☣️ UN 2810 • CLASS 6

UN 2810 — Compounds, tree or weed killing, liquid (toxic)

Placard: Toxic. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Compounds, tree or weed killing, liquid (toxic) is a broad UN entry for herbicide or arboricide formulations. The active ingredient and carrier solvent must be confirmed before final tactics.

Hazard overview: The shared hazard is toxic exposure by inhalation, ingestion or skin contact. Some formulations also contain combustible solvents, so fire and vapor behavior can vary significantly.

Response guidance: Isolate the area, avoid contact and keep product out of drains and soil. Use foam, dry chemical or carbon dioxide according to the SDS and container label, and collect runoff as contaminated waste.

Firefighter training notes: Train crews to treat UN 2810 as a formulation-dependent pesticide entry. Do not assume the active ingredient; use SDS, labels and shipping papers before selecting foam, decon or waste tactics.

Regulatory context: UN 2810 is a Class 6 toxic shipment. Product labels, pesticide regulations, SDS data and local environmental reporting rules may control cleanup and disposal.

Storage & handling: Store tightly closed in compatible containers away from food, feed, oxidizers and ignition sources when solvent-based. Provide secondary containment and protect from heat.

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UN 2810 Quick Details

UN 2810
Product name: Compounds, tree or weed killing, liquid (toxic)
DOT Class: 6
Placard type: Toxic
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: isolate spill 25-50m in all directions; if tank/cargo involved in fire, isolate 800m and consider evacuation for 1600m downwind

Common Hazards of UN 2810

  • This entry covers variable toxic herbicide or arboricide liquids; exact hazards depend on formulation.
  • Inhalation, ingestion or skin absorption may cause serious poisoning.
  • Many products contain solvents or carriers that can burn or produce toxic smoke.
  • Liquid contact can irritate or injure skin and eyes and contaminate PPE.
  • Fire may produce toxic pesticide, solvent and decomposition vapors.
  • Runoff can contaminate soil, drains and waterways and may harm aquatic life.
  • SDS and shipping papers are essential because active ingredients vary widely.

Chemical Identity & Physical Properties

These products may be clear, amber or dark liquids with mild to pungent odors. Physical properties depend on the active ingredient, solvent base and concentration.

Also known asHerbicide liquidTree killing compoundWeed killing compoundPhytocide solutionArboricide liquid
AppearanceVarious colored liquids (amber, brown, or clear) with odors ranging from mild to pungent, depending on active ingredient formulation. Liquid at room temperature.
Flash PointVaries by formulation; typically 60-93C (140-200F) for petroleum-based carriers, some formulations may be lower
Boiling PointVaries by formulation; typically 100-200C (212-392F) depending on solvent base and active ingredients
Vapor DensityGenerally heavier than air (>1); typical range 2-4 depending on carrier solvent
Water ReactivityNo significant reaction with water; may form emulsions or separate layers depending on formulation
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2810

Extinguishing Media

Alcohol-resistant foam (AR-AFFF), dry chemical, CO2; regular foam may be ineffective with some formulations

PPE Requirements

⚠️ Level B minimum required; SCBA, chemical-resistant suit, gloves and boots mandatory; avoid all skin contact due to dermal toxicity

Use SCBA and chemical-resistant clothing for initial spill entry. Gloves, boots and eye protection must be selected for the pesticide formulation and carrier solvent.

Isolation & Evacuation

ERG 153: isolate spill 25-50m in all directions; if tank/cargo involved in fire, isolate 800m and consider evacuation for 1600m downwind
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 2810 Incident

  • Call 911 and the emergency response number shown on the shipping papers or container documents.
  • Keep unauthorized personnel away and establish an isolation perimeter before entry.
  • Stay upwind, uphill and upstream; keep responders out of vapors, dusts and runoff.
  • Avoid breathing vapors, dust, mist or smoke and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material unless properly trained and protected.
  • Ventilate confined spaces only when personnel are trained, equipped and monitored.
  • Use ERG guidance, SDS, shipping papers and air monitoring to confirm protective actions.
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📋 Copy & Share Field Card

UN 2810 — Compounds, tree or weed killing, liquid
HAZMAT RADIO NOTE — UN 2810 Product: Compounds, tree or weed killing, liquid (toxic) Class 6 / Toxic / ERG 153 PPE: Level B minimum required; SCBA, chemical-resistant suit, gloves and boots mandatory; avoid all skin contact due to dermal toxicity ISOLATION: ERG 153: isolate spill 25-50m in all directions; if tank/cargo involved in fire, isolate 800m and consider evacuation for 1600m downwind ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2810 — Compounds, tree or weed killing, liquid (toxic) Class: 6 | Placard: Toxic | ERG Guide: 153 Appearance: Various colored liquids (amber, brown, or clear) with odors ranging from mild to pungent, depending on active ingredient formulation. Liquid at room temperature. Water Reactivity: No significant reaction with water; may form emulsions or separate layers depending on formulation Extinguishing: Alcohol-resistant foam (AR-AFFF), dry chemical, CO2; regular foam may be ineffective with some formulations PPE: Level B minimum required; SCBA, chemical-resistant suit, gloves and boots mandatory; avoid all skin contact due to dermal toxicity Isolation: ERG 153: isolate spill 25-50m in all directions; if tank/cargo involved in fire, isolate 800m and consider evacuation for 1600m downwind — Key Hazards — • This entry covers variable toxic herbicide or arboricide liquids; exact hazards depend on formulation. • Inhalation, ingestion or skin absorption may cause serious poisoning. • Many products contain solvents or carriers that can burn or produce toxic smoke. — First Actions — • Call 911 and the emergency response number shown on the shipping papers or container documents. • Keep unauthorized personnel away and establish an isolation perimeter before entry. • Stay upwind, uphill and upstream; keep responders out of vapors, dusts and runoff. • Avoid breathing vapors, dust, mist or smoke and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/compounds-tree-or-weed-un-2810 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2810 Compounds, tree or weed killing, liquid (toxic) Cls6 ERG153 | allfirefighter.com/hazmat/un/compounds-tree-or-weed-un-2810SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/compounds-tree-or-weed-un-2810

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2810

It covers many herbicide formulations, so the active ingredient and carrier must be verified from the SDS.

No. Some solvent-based products may burn, but water-based formulations may not.

Toxic exposure through skin contact, inhalation or ingestion is the primary concern.

Runoff may carry toxic herbicide into drains, soil or waterways.

SCBA with chemical-resistant suit, gloves and boots is appropriate until the formulation is confirmed.

It depends on the carrier solvent; alcohol-resistant foam may be needed for some formulations.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.