☣️ UN 3006 • CLASS 6
Thiocarbamate pesticide, liquid, poisonous
Placard: Toxic. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
Advertisement
Quick details
UN 3006
Class: 6
Placard type: Toxic
ERG: Guide 151 (check current ERG)
Isolation: ERG 151: isolate spill 25-50m all directions; for large spills consider evacuation 100m downwind; if fire/tank involved isolate 800m and evacuate 1600m downwind
Chemical & Response Details
| Also known as | Thiocarbamate pesticideThiocarbamate insecticideDithiocarbamate pesticide liquidCarbamate pesticide solution |
| Appearance | Varies by formulation; typically a clear to amber or dark brown liquid with a mild to pungent chemical odor. May be dissolved in organic solvents. |
| Flash Point | Varies by formulation and solvent; typically 23-61C (73-142F) for common petroleum-based carriers |
| Boiling Point | Varies by formulation; typically 100-200C (212-392F) depending on active ingredient and carrier solvent |
| Vapor Density | Heavier than air; typically 3-6 depending on formulation |
| Water Reactivity | No violent reaction with water, but may hydrolyze slowly; avoid contaminating water sources due to high toxicity |
| Extinguishing | Alcohol-resistant foam, dry chemical, CO2; water spray for cooling only, not for extinguishment |
| PPE | ⚠️ Level A or B required; SCBA mandatory; full chemical-resistant suit; butyl rubber gloves; avoid all skin contact due to dermal absorption hazard |
| Isolation | ERG 151: isolate spill 25-50m all directions; for large spills consider evacuation 100m downwind; if fire/tank involved isolate 800m and evacuate 1600m downwind |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
- Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.
- Avoid any skin contact.
- Fire may produce irritating, corrosive and/or toxic gases.
- Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental
- Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive
- Containers may explode when heated.
- Runoff may pollute waterways.
First actions (field-minded)
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
Advertisement
📋 Copy & Share
UN 3006 — Thiocarbamate pesticide, liquid, poisono HAZMAT RADIO NOTE — UN 3006
Product: Thiocarbamate pesticide, liquid, poisonous
Class 6 / Toxic / ERG 151
PPE: Level A or B required; SCBA mandatory; full chemical-resistant suit; butyl rubber gloves; avoid all skin contact due to dermal absorption hazard
ISOLATION: ERG 151: isolate spill 25-50m all directions; for large spills consider evacuation 100m downwind; if fire/tank involved isolate 800m and evacuate 1600m downwind
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 3006 — Thiocarbamate pesticide, liquid, poisonous
Class: 6 | Placard: Toxic | ERG Guide: 151
Appearance: Varies by formulation; typically a clear to amber or dark brown liquid with a mild to pungent chemical odor. May be dissolved in organic solvents.
Water Reactivity: No violent reaction with water, but may hydrolyze slowly; avoid contaminating water sources due to high toxicity
Extinguishing: Alcohol-resistant foam, dry chemical, CO2; water spray for cooling only, not for extinguishment
PPE: Level A or B required; SCBA mandatory; full chemical-resistant suit; butyl rubber gloves; avoid all skin contact due to dermal absorption hazard
Isolation: ERG 151: isolate spill 25-50m all directions; for large spills consider evacuation 100m downwind; if fire/tank involved isolate 800m and evacuate 1600m downwind
— Key Hazards —
• Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.
• Avoid any skin contact.
• Fire may produce irritating, corrosive and/or toxic gases.
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
SOURCE: allfirefighter.com/hazmat/un/3006 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN3006 Thiocarbamate pesticide, liquid, poisonous Cls6 ERG151 | allfirefighter.com/hazmat/un/3006SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/3006
Advertisement
FAQ
Highly toxic, may be fatal if inhaled, ingested or absorbed through skin. Avoid any skin contact. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive Containers may explode when heated. Runoff may pollute waterways.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level A or B required; SCBA mandatory; full chemical-resistant suit; butyl rubber gloves; avoid all skin contact due to dermal absorption hazard
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 151 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.