specific compound; typically >100C (>212F) for most carbamate solids |
| Boiling Point | Not applicable (decomposes before boiling); most carbamates decompose at 150-200C |
| Vapor Density | Not applicable (solid at room temperature) |
| Water Reactivity | Generally stable in water but slowly hydrolyzes; avoid strong acids or bases which accelerate decomposition |
| Extinguishing | Dry chemical, CO2, water spray for cooling; foam may be used for fire control |
| PPE | ⚠️ Level B minimum required; SCBA with full face protection mandatory; chemical-resistant suit, gloves, and boots essential due to dermal toxicity |
| Isolation | ERG 151: Initial isolation 25m in all directions; protect persons downwind; if tank/rail car involved in fire isolate 800m and consider evacuation |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
- Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.
- Avoid any skin contact.
- Fire may produce irritating, corrosive and/or toxic gases.
- Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental
- Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive
- Containers may explode when heated.
- Runoff may pollute waterways.
First actions (field-minded)
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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UN 2757 — Carbamate pesticide, solid, poisonous HAZMAT RADIO NOTE — UN 2757
Product: Carbamate pesticide, solid, poisonous
Class 6 / Toxic / ERG 151
PPE: Level B minimum required; SCBA with full face protection mandatory; chemical-resistant suit, gloves, and boots essential due to dermal toxicity
ISOLATION: ERG 151: Initial isolation 25m in all directions; protect persons downwind; if tank/rail car involved in fire isolate 800m and consider evacuation
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 2757 — Carbamate pesticide, solid, poisonous
Class: 6 | Placard: Toxic | ERG Guide: 151
Appearance: Typically appears as white to tan crystalline powder or granular solid with mild to no odor at room temperature. Various carbamate pesticides exist under this classification.
Water Reactivity: Generally stable in water but slowly hydrolyzes; avoid strong acids or bases which accelerate decomposition
Extinguishing: Dry chemical, CO2, water spray for cooling; foam may be used for fire control
PPE: Level B minimum required; SCBA with full face protection mandatory; chemical-resistant suit, gloves, and boots essential due to dermal toxicity
Isolation: ERG 151: Initial isolation 25m in all directions; protect persons downwind; if tank/rail car involved in fire isolate 800m and consider evacuation
— Key Hazards —
• Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.
• Avoid any skin contact.
• Fire may produce irritating, corrosive and/or toxic gases.
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
SOURCE: allfirefighter.com/hazmat/un/2757 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN2757 Carbamate pesticide, solid, poisonous Cls6 ERG151 | allfirefighter.com/hazmat/un/2757SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/2757
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FAQ
Highly toxic, may be fatal if inhaled, ingested or absorbed through skin. Avoid any skin contact. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive Containers may explode when heated. Runoff may pollute waterways.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level B minimum required; SCBA with full face protection mandatory; chemical-resistant suit, gloves, and boots essential due to dermal toxicity
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 151 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.