☣️ UN 3175 • CLASS 4

UN 3175 — Solids containing flammable liquid, n.o.s.

Placard: Flammable Solid. ERG Guide 133. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Solids containing flammable liquid, n.o.s. covers a broad flammable solid hazard. The exact composition controls water compatibility, smoke hazards and cleanup.

Hazard overview: Treat the material as ignitable and potentially reactive until SDS confirms the specific substance and compatible extinguishing media.

Response guidance: Isolate the area, remove ignition sources, avoid dust or splash spread, and use dry media unless product data allows water or foam.

Firefighter training notes: Use this page as initial reference only; responders should train from ERG, SDS, department SOPs and product-specific preplans.

Regulatory context: UN 3175 is regulated for transport under its proper shipping name, hazard class 4 and ERG Guide 133. Verify current DOT/PHMSA requirements and shipping papers.

Storage & handling: Store only as permitted by the SDS and applicable code: segregate from incompatible materials, protect packages from heat, damage and moisture, and maintain labels.

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UN 3175 Quick Details

UN 3175
Product name: Solids containing flammable liquid, n.o.s.
DOT Class: 4
Placard type: Flammable Solid
ERG Guide: 133 (check current ERG)
Initial isolation: ERG 133: isolate spill/leak area 25m in all directions; if tank/rail car involved in fire, isolate 800m in all directions

Common Hazards of UN 3175

  • Flammable solid; ignition may occur from heat, sparks, friction or flames.
  • Dust, powder or exposed surface area can burn rapidly and may re-ignite.
  • Fire may produce irritating, toxic or corrosive smoke depending on the exact material.
  • Containers may rupture or fail when heated.
  • Water compatibility varies; some materials may react or spread contamination.
  • Runoff from firefighting can carry hazardous residues.
  • For n.o.s. entries, the SDS and shipping papers determine final extinguishing media and PPE.

Chemical Identity & Physical Properties

Solid material impregnated, wetted, or containing flammable liquid. Appearance varies widely depending on specific composition; may be granular, fibrous, or solid mass.

Also known asFlammable solid with liquidSolid-liquid flammable mixtureWetted flammable solid
AppearanceSolid material impregnated, wetted, or containing flammable liquid. Appearance varies widely depending on specific composition; may be granular, fibrous, or solid mass.
Flash PointVaries by composition; typically below 60C (140F) due to flammable liquid content
Boiling PointNot applicable (solid material with absorbed liquid)
Vapor DensityNot applicable (solid, though vapors from liquid component may be heavier than air)
Water ReactivityGenerally no significant reaction, but water may release absorbed flammable liquid
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3175

Extinguishing Media

Dry chemical, CO2, water spray (use caution as water may spread liquid), foam may be used

PPE Requirements

⚠️ Level C minimum for non-fire situations; Level B with SCBA for fire or high vapor concentrations

Use SCBA for fire conditions and chemical protective clothing when dust, toxic smoke or corrosive contact is possible.

Isolation & Evacuation

ERG 133: isolate spill/leak area 25m in all directions; if tank/rail car involved in fire, isolate 800m in all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 133).

First Actions for a UN 3175 Incident

  • Call 911 and the emergency response number shown on shipping papers.
  • Keep unauthorized personnel away and establish an isolation perimeter.
  • Stay upwind, uphill and upstream; avoid low areas where vapors or gases may collect.
  • Avoid breathing vapors, dust, smoke or decomposition products.
  • Do not touch damaged containers or spilled material without appropriate PPE.
  • Control ignition sources and avoid raising dust or spreading absorbed flammable liquid.
  • Ventilate confined spaces only if trained, equipped and atmospheric monitoring supports entry.
  • Use ERG guidance, SDS, labels and shipping papers to confirm the exact hazards before action.
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📋 Copy & Share Field Card

UN 3175 — Solids containing flammable liquid, n.o.
HAZMAT RADIO NOTE — UN 3175 Product: Solids containing flammable liquid, n.o.s. Class 4 / Flammable Solid / ERG 133 PPE: Level C minimum for non-fire situations; Level B with SCBA for fire or high vapor concentrations ISOLATION: ERG 133: isolate spill/leak area 25m in all directions; if tank/rail car involved in fire, isolate 800m in all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3175 — Solids containing flammable liquid, n.o.s. Class: 4 | Placard: Flammable Solid | ERG Guide: 133 Appearance: Solid material impregnated, wetted, or containing flammable liquid. Appearance varies widely depending on specific composition; may be granular, fibrous, or solid mass. Water Reactivity: Generally no significant reaction, but water may release absorbed flammable liquid Extinguishing: Dry chemical, CO2, water spray (use caution as water may spread liquid), foam may be used PPE: Level C minimum for non-fire situations; Level B with SCBA for fire or high vapor concentrations Isolation: ERG 133: isolate spill/leak area 25m in all directions; if tank/rail car involved in fire, isolate 800m in all directions — Key Hazards — • Flammable solid; ignition may occur from heat, sparks, friction or flames. • Dust, powder or exposed surface area can burn rapidly and may re-ignite. • Fire may produce irritating, toxic or corrosive smoke depending on the exact material. — First Actions — • Call 911 and the emergency response number shown on shipping papers. • Keep unauthorized personnel away and establish an isolation perimeter. • Stay upwind, uphill and upstream; avoid low areas where vapors or gases may collect. • Avoid breathing vapors, dust, smoke or decomposition products. SOURCE: allfirefighter.com/hazmat/un/solids-containing-flammable-liquid-un-3175 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3175 Solids containing flammable liquid, n.o.s. Cls4 ERG133 | allfirefighter.com/hazmat/un/solids-containing-flammable-liquid-un-3175SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/solids-containing-flammable-liquid-un-3175

Related UN Numbers in Class 4

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3175

Yes. It is a flammable solid entry and can ignite from heat, sparks, friction or flames.

Water compatibility depends on the exact material; use dry agents unless SDS confirms water is safe.

Use SCBA for fire conditions and chemical protective clothing when toxicity, corrosivity or dust is present.

This is a broad entry, so the exact substance determines reactivity, smoke toxicity and cleanup method.

Absorbed liquid can release flammable vapor and may spread if the solid breaks apart.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.