☣️ UN 3176 • CLASS 4

UN 3176 — Flammable solid, organic, molten, n.o.s.

Placard: Flammable Solid. ERG Guide 133. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Flammable solid, organic, molten, n.o.s. covers a broad flammable solid hazard. The exact composition controls water compatibility, smoke hazards and cleanup.

Hazard overview: Treat the material as ignitable and potentially reactive until SDS confirms the specific substance and compatible extinguishing media.

Response guidance: Isolate the area, remove ignition sources, avoid dust or splash spread, and use dry media unless product data allows water or foam.

Firefighter training notes: Use this page as initial reference only; responders should train from ERG, SDS, department SOPs and product-specific preplans.

Regulatory context: UN 3176 is regulated for transport under its proper shipping name, hazard class 4 and ERG Guide 133. Verify current DOT/PHMSA requirements and shipping papers.

Storage & handling: Store only as permitted by the SDS and applicable code: segregate from incompatible materials, protect packages from heat, damage and moisture, and maintain labels.

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UN 3176 Quick Details

UN 3176
Product name: Flammable solid, organic, molten, n.o.s.
DOT Class: 4
Placard type: Flammable Solid
ERG Guide: 133 (check current ERG)
Initial isolation: ERG 133: Initial isolation 50m in all directions; protective action distance 100m for large spill; thermal hazard perimeter based on material temperature

Common Hazards of UN 3176

  • Flammable solid; ignition may occur from heat, sparks, friction or flames.
  • Molten material can cause severe thermal burns and violent spattering if contacted by water.
  • Dust, powder or exposed surface area can burn rapidly and may re-ignite.
  • Fire may produce irritating, toxic or corrosive smoke depending on the exact material.
  • Containers may rupture or fail when heated.
  • Water compatibility varies; some materials may react or spread contamination.
  • Runoff from firefighting can carry hazardous residues.
  • For n.o.s. entries, the SDS and shipping papers determine final extinguishing media and PPE.

Chemical Identity & Physical Properties

Molten organic material maintained at elevated temperature above its melting point. Appearance varies depending on specific substance but typically viscous liquid state with potential vapors or fumes.

Also known asMolten organic flammable solidHeated flammable organic materialOrganic flammable solid N.O.S.Hot flammable organic substance
AppearanceMolten organic material maintained at elevated temperature above its melting point. Appearance varies depending on specific substance but typically viscous liquid state with potential vapors or fumes.
Flash PointNot applicable (already molten and above ignition temperature)
Boiling PointVariable depending on specific organic material
Vapor DensityVariable, typically heavier than air when vapors present
Water ReactivityGenerally no violent reaction, but water contact may cause violent boiling, spattering, and steam generation due to temperature differential
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3176

Extinguishing Media

Dry chemical, dry sand, soda ash; avoid water streams due to spattering risk

PPE Requirements

⚠️ Level B minimum with thermal protection; SCBA required; heat-resistant gloves and face shield mandatory due to molten material hazard

Use SCBA for fire conditions and chemical protective clothing when dust, toxic smoke or corrosive contact is possible.

Isolation & Evacuation

ERG 133: Initial isolation 50m in all directions; protective action distance 100m for large spill; thermal hazard perimeter based on material temperature
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 133).

First Actions for a UN 3176 Incident

  • Call 911 and the emergency response number shown on shipping papers.
  • Keep unauthorized personnel away and establish an isolation perimeter.
  • Stay upwind, uphill and upstream; avoid low areas where vapors or gases may collect.
  • Avoid breathing vapors, dust, smoke or decomposition products.
  • Do not touch damaged containers or spilled material without appropriate PPE.
  • Control ignition sources and avoid raising dust or spreading absorbed flammable liquid.
  • Ventilate confined spaces only if trained, equipped and atmospheric monitoring supports entry.
  • Use ERG guidance, SDS, labels and shipping papers to confirm the exact hazards before action.
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📋 Copy & Share Field Card

UN 3176 — Flammable solid, organic, molten, n.o.s.
HAZMAT RADIO NOTE — UN 3176 Product: Flammable solid, organic, molten, n.o.s. Class 4 / Flammable Solid / ERG 133 PPE: Level B minimum with thermal protection; SCBA required; heat-resistant gloves and face shield mandatory due to molten material hazard ISOLATION: ERG 133: Initial isolation 50m in all directions; protective action distance 100m for large spill; thermal hazard perimeter based on material temperature ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3176 — Flammable solid, organic, molten, n.o.s. Class: 4 | Placard: Flammable Solid | ERG Guide: 133 Appearance: Molten organic material maintained at elevated temperature above its melting point. Appearance varies depending on specific substance but typically viscous liquid state with potential vapors or fumes. Water Reactivity: Generally no violent reaction, but water contact may cause violent boiling, spattering, and steam generation due to temperature differential Extinguishing: Dry chemical, dry sand, soda ash; avoid water streams due to spattering risk PPE: Level B minimum with thermal protection; SCBA required; heat-resistant gloves and face shield mandatory due to molten material hazard Isolation: ERG 133: Initial isolation 50m in all directions; protective action distance 100m for large spill; thermal hazard perimeter based on material temperature — Key Hazards — • Flammable solid; ignition may occur from heat, sparks, friction or flames. • Molten material can cause severe thermal burns and violent spattering if contacted by water. • Dust, powder or exposed surface area can burn rapidly and may re-ignite. — First Actions — • Call 911 and the emergency response number shown on shipping papers. • Keep unauthorized personnel away and establish an isolation perimeter. • Stay upwind, uphill and upstream; avoid low areas where vapors or gases may collect. • Avoid breathing vapors, dust, smoke or decomposition products. SOURCE: allfirefighter.com/hazmat/un/flammable-solid-organic-molten-un-3176 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3176 Flammable solid, organic, molten, n.o.s. Cls4 ERG133 | allfirefighter.com/hazmat/un/flammable-solid-organic-molten-un-3176SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/flammable-solid-organic-molten-un-3176

Related UN Numbers in Class 4

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3176

Yes. It is a flammable solid entry and can ignite from heat, sparks, friction or flames.

Water compatibility depends on the exact material; use dry agents unless SDS confirms water is safe.

Use SCBA for fire conditions and chemical protective clothing when toxicity, corrosivity or dust is present.

This is a broad entry, so the exact substance determines reactivity, smoke toxicity and cleanup method.

Hot material can cause severe burns and may spatter violently if water is applied.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.