☣️ UN 3013 • CLASS 6

Substituted nitrophenol pesticide, liquid, poisonous, flammable

Placard: Toxic. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
Advertisement
Quick details
UN 3013
Class: 6
Placard type: Toxic
ERG: Guide 131 (check current ERG)
Isolation: ERG 131: isolate spill 25-50m all directions; evacuate 300m downwind if large spill; 800m if fire involving tanks/railcars
Chemical & Response Details
Also known asnitrophenol pesticidedinitrophenol pesticideDNOC pesticidenitrated phenol insecticide
AppearanceLiquid pesticide formulation, typically yellow to brown in color with a characteristic phenolic or chemical odor. May be viscous depending on formulation and concentration.
Flash Point23-61C (73-142F) depending on formulation
Boiling PointVaries by formulation, typically 100-200C (212-392F)
Vapor DensityHeavier than air (typically >3)
Water ReactivityNo significant reaction with water, but may be slightly soluble
ExtinguishingAlcohol-resistant foam, CO2, dry chemical, water spray for cooling
PPE⚠️ Level B minimum; full face SCBA required; chemical-resistant suit and gloves mandatory due to high dermal toxicity
IsolationERG 131: isolate spill 25-50m all directions; evacuate 300m downwind if large spill; 800m if fire involving tanks/railcars
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
  • TOXIC; may be fatal if inhaled, ingested or absorbed through skin.
  • Inhalation or contact with some of these materials will irritate or burn skin and eyes.
  • Methyl chloroacetate (UN2295) is an eye irritant/lachrymator (causes flow of tears).
  • Fire will produce irritating, corrosive and/or toxic gases.
  • Vapors may cause dizziness or asphyxiation, especially when in closed or confined areas.
  • Runoff from fire control or dilution water may cause environmental contamination.
  • HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
  • Vapors may form explosive mixtures with air.
First actions (field-minded)
  • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Ventilate closed spaces before entering, but only if properly trained and equipped.
  • Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
  • For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
  • For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
Advertisement
📋 Copy & Share
UN 3013 — Substituted nitrophenol pesticide, liqui
HAZMAT RADIO NOTE — UN 3013 Product: Substituted nitrophenol pesticide, liquid, poisonous, flammable Class 6 / Toxic / ERG 131 PPE: Level B minimum; full face SCBA required; chemical-resistant suit and gloves mandatory due to high dermal toxicity ISOLATION: ERG 131: isolate spill 25-50m all directions; evacuate 300m downwind if large spill; 800m if fire involving tanks/railcars ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3013 — Substituted nitrophenol pesticide, liquid, poisonous, flammable Class: 6 | Placard: Toxic | ERG Guide: 131 Appearance: Liquid pesticide formulation, typically yellow to brown in color with a characteristic phenolic or chemical odor. May be viscous depending on formulation and concentration. Water Reactivity: No significant reaction with water, but may be slightly soluble Extinguishing: Alcohol-resistant foam, CO2, dry chemical, water spray for cooling PPE: Level B minimum; full face SCBA required; chemical-resistant suit and gloves mandatory due to high dermal toxicity Isolation: ERG 131: isolate spill 25-50m all directions; evacuate 300m downwind if large spill; 800m if fire involving tanks/railcars — Key Hazards — • TOXIC; may be fatal if inhaled, ingested or absorbed through skin. • Inhalation or contact with some of these materials will irritate or burn skin and eyes. • Methyl chloroacetate (UN2295) is an eye irritant/lachrymator (causes flow of tears). — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Ventilate closed spaces before entering, but only if properly trained and equipped. SOURCE: allfirefighter.com/hazmat/un/3013 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.

SMS (short)
UN3013 Substituted nitrophenol pesticide, liquid, poisonous, flammable Cls6 ERG131 | allfirefighter.com/hazmat/un/3013SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/3013
Related UN numbers (same class)
Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

FAQ

TOXIC; may be fatal if inhaled, ingested or absorbed through skin. Inhalation or contact with some of these materials will irritate or burn skin and eyes. Methyl chloroacetate (UN2295) is an eye irritant/lachrymator (causes flow of tears). Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or asphyxiation, especially when in closed or confined areas. Runoff from fire control or dilution water may cause environmental contamination. HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air.

CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.

Level B minimum; full face SCBA required; chemical-resistant suit and gloves mandatory due to high dermal toxicity

No. This is a training/quick-reference aid only. Always consult the current ERG Guide 131 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.