☣️ UN 2929 • CLASS 6
Poisonous liquid, flammable, organic, n.o.s.
Placard: Toxic. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 2929
Class: 6
Placard type: Toxic
ERG: Guide 131 (check current ERG)
Isolation: ERG 131: Isolate spill 25-50m all directions; evacuate immediate area; for large spills isolate 150m downwind and evacuate 300m in all directions
Chemical & Response Details
| Also known as | Toxic liquid, flammable, organic, n.o.s.Poisonous liquid, flammable, organic, not otherwise specifiedOrganic toxic flammable liquid |
| Appearance | Variable appearance depending on specific substance; typically a liquid at room temperature with potential for various colors and odors. This is a generic UN classification covering multiple toxic organic liquids with flammable properties. |
| Flash Point | Below 61C (141F) - flammable liquid classification |
| Boiling Point | Variable depending on specific substance |
| Vapor Density | Typically heavier than air (>1) |
| Water Reactivity | Variable; generally no significant reaction with water for most organic liquids in this class |
| Extinguishing | Alcohol-resistant foam, CO2, dry chemical, water spray for cooling |
| PPE | ⚠️ Level A or B minimum; SCBA required; full chemical protective suit; avoid all contact with skin, eyes, or clothing due to toxic absorption hazard |
| Isolation | ERG 131: Isolate spill 25-50m all directions; evacuate immediate area; for large spills isolate 150m downwind and evacuate 300m in all directions |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
- TOXIC; may be fatal if inhaled, ingested or absorbed through skin.
- Inhalation or contact with some of these materials will irritate or burn skin and eyes.
- Methyl chloroacetate (UN2295) is an eye irritant/lachrymator (causes flow of tears).
- Fire will produce irritating, corrosive and/or toxic gases.
- Vapors may cause dizziness or asphyxiation, especially when in closed or confined areas.
- Runoff from fire control or dilution water may cause environmental contamination.
- HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
- Vapors may form explosive mixtures with air.
First actions (field-minded)
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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UN 2929 — Poisonous liquid, flammable, organic, n. HAZMAT RADIO NOTE — UN 2929
Product: Poisonous liquid, flammable, organic, n.o.s.
Class 6 / Toxic / ERG 131
PPE: Level A or B minimum; SCBA required; full chemical protective suit; avoid all contact with skin, eyes, or clothing due to toxic absorption hazard
ISOLATION: ERG 131: Isolate spill 25-50m all directions; evacuate immediate area; for large spills isolate 150m downwind and evacuate 300m in all directions
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 2929 — Poisonous liquid, flammable, organic, n.o.s.
Class: 6 | Placard: Toxic | ERG Guide: 131
Appearance: Variable appearance depending on specific substance; typically a liquid at room temperature with potential for various colors and odors. This is a generic UN classification covering multiple toxic organic liquids with flammable properties.
Water Reactivity: Variable; generally no significant reaction with water for most organic liquids in this class
Extinguishing: Alcohol-resistant foam, CO2, dry chemical, water spray for cooling
PPE: Level A or B minimum; SCBA required; full chemical protective suit; avoid all contact with skin, eyes, or clothing due to toxic absorption hazard
Isolation: ERG 131: Isolate spill 25-50m all directions; evacuate immediate area; for large spills isolate 150m downwind and evacuate 300m in all directions
— Key Hazards —
• TOXIC; may be fatal if inhaled, ingested or absorbed through skin.
• Inhalation or contact with some of these materials will irritate or burn skin and eyes.
• Methyl chloroacetate (UN2295) is an eye irritant/lachrymator (causes flow of tears).
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/2929 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN2929 Poisonous liquid, flammable, organic, n.o.s. Cls6 ERG131 | allfirefighter.com/hazmat/un/2929SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/2929
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FAQ
TOXIC; may be fatal if inhaled, ingested or absorbed through skin. Inhalation or contact with some of these materials will irritate or burn skin and eyes. Methyl chloroacetate (UN2295) is an eye irritant/lachrymator (causes flow of tears). Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or asphyxiation, especially when in closed or confined areas. Runoff from fire control or dilution water may cause environmental contamination. HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level A or B minimum; SCBA required; full chemical protective suit; avoid all contact with skin, eyes, or clothing due to toxic absorption hazard
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 131 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.