☣️ UN 2936 • CLASS 6

UN 2936 — Thiolactic acid

Placard: Toxic. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Thiolactic acid is a corrosive organic acid assigned to ERG 153. It can burn skin and eyes, produce irritating vapors or mists and create acidic runoff during spills or fire control.

Hazard overview: The primary hazard is corrosive contact with liquid or mist. Heating can release irritating sulfur-containing and acidic gases, while incompatible oxidizers or bases may intensify the reaction.

Response guidance: Isolate the release, stay upwind and avoid direct contact. Use dry chemical, CO2, alcohol-resistant foam or water spray for surrounding fire and container cooling, while preventing acidic runoff from entering drains.

Firefighter training notes: Train responders to handle corrosive organic acid spills with splash control, vapor awareness, decontamination planning and runoff containment.

Regulatory context: UN 2936 is a regulated corrosive hazardous material. Verify concentration, packing group and emergency response contact from the SDS and shipping papers.

Storage & handling: Store in corrosion-resistant containers in a cool, ventilated area away from oxidizers, bases, metals and ignition sources.

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UN 2936 Quick Details

UN 2936
Product name: Thiolactic acid
DOT Class: 6
Placard type: Toxic
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: isolate spill area and increase downwind protection if vapors, fire or large release conditions develop

Common Hazards of UN 2936

  • Thiolactic acid is corrosive and can cause burns to skin and eyes.
  • Vapor or mist may irritate the respiratory tract and may be harmful if inhaled.
  • Combustible liquid; may burn when heated though it does not ignite as readily as low-flash liquids.
  • Fire may produce sulfur oxides, carbon oxides and irritating acidic gases.
  • Reaction with strong oxidizers or bases may generate heat.
  • Runoff may be acidic and harmful to waterways.
  • Containers may rupture when heated.

Chemical Identity & Physical Properties

Thiolactic acid is generally a liquid organic acid with a strong, unpleasant sulfur-like odor. It should be treated as corrosive even when appearance seems ordinary.

Also known as2-Mercaptopropionic acidalpha-Mercaptopropionic acidThiolatic acid2-Sulfanylpropanoic acid
CAS Number79-42-5
AppearanceColorless to pale yellow liquid with a strong unpleasant mercaptan odor. Corrosive and toxic.
Flash Point107°C (225°F)
Boiling Point116°C (241°F) at 15 mmHg
Vapor Density3.7 (heavier than air)
Water ReactivityNo violent reaction expected, but dilution can generate heat and acidic runoff
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2936

Extinguishing Media

Dry chemical, CO2, alcohol-resistant foam or water spray for cooling; avoid spreading acidic runoff

PPE Requirements

⚠️ Chemical-resistant suit, gloves, boots and eye/face protection; SCBA for vapor, mist or fire conditions

Use chemical-resistant gloves, boots, eye and face protection and protective clothing. SCBA is recommended for fire, mist, vapor or confined-space conditions.

Isolation & Evacuation

ERG 153: isolate spill area and increase downwind protection if vapors, fire or large release conditions develop
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 2936 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream; avoid low areas where vapors may collect.
  • Avoid breathing vapors, dust, mist, smoke or fire gases.
  • Do not touch damaged containers or spilled material without proper PPE.
  • Ventilate confined spaces only if trained, equipped and authorized.
  • Use ERG, SDS, shipping papers, labels and monitoring results for final tactical decisions.
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📋 Copy & Share Field Card

UN 2936 — Thiolactic acid
HAZMAT RADIO NOTE — UN 2936 Product: Thiolactic acid Class 6 / Toxic / ERG 153 PPE: Chemical-resistant suit, gloves, boots and eye/face protection; SCBA for vapor, mist or fire conditions ISOLATION: ERG 153: isolate spill area and increase downwind protection if vapors, fire or large release conditions develop ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2936 — Thiolactic acid Class: 6 | Placard: Toxic | ERG Guide: 153 Appearance: Colorless to pale yellow liquid with a strong unpleasant mercaptan odor. Corrosive and toxic. Water Reactivity: No violent reaction expected, but dilution can generate heat and acidic runoff Extinguishing: Dry chemical, CO2, alcohol-resistant foam or water spray for cooling; avoid spreading acidic runoff PPE: Chemical-resistant suit, gloves, boots and eye/face protection; SCBA for vapor, mist or fire conditions Isolation: ERG 153: isolate spill area and increase downwind protection if vapors, fire or large release conditions develop — Key Hazards — • Thiolactic acid is corrosive and can cause burns to skin and eyes. • Vapor or mist may irritate the respiratory tract and may be harmful if inhaled. • Combustible liquid; may burn when heated though it does not ignite as readily as low-flash liquids. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream; avoid low areas where vapors may collect. • Avoid breathing vapors, dust, mist, smoke or fire gases. SOURCE: allfirefighter.com/hazmat/un/thiolactic-acid-un-2936 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2936 Thiolactic acid Cls6 ERG153 | allfirefighter.com/hazmat/un/thiolactic-acid-un-2936SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/thiolactic-acid-un-2936

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2936

UN 2936 is thiolactic acid, a corrosive organic acid.

It is combustible rather than highly flammable, but it can burn when heated.

Skin and eye burns, respiratory irritation from mist or vapor and harmful fire gases are key concerns.

Dry chemical, CO2, alcohol-resistant foam or water spray for cooling may be used when compatible with the scene.

Chemical-resistant clothing, gloves, eye and face protection and SCBA for vapor or fire conditions are recommended.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.