☣️ UN 2870 • CLASS 4

UN 2870 — Aluminum borohydride in devices

Placard: Spontaneously Combustible. ERG Guide 135. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Aluminum borohydride in devices requires dry, cautious hazmat handling because moisture, dust, or damaged packaging can change the incident quickly. Verify the exact product condition before applying water or moving containers.

Hazard overview: The key hazards for Aluminum borohydride in devices are reactive fire behavior, toxic or corrosive fumes, and contaminated runoff. Fine particles, damaged devices, or wet material can be much more dangerous than intact product.

Response guidance: Isolate the release, keep water away from reactive material, remove ignition sources, and monitor for hydrogen or acid gases where relevant. Use dry sand, dry powder, lime, soda ash, or other compatible dry media only when appropriate to the exact material.

Firefighter training notes: Training should focus on moisture exclusion, dry extinguishing media, gas monitoring, and withdrawal distances for UN 2870.

Regulatory context: Verify the SDS, shipping papers, packaging condition, and ERG 135 before selecting water, neutralization, or cleanup tactics.

Storage & handling: Store dry and tightly closed, away from water, humidity, incompatible acids/bases, oxidizers, fuels, and ignition sources as specified by SDS.

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UN 2870 Quick Details

UN 2870
Product name: Aluminum borohydride in devices
DOT Class: 4
Placard type: Spontaneously Combustible
ERG Guide: 135 (check current ERG)
Initial isolation: ERG 135: isolate spill 25-50m all directions. Large spill: evacuate 800m downwind. Fire: evacuate 800m radius. Keep containers cool with unmanned water spray from distance if involved in fire.

Common Hazards of UN 2870

  • Damaged devices can expose aluminum borohydride that may ignite with air or moisture and release hydrogen.
  • Contact can injure skin, eyes, and respiratory tissue; fumes may collect in low or confined areas.
  • Fire may produce toxic or irritating decomposition products.
  • Containers or devices may rupture when heated or contaminated.
  • Direct water, foam, or incompatible agents can worsen the incident for released reactive material.
  • Runoff can become corrosive or contaminated and should be contained.
  • Use SDS, shipping papers, and monitoring before selecting final tactics.

Chemical Identity & Physical Properties

Colorless to pale yellow liquid with a pungent odor. Pyrophoric liquid that ignites spontaneously in moist air. Typically shipped in sealed devices or containers under inert atmosphere

Also known asAluminum tetrahydroborateTetrahydroaluminum borateAluminum borohydride solutionAluminium borohydride
CAS Number16962-07-5
AppearanceColorless to pale yellow liquid with a pungent odor. Pyrophoric liquid that ignites spontaneously in moist air. Typically shipped in sealed devices or containers under inert atmosphere.
Flash PointNot applicable (pyrophoric, ignites spontaneously below room temperature)
Boiling Point44C (111F) at 760 mmHg
Vapor Density2.4 (heavier than air)
Water ReactivityReacts violently with water, releasing flammable hydrogen gas and heat. Never use water directly on this material.
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2870

Extinguishing Media

Dry chemical powder, dry sand, sodium chloride powder. Do not use water, foam, CO2, or halogenated agents.

PPE Requirements

⚠️ Level A required for initial response due to pyrophoric nature. Full-face SCBA, vapor-protective suit, butyl rubber gloves. Avoid all sources of ignition.

Use SCBA with chemical- and heat-protective clothing. Specialist metal-fire or water-reactive tactics may be needed, and distance remains part of PPE.

Isolation & Evacuation

ERG 135: isolate spill 25-50m all directions. Large spill: evacuate 800m downwind. Fire: evacuate 800m radius. Keep containers cool with unmanned water spray from distance if involved in fire.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 135).

First Actions for a UN 2870 Incident

  • Call 911 and the emergency response number shown on shipping papers or the SDS.
  • Keep unauthorized personnel away and isolate the area from ignition and moisture sources.
  • Stay upwind, uphill, and upstream; avoid low areas where corrosive fumes or hydrogen may collect.
  • Avoid breathing fumes and prevent all skin and eye contact with material or runoff.
  • Do not touch containers or residue without SCBA and chemical-resistant PPE.
  • Do not apply water directly to the material unless specialist guidance confirms it is safe.
  • Use ERG guidance, SDS, shipping papers, and monitoring for hydrogen, acid gases, and oxygen levels.
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📋 Copy & Share Field Card

UN 2870 — Aluminum borohydride in devices
HAZMAT RADIO NOTE — UN 2870 Product: Aluminum borohydride in devices Class 4 / Spontaneously Combustible / ERG 135 PPE: Level A required for initial response due to pyrophoric nature. Full-face SCBA, vapor-protective suit, butyl rubber gloves. Avoid all sources of ignition. ISOLATION: ERG 135: isolate spill 25-50m all directions. Large spill: evacuate 800m downwind. Fire: evacuate 800m radius. Keep containers cool with unmanned water spray from distance if involved in fire. ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2870 — Aluminum borohydride in devices Class: 4 | Placard: Spontaneously Combustible | ERG Guide: 135 Appearance: Colorless to pale yellow liquid with a pungent odor. Pyrophoric liquid that ignites spontaneously in moist air. Typically shipped in sealed devices or containers under inert atmosphere. Water Reactivity: Reacts violently with water, releasing flammable hydrogen gas and heat. Never use water directly on this material. Extinguishing: Dry chemical powder, dry sand, sodium chloride powder. Do not use water, foam, CO2, or halogenated agents. PPE: Level A required for initial response due to pyrophoric nature. Full-face SCBA, vapor-protective suit, butyl rubber gloves. Avoid all sources of ignition. Isolation: ERG 135: isolate spill 25-50m all directions. Large spill: evacuate 800m downwind. Fire: evacuate 800m radius. Keep containers cool with unmanned water spray from distance if involved in fire. — Key Hazards — • Damaged devices can expose aluminum borohydride that may ignite with air or moisture and release hydrogen. • Contact can injure skin, eyes, and respiratory tissue; fumes may collect in low or confined areas. • Fire may produce toxic or irritating decomposition products. — First Actions — • Call 911 and the emergency response number shown on shipping papers or the SDS. • Keep unauthorized personnel away and isolate the area from ignition and moisture sources. • Stay upwind, uphill, and upstream; avoid low areas where corrosive fumes or hydrogen may collect. • Avoid breathing fumes and prevent all skin and eye contact with material or runoff. SOURCE: allfirefighter.com/hazmat/un/aluminum-borohydride-in-devices-un-2870 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2870 Aluminum borohydride in devices Cls4 ERG135 | allfirefighter.com/hazmat/un/aluminum-borohydride-in-devices-un-2870SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/aluminum-borohydride-in-devices-un-2870

Related UN Numbers in Class 4

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2870

Yes or potentially, depending on condition and exact product; avoid direct water on released material until specialist guidance is confirmed.

Hydrogen, acid gases, corrosive fumes, or metal oxide fumes may be possible depending on the material.

Dry sand, dry powder, lime, soda ash, or compatible dry agents may be needed; verify with SDS and ERG guidance.

Monitoring helps confirm flammable gas, acid gas, oxygen level, and safe entry conditions.

SCBA with chemical-resistant and heat-protective clothing is required for release or fire conditions.

Avoid moisture, incompatible agents, friction, and unnecessary container movement.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.