☣️ UN 3012 • CLASS 6

UN 3012 — Mercury based pesticide, liquid, poisonous

Placard: Toxic. ERG Guide 151. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Mercury based pesticide, liquid, poisonous is a liquid pesticide formulation assigned to UN 3012. It should be treated as a toxic pesticide product until the active ingredient, carrier solvent and concentration are confirmed from shipping papers and the SDS.

Hazard overview: The main concern with UN 3012 is toxic exposure from the pesticide formulation. Dermal absorption, inhalation of vapors or dust, ingestion, contaminated runoff and toxic fire gases are the response priorities.

Response guidance: For UN 3012, isolate the spill area, keep personnel upwind and avoid all skin contact. Use absorbent or containment methods compatible with the formulation and keep contaminated runoff out of drains. Fire control should focus on exposed packaging and the carrier solvent if present; verify the SDS before choosing water or foam.

Firefighter training notes: Train responders to treat UN 3012 as a toxic pesticide release, verify the exact product, control runoff and avoid skin contact during rescue, containment and decon.

Regulatory context: UN 3012 is regulated for transport as a hazardous pesticide entry. Product labels, shipping papers, SDS and local environmental reporting rules should guide final actions.

Storage & handling: Store UN 3012 away from food, feed, drains, ignition sources where applicable and incompatible chemicals. Keep containers closed, labeled and protected from heat or physical damage.

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UN 3012 Quick Details

UN 3012
Product name: Mercury based pesticide, liquid, poisonous
DOT Class: 6
Placard type: Toxic
ERG Guide: 151 (check current ERG)
Initial isolation: ERG 151: isolate spill 25-50m; if tank/rail car involved in fire, isolate 800m all directions

Common Hazards of UN 3012

  • Mercury-based pesticide liquids may be fatal if inhaled, ingested or absorbed through skin.
  • Liquid contact can contaminate PPE and expose responders during doffing.
  • Fire or heating may release irritating, corrosive or toxic decomposition gases.
  • Containers may rupture when heated even when the product itself is not readily flammable.
  • Runoff from spill control or firefighting can carry pesticide contamination into waterways.
  • Some formulations contain solvents or surfactants that change vapor, foam and cleanup behavior.
  • Exact product identity and concentration must be verified from SDS and shipping papers.
  • Mercury compounds can create persistent contamination and long-term environmental hazards.

Chemical Identity & Physical Properties

Liquid formulation, color varies by product (often clear to amber), may have chemical or solvent odor, room temperature liquid. Product-specific appearance and odor should not be used as the only identification method.

Also known asMercury pesticideOrganomercury pesticideMercurial pesticideMercury fungicide
AppearanceLiquid formulation, color varies by product (often clear to amber), may have chemical or solvent odor, room temperature liquid.
Flash PointVaries by formulation, typically 23-61C (73-142F) depending on solvent base
Boiling PointVaries by formulation, typically above 100C (212F)
Vapor DensityHeavier than air (typically 2-5 relative to air)
Water ReactivityNo significant reaction with water, but mercury compounds may leach
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3012

Extinguishing Media

Alcohol-resistant foam, dry chemical or CO2 for solvent fires; water spray only for cooling containers and vapor control when compatible.

PPE Requirements

⚠️ Level A or B required; full face SCBA mandatory; chemical-resistant suit; avoid all skin contact; mercury vapor hazard

Use positive-pressure SCBA and chemical-resistant protective clothing suitable for pesticide liquids. Gloves, boots and suit material should be selected from the SDS because permeation varies by active ingredient and solvent.

Isolation & Evacuation

ERG 151: isolate spill 25-50m; if tank/rail car involved in fire, isolate 800m all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 151).

First Actions for a UN 3012 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream; avoid low areas where vapors may collect.
  • Avoid breathing vapors, dust, mist or fire gases and prevent skin or eye contact.
  • Do not touch damaged containers or spilled material without appropriate PPE.
  • Ventilate confined spaces only when trained, equipped and authorized.
  • Use ERG 151, SDS, shipping papers and monitoring to confirm product hazards before close approach.
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📋 Copy & Share Field Card

UN 3012 — Mercury based pesticide, liquid, poisono
HAZMAT RADIO NOTE — UN 3012 Product: Mercury based pesticide, liquid, poisonous Class 6 / Toxic / ERG 151 PPE: Level A or B required; full face SCBA mandatory; chemical-resistant suit; avoid all skin contact; mercury vapor hazard ISOLATION: ERG 151: isolate spill 25-50m; if tank/rail car involved in fire, isolate 800m all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3012 — Mercury based pesticide, liquid, poisonous Class: 6 | Placard: Toxic | ERG Guide: 151 Appearance: Liquid formulation, color varies by product (often clear to amber), may have chemical or solvent odor, room temperature liquid. Water Reactivity: No significant reaction with water, but mercury compounds may leach Extinguishing: Alcohol-resistant foam, dry chemical or CO2 for solvent fires; water spray only for cooling containers and vapor control when compatible. PPE: Level A or B required; full face SCBA mandatory; chemical-resistant suit; avoid all skin contact; mercury vapor hazard Isolation: ERG 151: isolate spill 25-50m; if tank/rail car involved in fire, isolate 800m all directions — Key Hazards — • Mercury-based pesticide liquids may be fatal if inhaled, ingested or absorbed through skin. • Liquid contact can contaminate PPE and expose responders during doffing. • Fire or heating may release irritating, corrosive or toxic decomposition gases. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream; avoid low areas where vapors may collect. • Avoid breathing vapors, dust, mist or fire gases and prevent skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/mercury-based-pesticide-liquid-un-3012 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3012 Mercury based pesticide, liquid, poisonous Cls6 ERG151 | allfirefighter.com/hazmat/un/mercury-based-pesticide-liquid-un-3012SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/mercury-based-pesticide-liquid-un-3012

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3012

UN 3012 is a mercury-based pesticide liquid classified as toxic. The exact formulation must be verified from the SDS and shipping papers.

The pesticide entry is primarily toxic, but flammability can vary with the solvent carrier. Check the product SDS before choosing foam or water.

Mercury compounds can poison responders through inhalation, ingestion or skin contact and can leave persistent environmental contamination.

Use SCBA and chemical-resistant protective clothing. Level A or B may be needed depending on vapor levels, liquid contact and incident conditions.

Prevent contaminated runoff from entering drains or waterways when it can be done safely under incident command.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.